Formation rates of polychlorinated dibenzofurans and dibenzo-p-dioxins from polycyclic aromatic hydrocarbons, activated carbon and phenol

The formation rates of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) from polycyclic aromatic hydrocarbons (PAHs), activated carbon, and phenol were compared. The heat treatment at 300°C of all tested PAH on silica in the presence of CUCl₂ Preferred PCDDs over PCDDs. Perylene reproducibly gave a higher yield of PCDDs than activated carbon gave under the same conditions. The formation rate of PCDDs from perylene could be higher than the values in this study because the residence time of perylene in the reactor is shorter than that of activated carbon. PCDDs were mainly formed from phenol.     

Agroforestry in the Western Ghats of peninsular India and the satoyama landscapes of Japan: a comparison of two sustainable land use systems

Agroforestry in the Western Ghats (WG) of peninsular India and satoyama in rural Japan are traditional land-use systems with similar evolutionary trajectories. Some of their relevance was lost by the middle of the twentieth century, when modern agricultural technologies and urbanisation engineered shifts in emphasis towards maximising crop production. There has been, however, a resurgence of interest in traditional land-use systems recently, in view of their ability to provide ecosystem services. Both agroforestry and satoyama are thought to be harbingers of biological diversity and have the potential to serve as “carbon forests.” Carbon (C) stock estimates of the sampled homegardens in WG ranged from 16 to 36 Mg ha⁻¹. Satoyama woodlands owing to variations in tree stocking and management conditions indicated widely varying C stocks (2–279 Mg ha⁻¹). Agroforestry and satoyama also differ in nature, complexity, and objectives. While agroforestry involves key productive and protective functions, and adopts ‘intensive management’, the satoyama woodlands are extensively managed; understorey production is seldom a consideration. Differences in canopy architecture (multi-tiered structure of agroforestry vs. the more or less unitary canopy of satoayama) and land ownership pattern (privately owned/managed agroforestry holdings vs. community or local government or privately owned and mostly abandoned satoyamas) pose other challenges in the transfer and application of knowledge gained in one system to the other. Nonetheless, lessons learnt from satoyama conservation may be suitable for common pool resource management elsewhere in Asia, and aspects relating to understorey production in agroforestry may be relevant for satoyama under certain scenarios.     

Size partitioning of particulate inorganic nitrogen species between the fine and coarse mode ranges and its implication to their deposition on the surface ocean

In order to discuss the dry deposition fluxes of atmospheric fixed nitrogen species, observations of aerosol chemistry including nitrate (NO₃^?) and ammonium (NH₄⁺) were conducted at two islands, Rishiri Island and Sado Island, over the Sea of Japan. Although the atmospheric concentrations of particulate NH₄⁺–N showed higher values than those of particulate NO₃^?–N at both sites, the dry deposition fluxes of the particulate NO₃^?–N were estimated to be higher than those of the particulate NH₄⁺–N. This was caused by the difference of particle sizes between the particulate NO₃^? and NH₄⁺; NH₄⁺ was almost totally contained in fine particles (d < 2.5 μm) with smaller deposition velocity, whereas NO₃^? was mainly contained in coarse particles (d > 2.5 μm) with greater deposition velocity. Fine mode NO₃^? was strongly associated with fine mode sea-salt and mineral particles, of which higher concentrations shifted the size of particulate NO₃^? toward the fine mode range. This size shift would decrease the dry deposition flux of the fixed nitrogen species on coastal waters and accelerate atmospheric transport of them to the remote oceanic areas.     

Anaerobic transformation of chlorophenols in methanogenic sludge unexposed to chlorophenols

Transformation of all 19 chlorophenol (CP) isomers was investigated in a laboratory anaerobic methanogenic sludge that had not been exposed to synthetic chemicals. Concentration of CP was analyzed over time to calculate disappearance rate constants using first-order reaction kinetics and all possible CP degradation pathways were estimated. The rate constants ranged between 0.46 x 10(-3) and 0.161 day(-1). CPs were transformed via dechlorination. The chlorine atom at the ortho-position was the most easily dechlorinated, whereas dechlorination rate at the para-position was lowest. The overall pathways of CP transformation were much less diverse than that we previously found for contaminated sediment. The Dolfing hypothesis of microbial selection of the most thermodynamically favorable pathways was not applicable for CP transformation in this study as well as previous study performed by our group.     

Relationship Between Pastoralists’ Evaluation of Rangeland State and Vegetation Threshold Changes in Mongolian Rangelands

Applying the threshold concept to rangeland management is an important challenge in semi-arid and arid regions. Threshold recognition and prediction is necessary to enable local pastoralists to prevent the occurrence of an undesirable state that would result from unsustainable grazing pressure, but this requires a better understanding of the pastoralists’ perception of vegetation threshold changes. We estimated plant species cover in survey plots along grazing gradients in steppe and desert-steppe areas of Mongolia. We also conducted interviews with local pastoralists and asked them to evaluate whether the plots were suitable for grazing. Floristic composition changed nonlinearly along the grazing gradient in both the desert-steppe and steppe areas. Pastoralists observed the floristic composition changes along the grazing gradients, but their evaluations of grazing suitability did not always decrease along the grazing gradients, both of which included areas in a post-threshold state. These results indicated that local pastoralists and scientists may have different perceptions of vegetation states, even though both of groups used plant species and coverage as indicators in their evaluations. Therefore, in future studies of rangeland management, researchers and pastoralists should exchange their knowledge and perceptions to successfully apply the threshold concept to rangeland management.     

The role of community-based organization in the promotion of disaster preparedness at the community level: a case study of a coastal town in the Kochi Prefecture of the Shikoku Region, Japan

The Japanese rural coastal areas are inherently vulnerable to typhoons and tsunamis. Their vulnerability has been further increasing recently, in part due to social factors such as the aging of society and depopulation. Following the Kobe earthquake of 1995, the Japanese government has promoted the Voluntary Disaster Preparedness Organization (VDPO) to build communities that are more sustainable and resilient to natural disasters. However, studies indicate that some VDPO activity has stagnated. The present study focuses on a rural coastal area in Japan and examines whether VDPO impacts residents’ awareness of disaster preparedness and also examines ties among the community. The study relies on a questionnaire survey. It reveals that VDPO contributes to improving both awareness of disaster preparedness and ties in the community.     

Body morphologies shape territorial dominance in the satyrine butterfly <Emphasis Type="Italic">Lethe diana</Emphasis>

Male butterflies compete over mating territories via aerial interactions. It has often been suggested that flight performance, and thus flight-related traits, would play an important role in butterflies’ contest resolution; however, most studies have not demonstrated a clear relationship between these traits and territory ownership in butterflies. Males of the satyrine butterfly Lethe diana compete over territories via linear chases, a behavior that is uncommon among butterflies: rather, contests of most butterfly species consist of circling flights. In the present study, some morphological and physiological traits of L. diana were compared between territory owners and intruders to search for traits correlated with resource holding power (RHP). Territory owners had higher flight-muscle ratio (FMR) and were heavier than intruders, indicating that flight performance plays a key role in their contest resolution. Contest duration was not affected by the owners’ FMR or body mass, and thus I obtained no evidence supporting the hypothesis that contestants assess their relative RHP before making a decision to retreat. I speculate that the fact that these traits had an effect on territorial status in L. diana was a result of the characteristics of the contest behavior of this butterfly. During their contests, males L. diana fly faster in their linear flights than males of most other butterflies, which engage in slower circling flights. Therefore, males of L. diana probably need higher flight performance capabilities in order to win their contests.