Common buzzards (Buteo buteo) bio-indicators of heavy metals pollution in Sicily (Italy)

The aim of this study was to evaluate the accumulation of toxic (As, Cd and Pb) and essential (Cu, Mn and Zn) metals in samples (feathers, liver, kidney, lung, intestine and muscle) of common buzzards (Buteo buteo) from Sicily, used as bio-indicators for monitoring environmental metals pollution. All samples of buzzards were collected at the “Recovery Center of Wild Fauna” of Palermo, through the Zooprophilactic Institute. The quantitative determinations of metals were carried out using an atomic absorbtion spectrophotometer (AAS). The results obtained showed the presence of metals in all samples analyzed. For toxic metals the highest levels of Pb and As were found in liver and those of Cd in kidney; for essential metals Zn levels were higher than Cu and Mn in all tissues analyzed. Significant differences are observed in metal levels between female and male and juvenile and adult bird samples.Highest metal levels found in liver, kidney and muscle can be considered indicative of chronic exposure to metals while the presence of metals in feathers can be consequential to storing and elimination processes. The results obtained suggest that common buzzards (Buteo buteo) may be very useful as bio-indicators for monitoring environmental pollution.     

Understanding the fate and transport of petroleum hydrocarbons from coal tar within gasholders

Coal tars have been identified as posing a threat to human health due to their toxic, mutagenic and carcinogenic characteristics. Workers involved in former gasholders decommissioning are potentially exposed to relevant concentrations of volatile and semi-volatile hydrocarbons upon opening up derelict tanks and during tar excavation/removal. While information on contaminated sites air-quality and its implications on medium-long term exposure is available, acute exposure issues associated with the execution of critical tasks are less understood. Calculations indicated that the concentration of a given contaminant in the gasholder vapour phase only depends on the coal tar composition, being only barely affected by the presence of water in the gasholder and the tar volume/void space ratio. Fugacity modelling suggested that risk-critical compounds such as benzene, naphthalene and other monocyclic and polycyclic aromatic hydrocarbons may gather in the gasholder air phase at significant concentrations. Gasholder emissions were measured on-site and compared with the workplace exposure limits (WELs) currently in use in UK. While levels for most of the toxic compounds were far lower than WELs, benzene air-concentrations where found to be above the accepted threshold. In addition due to the long exposure periods involved in gasholder decommissioning and the significant contribution given by naphthalene to the total coal tar vapour concentration, the adoption of a WEL for naphthalene may need to be considered to support operators in preventing human health risk at the workplace. The Level I fugacity approach used in this study demonstrated its suitability for applications to sealed environments such as gasholders and its further refining could provide a useful tool for land remediation risk assessors.     

Mass balance approach to estimating radionuclide loads and concentrations in edible fish tissues using stable analogues

Humans can consume a number of types of biota tissues, which have varying propensities to accumulate radionuclides. As a result, depending upon the biota species, the radionuclide and the tissue under consideration, it may be necessary to estimate the percent radionuclide load in specific edible tissues, and in cases where whole organisms are consumed, to estimate the radionuclide load in the whole body of an organism, based on data that have been collected for individual tissues. To accomplish this, data were compiled that can be used to estimate the partitioning patterns and percent loads of various groups of elements in edible tissues of freshwater fishes. General trends in partitioning, such as those provided in this paper, can be used to predict radionuclide transfer to humans and the corresponding potential radiological dose to humans via dietary pathways, in this case following the consumption of fish.     

On causes of gigantism in herbaceous plants

Landscape-geochemical features providing for manifestation of gigantism in herbaceous plants have been revealed in natural habitats in the south of Sakhalin and Kunashir islands. Tall herb assemblages have proved to be associated with geochemical landscapes characterized by reducing (gley or hydrogen sulfide) conditions and increased contents of petroleum hydrocarbons and some trace elements (total and movable forms). A hypothesis is put forward that gigantism in herbaceous plants is manifested in zones of active faults, which serve as a kind of conduits supplying endogenous heat, matter, and water to the root systems.     

Adaptive Management of Stream Channel Maintenance at Bridge Crossings in the Northern Tier Region,Pennsylvania1

Abstract: An adaptive management framework is applied to the problem of identifying mitigation measures for sediment deposition near bridge crossings in small streams in the Northern Tier region of northern Pennsylvania. The presence of the rigid bridge infrastructure introduces a challenge for applying adaptive management practices, because the integrity of the bridge structure itself has to be maintained regardless of the mitigation practices used in the stream channel near the bridge. In an effort to overcome the unacceptable risk that field‐scale adaptive management experiments present to rigid bridge infrastructure, an adaptive management approach for laboratory‐scale experimentation of mitigation methods at bridge crossings in the Northern Tier region is presented as a way to decrease the level of uncertainty about channel response to mitigation measures and increase the rate of learning about the effectiveness of these measures. Four cycles of adaptive management experiments are discussed to demonstrate that this approach results in fast and efficient learning about channel response to mitigation methods for the given conditions. The value of monitoring and of assessment of monitored data in the overall efficiency of the adaptive management approach is highlighted. Assessment of what was learned in the adaptive management experiment cycles presented here leads to new directions to continually improve management policies and practices in stream channels at bridge crossings in the Northern Tier region. The adaptive management process, rather than continuing with a normally risk‐averse management approach, results in opportunities for learning new information about a system’s response.     

The effects of aeration rate on generated compost quality, using aerated static pile method

To determine the most appropriate composting process in an active municipal solid waste system, an experiment was carried out using a nested design method with three aeration rates. During each aeration rate, parameters such as temperature, pH, EC, carbon-to-nitrogen ratio, NO(3)-N, nitrogen, potassium and phosphorous were measured and the efficiency of different composting processes was evaluated. The result of this study showed that the lower and medium aeration rates had a significant impact on nitrogen, carbon-to-nitrogen ratio and temperature profile, while higher aeration rates led to higher EC values. Furthermore, the thermophilic phase lasted 13, 9 and 4 weeks for the aeration rates of 0.4, 0.6 and 0.9 L min(-1)kg(-1), respectively. Accordingly, it was concluded that starting at a rate of 0.6 L min(-1)kg(-1) during first 2 months (about 9 weeks) of the process and continuing at a rate of 0.4 L min(-1)kg(-1)until the end of composting process would result in lower energy consumption.     

Aging and compressibility of municipal solid wastes

The expansion of a municipal solid waste (MSW) landfill requires the ability to predict settlement behavior of the existing landfill. The practice of using a single compressibility value when performing a settlement analysis may lead to inaccurate predictions. This paper gives consideration to changes in the mechanical compressibility of MSW as a function of the fill age of MSW as well as the embedding depth of MSW. Borehole samples representative of various fill ages were obtained from five boreholes drilled to the bottom of the Qizhishan landfill in Suzhou, China. Thirty-one borehole samples were used to perform confined compression tests. Waste composition and volume-mass properties (i.e., unit weight, void ratio, and water content) were measured on all the samples. The test results showed that the compressible components of the MSW (i.e., organics, plastics, paper, wood and textiles) decreased with an increase in the fill age. The in situ void ratio of the MSW was shown to decrease with depth into the landfill. The compression index, Cc, was observed to decrease from 1.0 to 0.3 with depth into the landfill. Settlement analyses were performed on the existing landfill, demonstrating that the variation of MSW compressibility with fill age or depth should be taken into account in the settlement prediction.     

De-novo formation of dioxins and furans and the memory effect in waste incineration flue gases

The formation of dioxin (polychlorinated-rho-dibenzodioxins - PCDD) and furan (polychlorinated dibenzofurans - PCDF) in waste incineration flyash in relation to temperature has been investigated in a bench scale reactor. The PCDD/PCDF released into the exhaust gases of the reactor and trapped in a condensation and vapour phase adsorption system were also determined. The concentrations of PCDD/PCDF in the flyash were analysed in detail for all congeners and isomers including the mono-, di- and tri-PCDD/PCDF. De-novo synthesis of PCDD/PCDF was clearly seen in the flyash with large changes in concentrations of PCDD/PCDF with only small changes in temperature. Exhaust gas PCDD/PCDF were detected at all temperatures, with the maximum emission occurring at a flyash temperature of 350 degrees C, where the equivalent of over 42 times the total dioxin/furan concentration of the original flyash was lost to the vapour phase per unit mass of initial flyash. Although the desorbed species were mainly the lower mono- to tri-congener group of dioxins and furans, the desorbed dioxin/furans had a considerable toxic equivalent value.     

Design,measurement and evaluation of photovoltaic pumping system for rural areas in Oman

In the present paper, the optimum design of a PV system used to operate a water pumping system was determined for Oman. The system design focused on the environmental conditions of Sohar city. The implementation and measurement of the designed system are presented to prove the effectiveness of the proposed system. The results show that the system can provide the required power at peak hours, leading to a substantial reduction in the sizing of the PV system. Consequently, the investment capital costs 2400 USD, and the cost of energy is equal to 0.309 USD/kWh. Furthermore, the results indicate that the system annual yield factor is 2024.66 kWh/kWp and that the capacity factor is 23.05 %, which is encouraging since the latter is typically 21 %. The system capital cost and the cost of energy are worth comparing to a diesel generator. A comparison is made between the proposed system and several others in the literature. The comparison indicated that the system cost of energy is promising.