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71.
Treatment of bleaching wastewater from pulp paper plants in China using enzymes and coagulants 总被引:1,自引:0,他引:1
ZHANG Tong Shinji Wa Takao Yamagishi Ichikawa Hiroyasu Kenji Tatsumi ZHAO Qingxiang 《环境科学学报(英文版)》1999,11(4):480-484
IntroductionBleachingwastewaterfrompulppaperplantscontainsmanykindsofchlorinatedorganiccompoundswhichareprovedtobecarcinogenic,mutagenicandrefractory(Gellman,1988;Paasivirta,1988;Garden,1990;Suntio,1988;Vuorinen,1987;Seppala,1988).Severalmethods,inc… 相似文献
72.
73.
Global solar radiation is recorded by fading of the colored film into which azo-dye is impregnated with use of organic solvent. Oil Red O, Sudan I, Sudan IV and Pyridylazonaphthol are used as the azo dye. These films can be applied to measure the solar radiation in many kinds of environmental or ecological conditions. The merits of the film compared with usual measurements are to be: unnecessary of any electric sources; cheap and mass-productive easily; suitable to integrate solar radiation for long time; easy dealing in out-door or underwater conditions; possible to use on leaves of any plants because of light weight; possible to use in a lot of points at the same time. 相似文献
74.
Aqueous phenol solutions containing TiO(2) nanoparticles were irradiated with ultraviolet (UV), gamma-ray and electron beams. Organic compounds were fully removed by each type of radiation in the presence of the particles. The absorbed energy of the ionizing radiation (gamma-ray and electron beams) needed for removal was much lower than that of UV photocatalysis. Phenol was decomposed by the ionizing radiation in the absence of the nanoparticles and the addition of TiO(2) had no significant effect on phenol decomposition rate. Instead, total organic carbon (TOC) removal using the ionizing radiation was accelerated drastically by TiO(2). It is suggested that TiO(2) particles affect the intermediate compounds produced through the decomposition of phenol. The amount of removed TOC per absorbed energy were compared in the absence and the presence of TiO(2) nanoparticles. Radiolysis with the nanoparticles showed consistently high rate and high efficiency of TOC removal. 相似文献
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76.
Takao Iida Hironori Hirakawa Takahiko Matsueda Shigeyuki Takenakal Junya Nagayama 《Chemosphere》1999,38(15):3497-3502
We investigated PCDDs and related compounds in the blood of young Japanese women, approximately 20 years of age, who had not yet had children, and discussed how the TEQ level of PCDDs and related compounds in their blood may affect the next generation. Means of total TEQ levels were 0.063 pg/g for whole blood basis and 21 pg/g for lipid basis. TEQ of PCDDs, PCDFs and coplanar PCBs accounted for about 43, 34 and 23% of the total TEQ in the whole blood basis, respectively. In the lipid basis, their values were about 44, 34 and 22%, respectively. Previously, we investigated PCDDs and related compounds levels in mother's breast milk, lymphocyte subpopulation and thyroid function of their children, and found negative correlations between the TEQ level of PCDDs and related compounds and CD4+/CD8+, and/or the TEQ level of PCDDs and related compounds and the T4 level in 36 mothers and children. Of these cases, the average age was approximately 28 years. PCDDs and related compounds may be related to immunopathy, such as atopic dermatitis. The effects of PCDDs and related compounds on babies of young Japanese women are important and must be further evaluated. 相似文献
77.
Tomoaki Tsutsumi Toshihiko Yanagi Munetomo Nakamura Yoichi Kono Hiroyasu Uchibe Takao Iida Tsuguhide Hori Reiko Nakagawa Kazuhiro Tobiishi Rieko Matsuda Kumiko Sasaki Masatake Toyoda 《Chemosphere》2001,45(8):1129-1137
Total diet study (TDS) samples of 14 food groups from 16 locations in Japan, collected in 1999 and 2000, were analyzed for polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs), and dioxin-like polychlorinated biphenyls (dioxin-like PCBs) to estimate the update of daily intake of these contaminants from food. The mean daily intake of toxic equivalency (TEQ) for an adult weighing 50 kg, calculated at non-detected isomer concentrations equal to zero (ND=0), was estimated to be 2.25 pg TEQ/kg b.w./day. When non-detected isomer concentrations are assumed to be equal to half of the limits of detection (ND=1/2 LOD), the mean daily intake was estimated to be 3.22 pg TEQ/kg b.w./day. These values were below the tolerable daily intake (TDI) of 4 pg TEQ/kg b.w. for PCDD/Fs and dioxin-like PCBs set in Japan. In both the estimates, the mean daily intakes were highest from fish and shellfish (76.9% at ND=0 and 53.9% at ND=1/2 LOD of the total TEQs), followed by those from meat and eggs (15.5% at ND=0 and 11.7% at ND=1/2 LOD of the total TEQs). Congener specific data revealed that these total TEQ levels were dominated by 1,2,3,7,8-PeCDD, 2,3,4,7,8-PeCDF and 3,3′,4,4′,5-PeCB in each case (71.7% at ND=0 and 63.1% at ND=1/2 LOD of the total TEQs). The dioxin-like PCBs (non-ortho and mono-ortho PCBs) accounted for about 50% of these total TEQs. These data will be very useful in the risk assessment of PCDD/Fs and dioxin-like PCBs from food in Japan. 相似文献
78.
Hiroaki Naoe Shuichi Hasegawa Jost Heintzenberg Kikuo Okada Akihiro Uchiyama Yuji Zaizen Eriko Kobayashi Akihiro Yamazaki 《Atmospheric environment (Oxford, England : 1994)》2009,43(6):1296-1301
The state of mixture of light-absorbing carbonaceous particles was investigated in relation to light absorption properties using electron microscopic examinations, black carbon (BC) analyses of quartz filter by thermal/optical reflectance (TOR) method, measurements with two continuous light-absorbing photometers at a suburban site of Tsukuba, about 60 km northeast of Tokyo. The volume fraction of water-soluble material (?) in individual particles is important for assessing particulate light-absorbing and/or scattering of atmospheric aerosols. The values of ? in BC particles were evaluated by electron micrographs before and after dialysis (extraction) of water-soluble material. The mass absorption coefficient (MAC in units of m2 g?1) tended to increase with increasing the average ? in BC particles with the radius range of 0.05–0.5 μm. Thus, our results indicate that coatings of water-soluble material around BC particles can enhance the absorption of solar radiation. Moreover, the single scattering albedo (SSA) will increase because a large amount of coating material will scatter more light. 相似文献
79.
Toshio Mogi Hiroumi Shiina Yuji Wada Ritsu Dobashi 《Journal of Loss Prevention in the Process Industries》2013,26(1):32-37
Dimethyl ether (DME) has been focused as a substitute for diesel fuel, and a number of studies have investigated engines fueled with DME because DME has a low auto-ignition temperature and does not generate particulate matter (PM). Therefore, in the last few years, the construction of DME filling stations for trucks in Japan has been planned. The introduction of DME vehicles requires expansion of DME supply stations, which in turn requires the collection of safety data and the establishment of safety regulations. The present paper describes an experimental investigation of the hypothetical scenario in which liquid DME is accidentally released and an explosion occurs. In the present study, large-scale leakage and ignition of DME were investigated and flame propagation data was obtained. We also measured the overpressure of the blast wave and the heat flux from the fireball. When the ignition position is near the nozzle, the flame propagation velocity is higher. The overpressure from the DME fireball is stronger than that from DME/air mixture deflagration. In summary, these results provide safety data for safety management of DME filling stations. 相似文献
80.
Structure design of a photosynthetic-based biofuel cell and the fabrication processes to make it have been explored and developed. Novel nanostructure and modified polyaniline have been used to enhance the performance of the biofuel cell. The mechanism of the electron transfer process and the electrocatalysis of polyaniline have been investigated. Photosynthetic-based biofuel cells with a mA/cm2 current density have been demonstrated. 相似文献