Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate)/Polylactide Blends: Thermal Stability,Flammability and Thermo-Mechanical Behavior

Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and polylactide (PLA) with different PHBV/PLA weight ratios (100/0, 75/25, 50/50, 25/75, 0/100) were prepared by melt compounding. Their mutual contributions in terms of thermal stability, flammability resistance, mechanical properties and rheological behavior were investigated. The study showed that the increase in PLA content in PHBV/PLA blends leads to enhanced properties. Consequently, thermal stability and flammability resistance were improved. Further, the rheological measurements indicated an increase in storage modulus and loss modulus of PHBV matrix by addition of PLA.     

Restoration ecology of riverine wetlands: II. An example in a former channel of the Rhône River

Riverine wetlands, which provide numerous valuable functions, are disappearing in floodplains of a channelized European river. A restoration project has been proposed by scientists to restore a former braided channel of the Rhône River by the removal of fine organic sediments in order to enhance groundwater supply. A precise and intensive prerestoration monitoring program during one year (including comparison with a reference channel) has taken into account several variables and ecological performance indicators measured at various spatial and temporal scales. Three restoration techniques were then suggested, taking into account two characteristics of ecosystem functions for increasing restoration success and self-sustainability: (1) the riparian forest as well as the shores must be preserved or disturbed as little as possible; and (2) the upstream alluvial plug must be preserved to prevent direct supply of nutrientrich water from the Rhône River. Among the three restoration options proposed, it was not possible to carry out the less ecologically disturbing one as it was considered too expensive, time consuming, and difficult to realize. A precise and intensive postrestoration monitoring program, conducted over two years, demonstrated restoration success but also unpredicted problems, such as a locally thick layer of fine organic sediment. As long as a self-sustainable state is not achieved, this monitoring should be continued. Afterwards, a less precise and less intensive long-term monitoring should enable the detection of future events that may influence ecosystem changes.     

Operational leeway in work situations: do ergonomic risk assessment tools consider operational leeway for job analysis?

Our study shows that information on operational leeway is limited in the originator articles of the ergonomic risk assessment tools for prevention of musculoskeletal disorders (MSDs). The tools’ underlying theoretical models do not consider the indicators of operational leeway, and they cannot determine the sufficiency of the situational operational leeway in a work situation. Consequently, regulation of the activity, which ensures the performance goals and the individual's health, has been overlooked. The lack of literature on indicators of situational operational leeway is one of the reasons for this deficit. Defining the indicators for this concept would be an innovation in the approach of MSD risk prevention. Developing empirically the concept of situational operational leeway in risk assessment tools would help to progress the current approach of MSD prevention. This study therefore proposes indicators of situational operational leeway to increase the representativeness and reliability of the risk assessment tools for MSDs.     

Hydroxyl, hydroperoxyl free radicals determination methods in atmosphere and troposphere

The hydroxyl radical (?OH) has a crucial function in the oxidation and removal of many atmospheric compounds that are harmful to health. Nevertheless, high reactivity, low atmospheric abundance, determination of hydroxyl, and hydroperoxyl radical's quantity is very difficult. In the atmosphere and troposphere, hydroperoxyl radicals (HO₂) are closely demanded in the chemical oxidation of the troposphere. But advances in technology have allowed researchers to improve the determination methods on the research of free radicals through some spectroscopic techniques. So far, several methods such as laser-induced fluorescence (LIF), high-performance liquid chromatography (HPLC), and chemical ionization mass spectroscopy have been identified and mostly used in determining the quantity of hydroxyl and hydroperoxyl radicals. In this systematic review, we have advised the use of scavenger as an advance for further researchers to circumvent some of these problems caused by free radicals. The primary goal of this review is to deepen our understanding of the functions of the most critical free radical (?OH, HO₂) and also understand the currently used methods to quantify them in the atmosphere and troposphere.     

Replacement of reproductives in Nasutitermes princeps (Desneux) (Isoptera: Termitidae)

Summary The production of replacement reproductives in experimentally orphaned societies was investigated in Nasutitermes princeps (Desneux). From 1 to 180 replacement queens and multiple kings, all adultoids, were found in the 13 nests that were re-collected. Normal imagos, microimagos, or a mixture of the two forms were present, depending on colony composition at the time of orphaning. In colonies with alates, the corresponding forms were found as replacement reproductives. Where only young nymphs were present, microimagos differentiated. Neither the number of queens nor their level of physogastry was correlated with the time elapsed since orphaning, but the total egg-laying rates were. We suggest that competition among queens rather than time determines individual physogastric development. Observations show that the most likely cause of accidental queen death in nature is probably nest fall from the supporting tree. Even in this case, the queen may be able to migrate to a newly rebuilt nest. An experimental simulation of this situation showed that colony migration can occur. The data indicate that the replacement of the primary queen after her accidental death cannot by itself account for the high rate of polygyny (60%) encountered in N. princeps. Two other possible causes are the replacement of the ageing foundress as a normal event of colony life, and colony reproduction by budding off new nests with adultoid reproductives.King Léopold III Biological Station, Laing Island, Papua New Guinea, contribution no. 84Research Assistant of the National Fund for Scientific Research (Belgium)     

Diving behaviour of female northern rockhopper penguins, Eudyptes chrysocome moseleyi, during the brooding period at Amsterdam Island (Southern Indian Ocean)

The pattern and characteristics of diving in 14 female northern rockhopper penguins, Eudyptes chrysocome moseleyi, were studied at Amsterdam Island (37°50′S; 77°31′E) during the guard stage, using electronic time–depth recorders. Twenty-nine foraging trips (27 daily foraging trips and two longer trips including one night) with a total of 16 572 dives of ≥3 m were recorded. Females typically left the colony at dawn and returned in the late afternoon, spending an average of 12 h at sea, during which they performed ∼550 dives. They were essentially inshore foragers (mean estimated foraging range 6 km), and mainly preyed upon the pelagic euphausiid Thysanoessa gregaria, fishes and squid being only minor components of the diet. Mean dive depth, dive duration, and post-dive intervals were 18.4 m (max. depth 109 m), 57 s (max. dive duration 168 s), and 21 s (37% of dive duration), respectively. Descent and ascent rates averaged 1.2 and 1.0 ms⁻¹ and were, together with dive duration, significantly correlated with dive depth. Birds spent 18% of their total diving time in dives reaching 15 to 20 m, and the mean maximum diving efficiency (bottom time:dive cycle duration) occurred for dives reaching 15 to 35 m. The most remarkable feature of diving behaviour in northern rockhopper penguins was the high percentage of time spent diving during daily foraging trips (on average, 69% of their time at sea); this was mainly due to a high dive frequency (∼44 dives per hour), which explained the high total vertical distance travelled during one trip (18 km on average). Diving activity at night was greatly reduced, suggesting that, as other penguins, E. chrysocome moseleyi are essentially diurnal, and locate prey using visual cues. Received: 9 December 1998 / Accepted: 3 March 1999     

The true distribution and accumulation of radiocaesium in stem of Scots pine (Pinus sylvestris L.)

The radial and vertical distributions of radiocaesium, potassium and calcium were determined in two Scots pine stands (17 and 58 yr old) similarly affected by the Chernobyl fallout. For both age classes, concentrations are always the lowest in the stemwood, highest in the inner bark and intermediary levels were observed for the outer bark. Due to the cumulative character of its biomass. however. stemwood is a long-term major reservoir of 137Cs. With tree development, changes in the 137Cs radial distribution are well described by variations in the sap ascent pattern and reveal an important transfer between tree rings. It is shown that. both the biomass evolution and knowledge of the evolution of the 137Cs radial gradient are important to predicting 137Cs accumulation in wood with time. According to the common transfer factor (TF) approach, one would expect a decrease in radiocaesium accumulation with time (from 0.0047 +/- 0.0013 to 0.0035 +/- 0.0008 m2kg(-1) for the 17 and 58 yr old trees, respectively). With the wood immobilisation potential (WIP) approach, it was, however, clearly shown that additional annual uptake was highest for the older stand (3.12 +/- 0.23 Bq cm(-3) yr(-1) for the 58-year-old stand compared to 1.99 +/- 0.30 Bq cm(-3) yr(-1) for the younger stand). Following the WIP approach, it was moreover possible to distinguish between the 137Cs incorporated via the root uptake process and a possible lasting effect of interception. It is shown that, whereas for the younger stand (5 yr old at the time of the accident) root uptake contributed exclusively to the wood contamination, the former process explained only 48% of the measured total 137Cs content in the wood of the older tree.     

Trophic ecology of Grey-headed albatrosses from Marion Island, Southern Ocean: insights from stomach contents and diet tracers

During chick-rearing, albatrosses can alternate between long foraging trips that provide the main source of food for the adults and short foraging trips that they use to feed their young. This flexibility in foraging behaviour can lead to differences in diet composition between adults and chicks and implies that they may be vulnerable in different ways to food shortages. The trophic ecology of the Grey-headed albatross Thalassarche chrysostoma was investigated at the sub-Antarctic Prince Edward Islands during the chick-rearing period in April 2006 using a combination of approaches. Diets of adults and chicks were assessed using stable isotope ratios and fatty acid (FA) profiles of blood and/or stomach oils, in addition to stomach contents analysis. Fish from the family Macrouridae and cephalopods (particularly the onychoteuthid Kondakovia longimana) were the primary prey, whereas crustaceans (krill Euphausia superba) represented a smaller proportion of the stomach contents. Stomach oil FA profiles contained more monounsaturated FA than the profiles of plasma, which were richer in saturated FA and arachidonic acid (20:4n-6). There was also a distinct separation of adults from chicks, with higher levels of monounsaturates in chick plasma, and higher saturated FA levels (particularly 16:0) in the adult plasma. Stable carbon isotope ratios of whole blood were similar in adults and chicks, whereas stable nitrogen isotope ratios showed significant enrichment by >1‰ in chicks. The combined FA, stable isotopes and stomach contents analyses suggest clear differences in diet quality between adults and chicks, with chicks feeding at a higher trophic position through feeding more on highly nutritious fish and adults keeping much of the less nutritious zooplankton for themselves.     

Past, current and future fire frequency in the Canadian boreal forest: implications for sustainable forest management

Over the past decades, there has been an increasing interest in the development of forest management approaches that are based on an understanding of historical natural disturbance dynamics. The rationale for such an approach is that management to favor landscape compositions and stand structures similar to those of natural ecosystems should also maintain biological diversity and essential ecological functions. In fire-dominated landscapes, this approach is possible only if current and future fire frequencies are sufficiently low, comparing to pre-industrial fire frequency, that we can substitute fire by forest management. We address this question by comparing current and future fire frequency to historical reconstruction of fire frequency from studies realized in the Canadian boreal forest. Current and simulated future fire frequencies using 2 and 3 x CO2 scenarios are lower than the historical fire frequency for many sites, suggesting that forest management could potentially be used to recreate the forest age structure of fire-controlled pre-industrial landscapes. There are however, important limitations to the current even-age management.     

Global change and the boreal forest: thresholds, shifting states or gradual change?

Changes in boreal climate of the magnitude projected for the 21st century have always caused vegetation changes large enough to be societally important. However, the rates and patterns of vegetation change are difficult to predict. We review evidence suggesting that these vegetation changes may be gradual at the northern forest limit or where seed dispersal limits species distribution. However, forest composition may be quite resilient to climate change in the central portions of a species range until some threshold is surpassed. At this point, changes can be rapid and unexpected, often causing a switch to very different ecosystem types. Many of these triggers for change are amenable to management, suggesting that our choice of policies in the coming decades will substantially influence the ecological and societal consequences of current climatic change.