以污泥为载体的金属氧化物脱硝催化剂的研究

以城市污水处理厂剩余污泥为原料,用氯化锌、硝酸锰和硝酸铁化学浸渍、高温热解制备脱除NO的催化剂.用微型气固相催化反应装置考察了该催化剂在CO选择性催化还原NO中的应用效果及寿命.实验结果表明:在350～550℃时的催化活性较高,在450℃时NO的最大转化率可达97.1%;催化剂的活性良好,经660 min的活性测试,催化剂的活性只降低了约3%.对该催化剂进行了BET、X射线衍射和扫描电镜分析,结果表明,该催化剂具有丰富的晶体结构,而且表面及空隙间负载的活性粒子较多,这些特征也表明该催化剂具有良好的催化性能.     

深度烟气脱硫(AFGD)工艺的研究

介绍了深度烟气脱硫（AFGD）工艺的过程及其核心部件JBR反应器的工作原理，分析了该项技术的技术创新之处及其综合性能。经过实际应用，AFGD工艺脱硫率可以达到93．4％。并且运行安全、稳定、简单和投资低。     

用三维平流扩散模式预测滇池地区氟化物污染

根据包含有PBL湍流统计量的三维物质连续方程,作者设计了一个同时考虑大气参数的时空(三维)变化、多个连续污染源、线性的化学转化和迁移以及复杂地形影响的三维平流扩散模式,并将滇池地区整个PBL内连续实测的湍流统计量、拉氏时间尺度、中尺度流场和混合层厚度直接输入模式,对山谷风、湖陆风和城市热岛(昆明市)中尺度局地环流控制下的氟化氢浓度的日变化作了预测。结果表明,在输入同一资料情况下,预测的结果与实测值大体上一致。     

Investigation of the common intermediates over Fe-ZSM-5 in NH3-SCR reaction at low temperature by in situ DRIFTS

The surface species formed in the reaction of NO and NO₂ with pre-adsorbed NH₃ over a Fe-ZSM-5 catalyst (1.27 wt.% Fe, SiO₂/Al₂O₃ = 25) at low temperature (140°C) were studied by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Through using a background spectrum of NH₃-saturated Fe-ZSM-5, we clearly observed the formation of common intermediates resulting from the reaction of NO₂ or NO + O₂ with pre-adsorbed NH₃. This presents strong evidence that the oxidation of NO to form surface nitrates and nitrites is the key step for standard SCR at low temperature. In addition, the results suggest that in the SCR reaction at low temperature, the NH₄⁺ ions absorbed on Brønsted acid sites are less active than NH₃ adsorbed on Lewis acid sites related to Fe species.     

Analysis of the origin of peak aerosol optical depth in springtime over the Gulf of Tonkin

By aggregating MODIS(moderate-resolution imaging spectroradiometer) AOD(aerosol optical depth) and OMI(ozone monitoring instrument) UVAI(ultra violet aerosol index)datasets over 2010–2014, it was found that peak aerosol loading in seasonal variation occurred annually in spring over the Gulf of Tonkin(17–23°N, 105–110°E). The vertical structure of the aerosol extinction coefficient retrieved from the spaceborne lidar CALIOP(cloud-aerosol lidar with orthogonal polarization) showed that the springtime peak AOD could be attributed to an abrupt increase in aerosol loading between altitudes of 2 and 5 km.In contrast, aerosol loading in the low atmosphere(below 1 km) was only half of that in winter. Wind fields in the low and high atmosphere exhibited opposite transportation patterns in spring over the Gulf of Tonkin, implying different sources for each level. By comparing the emission inventory of anthropogenic sources with biomass burning, and analyzing the seasonal variation of the vertical structure of aerosols over the Northern Indo-China Peninsula(NIC), it was concluded that biomass burning emissions contributed to high aerosol loading in spring. The relatively high topography and the high surface temperature in spring made planetary boundary layer height greater than 3 km over NIC. In addition, small-scale cumulus convection frequently occurred, facilitating pollutant rising to over 3 km, which was a height favoring long-range transport. Thus, pollutants emitted from biomass burning over NIC in spring were raised to the high atmosphere, then experienced long-range transport, leading to the increase in aerosol loading at high altitudes over the Gulf of Tonkin during spring.     

构建服务型消防行政管理模式的对策思考

改革开放和社会进步,给消防工作的发展提供了难得的机遇和挑战。强化政府消防行政职能,改善消防安全环境,构建服务型消防管理新模式成为社会发展的必然。本文分析了当前政府在消防行政管理中存在的问题,从消防行政管理理念、消防监督模式以及消防工作机制等方面给出了构建服务型消防行政管理模式的对策。     

废纸造纸废水零排放技术比较及绩效评估

通过调研江苏省废纸造纸企业,选取了三种典型的废纸造纸废水零排放技术,剖析了相应的工艺特点及优缺点,并对其进行绩效评估。比较得出“废纸造纸污水污泥双零排放技术”将污水、污泥加工处理后回用到造纸流程中,实现污水污泥双零排放,且该技术适用于生产高档瓦楞纸,较其他二者更具有优越性,从而为废纸造纸企业提供废水零排放技术参考,最终实现节能、减排、增效的目标。     

Experimental study on the control of black smoke pollution from the ceramic kilns based on the mechanism of the surfactant and coagulant

Aiming at the characteristics of carbon black, a new method of controlling the black smoke from the industrial coal-burning ceramic kilns by wetting was brought forward. The carbon black in the flue of coal-burning ceramic kiln was collected for the experiments, and its physical and chemical properties were studied in detail. In order to change the sedimentation and wettability state of the carbon black, the complex solution of the coagulant and surfactant was applied. After a series of orthogonal experiments, the complex solutions with better effects were chosen. Then, the sedimentation percentage of carbon black treated by the selected complex solutions was measured. The optimized complex solutions included Na₂SO₄ (100 mmol/L), sodium dodecyl benzenesulfonate (SDBS) (1.2 mmol/L) and polyacrylamide (PAM) (40 mg/L). After carbon black was absorbed, the complex solutions were clear and colorless. The complex solutions can be recycled, and the sedimentation percentage of carbon black is 94%. __________ Translated from Research of Environmental Sciences, 2006, 19(4), 80–85 [译自: 环境科学研究]     

居室氡浓度及其影响因素分析

氡是广泛存在于居室中的一种放射性气体,和人体的健康密切相关。以慈溪市某典型居民住宅为研究对象,重点研究了通风、温度、高度、地面装饰材料对室内氡浓度的影响,以及一天中氡浓度的连续变化规律。结果表明：在同一建筑物中,随着楼层的增加,室内氡浓度逐渐降低;在温度为24℃左右时室内氡浓度最低,在15℃～30℃之间,氡浓度表现大致为先下降后上升;随着通风时间的增加,室内氡浓度逐渐降低;夜间的氡水平比白天高,氡水平值的波动范围较大,且呈周期性变化。     

组织氛围对建筑工人不安全行为的影响机理及实证研究

为了研究组织氛围对建筑工人不安全行为的影响,从班组级安全氛围、班组级安全教育和项目级安全氛围三个层面测量组织氛围,基于组织氛围与安全态度、不安全动机及安全能力之间的关系,构建建筑工人不安全行为发生的机理。通过23个项目267份有效问卷收集数据,采用结构方程模型（SEM）进行验证,采用决策试验和评价实验室（DEMATEL）进一步计算和分析各潜变量之间的影响度和被影响度。研究结果表明:班组级安全氛围对安全态度、班组级安全教育对安全态度、安全能力对安全态度、安全态度对安全动机的影响显著;安全动机和安全能力对不安全行为的影响显著;班组级安全氛围、班组级安全教育和项目级安全氛围之间相互关系显著;班组级安全氛围、班组级安全教育和项目级安全教育是典型的原因影响因素,通过安全态度共同影响不安全行为。根据研究结果,提出应对措施,可为安全管理工作提供理论指导。