Environmental Chemistry Letters - Rising energy needs and the exhaustion of fossil fuels are calling for renewable fuels such as dihydrogen (H2), commonly named 'hydrogen.' Biomass... 相似文献
Environmental Science and Pollution Research - Metabolic syndrome (MetS) is an immense health issue that causes serious complications in aging males including BPH. Icariin (ICA) is a flavonol... 相似文献
Environmental Science and Pollution Research - Azolla is a group of aquatic floating plants that can achieve very high growth rates compared to other aquatic macrophytes, with a doubling time of... 相似文献
Environmental Science and Pollution Research - The vertical distribution pattern and concentrations of elements (Fe, Al, Ca, Mg, Mn, Cr, Cu, Ni, Co, Pb, Zn, and As) in the estuarine and lagoon... 相似文献
East Africa has enormous renewable energy potential, but only a small portion of it has been exploited, and little is known on its role in improving environmental quality. Thus, this study empirically examines the impact of renewable energy on the environment using ecological footprint (EF; positive indicator) and CO2 emissions (negative indicator) as proxy indicators for environmental quality in a panel of ten East African countries from 1990 to 2015. These indicators were chosen due to their potential impact in the environment. The work used the pooled mean group (PMG) as the main panel estimator to determine the impact while controlling non-renewable energy consumption, GDP per capita, and foreign direct investment (FDI). PMG has been used as it forces the long-run coefficients to be equal across all panel groups. The findings show that in the long run, there is a significant negative relationship between CO2 emissions and renewable energy consumption, as well as a significant positive relationship (with a low impact) between EF and renewable energy consumption, suggesting that renewable energy use enhances the area’s environmental quality. Also, results indicate that non-renewable energy use degrades environmental quality in both metrics, whereas GDP degrades environmental quality through CO2 emissions and improves environmental quality through EF. This requires East African countries to focus a higher emphasis on accessible renewable energy sources to achieve quick and sustainable economic growth and minimize environmental effects. To accomplish this, strategic policies and legislation, as well as the promotion of green technology, are required.
Chlorine position of chlorophenol isomers has a significant effect on the dechlorination kinetics of monochlorophenols, dichlorophenols, and trichlorophenols during Fenton oxidation. The effects have been evaluated by the rate constants of the dechlorination kinetic model developed in this study. It is found that the dechlorination rate of 3-CP is faster than that of 4-CP, which is faster than that of 2-CP. Since OH and Cl groups on the aromatic ring are ortho and para directors, the directory effect of OH and Cl groups enhances the dechlorination kinetics of 2-CP due to acceleration of the hydroxylation of 2-CP. Therefore, the dechlorination kinetics increases accordingly. For trichlorophenols (TCP), steric hindrance plays an important role during their dechlorination process. Specifically, the closer the chlorine atoms locate with each other on the aromatic ring, the more difficult the dechlorination processes will be. The dechlorination kinetics of dichlorophenols seems to be affected by both directory effect of OH and Cl groups and the effect of steric hindrance of chlorine atoms. The directory effect of OH and Cl groups on trichlorophenols decreases since the chlorine atom occupied the positions which are the most favorable for hydroxyl radical attack. 相似文献
Waste incineration bottom ash and treated flue gas cleaning products mixed with 2.5% of cement (50 kg/m3) were tested in the laboratory in terms of compressive strength and tank leaching tests over a 64-day period. Although the material displayed lower mechanical strength than a reference concrete, the strength still was sufficient for use as a base layer for roads. The metal content in the incineration-residue-based specimens was up to 100 times higher than in the reference concrete, suggesting that the mixed waste incineration residue should be used only for dedicated purposes. The leaching of Cl and Na was increased by a factor of 20-100 from the incineration-residue-based specimens as compared to the reference, while the leaching of K, Ca and SO4 was increased by a factor of 2-10. The leaching of heavy metals was also higher from the incineration-residue-based specimens than from the reference with respect to Cu (50 times), Cd, Pb and Zn (5 times), but not with respect to Cr and Ni. The leaching curves did only allow for a closer evaluation of the leaching process in a few cases. The physical retention of the constituents seemed to be the same in the reference as in the incineration-residue-based specimens. Heavy metal leaching was limited by enhanced chemical retention in the incineration-residue-specimens as compared to the reference. Since no quality criteria in terms of leaching from a monolithic material are currently available, the leaching issue must be evaluated case by case. 相似文献
The corrosion layer on steel surfaces that formed after exposure to waste isolation pilot plant (WIPP) brines under anoxic conditions was characterized for chemical composition, thickness and phase composition. The chemical composition of the corrosion layer was determined both by X-ray photoelectron spectroscopy (XPS) and by chemical analysis of acid solutions used to remove the corrosion layer. Atomic force microscopic (AFM) images indicated that the brine-corroded surface layer shows extensive granulation along the contours of the steel surface that is characteristic of sharp polishing marks. The corrosion layer seemed to be porous and could be dissolved and detached in dilute hydrochloric acid. The corrosion layer appears to be composed of iron oxides with some ionic substitutions from the brines. The 77 K M?ssbauer spectrum recorded for iron powder leached under similar conditions indicated the corrosion layer was comprised principally of green rust. 相似文献
Urbanization impacts the stormwater regime through increased runoff volumes and velocities. Detention ponds and low impact development (LID) strategies may be implemented to control stormwater runoff. Typically, mitigation strategies are designed to maintain postdevelopment peak flows at predevelopment levels for a set of design storms. Peak flow does not capture the extent of changes to the hydrologic flow regime, and the hydrologic footprint residence (HFR) was developed to calculate the area and duration of inundated land during a storm. This study couples a cellular automata land cover change model with a hydrologic and hydraulic framework to generate spatial projections of future development on the fringe of a rapidly urbanizing metropolitan area. The hydrologic flow regime is characterized for existing and projected land cover patterns under detention pond and LID‐based control, using the HFR and peak flow values. Results demonstrate that for less intense and frequent rainfall events, LID solutions are better with respect to HFR; for larger storms, detention pond strategies perform better with respect to HFR and peak flow. 相似文献