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61.
Aydin Urucu Oya Yurtman Gündüz Zeynep Deniz Sabahattin Kok Yetimoglu Ece Aydin Adnan 《Environmental Chemistry Letters》2014,12(3):449-453
Gold is a valuable metal occurring usually at very low concentrations in complex natural samples. Gold analysis thus needs preconcentration methods. Classical liquid–liquid extraction involves hazardous organic solvents. Alternatively, cloud point extraction involves non-toxic and nonvolatile surfactants. Here, we analyzed ore samples. The complex of Au(III) with sulphapyridylazo resorcin was extracted by the cloud point method. Concentrations were measured by flame atomic absorption spectrometry. We tested the effects of pH, reagent concentration, Triton X-100 surfactant concentration, equilibration temperature and time. Results show that the best detection limit of the method was 0.48 µg L?1 for Au with a preconcentration factor of 31 times. Calibration is linear in range of 6.4–2,000 µg L?1, and relative standard deviations are lower than 5 %. Quantum chemical computations reveal the plausible structure of the gold–ligand complex. This report represents the first determination of gold using sulphapyridylazo resorcin as a ligand. 相似文献
62.
Use of the processed used tires in embankment construction is becoming an accepted way of beneficially recycling scrap tires due to shortages of natural mineral resources and increasing waste disposal costs. Using these used tires in construction requires an awareness of the properties and the limitations associated with their use. The main objective of this paper is to assess the different processing techniques on the mechanical properties of used tires–sand mixtures to improve the engineering properties of the available soil. In the first part, a literature study on the mechanical properties of the processed used tires such as tire shreds, tire chips, tire buffings and their mixtures with sand are summarized. In the second part, large-scale direct shear tests are performed to evaluate shear strength of tire crumb–sand mixtures where information is not readily available in the literature. The test results with tire crumb were compared with the other processed used tire–sand mixtures. Sand–used tire mixtures have higher shear strength than that of the sand alone and the shear strength parameters depend on the processing conditions of used tires. Three factors are found to significantly affect the mechanical properties: normal stress, processing techniques, and the used tire content. 相似文献
63.
Ceyla Güngör Hasan Serin Selahattin Serin Kadir Aydın 《International Journal of Green Energy》2015,12(1):98-105
The overall objective of this study was to explore the utility of waste plastics as a potential source of diesel fuel. An experimental study was conducted to evaluate the use of various blends of plastic oil produced from waste polyethylene (WPE) with diesel fuel (D). WPE was degraded thermally and catalytically using sodium aluminum silicate as a catalyst. The oil collected at optimum conditions (414°C–480°C range and 1 h reaction time) was fractionated at different temperatures and fuel properties of the fractions were measured. Plastic oil was blended with diesel fuel at the volumetric ratios of 5%, 10%, 15%, 20%, and 100%. Fuel properties of blends are found comparable with those of diesel fuel within the EN 590 Diesel Fuel standard and they can also be used as fuel in compression ignition engines without any modification. Engine performance and exhaust emission studies of 5% WPE-D (WPE5) blend were performed. Experimental results showed that carbon monoxide (CO) emission is decreased by 20.63%, carbon dioxide (CO2) emission is increased by 3.34%, and oxides of nitrogen (NOx) emission is increased by 9.17% with WPE-D (WPE5) blend compared to diesel fuel. 相似文献
64.
Yusuf Yavuz Reza Shahbazi A. Savaş Koparal Ülker Bakır Öğütveren 《Environmental science and pollution research international》2014,21(14):8603-8609
The aim of this study is the treatment of Basic Red 29 (BR29) dye solution using hybrid iron-aluminum electrodes by electrocoagulation and electro-Fenton methods. The effect of current density, initial pH, supporting electrolyte, H2O2, and initial dye concentration on dye removal efficiency was investigated, and the best experimental conditions were obtained. Time-coarse variation of UV-Vis spectra and toxicity and chemical oxygen demand (COD) removal were also examined at the best experimental conditions. Both systems were found very successful for the removal of BR29 dye. The removal efficiency of >95 % for BR29 dye solution was reached easily in a short time. At the best experimental conditions, for the initial BR29 concentration of 100 mg/L, >95 % BR29 dye and 71.43 % COD removal were obtained after 20 and 40 min of electrolysis, respectively. Additionally, toxicity results for electro-Fenton treatment of 100 mg/L BR29 were also very promising. According to the results obtained, although electro-Fenton is more effective, both systems can be used successfully to treat textile wastewater including dyes. 相似文献
65.
Can Cinar Duygu Ipci Emre Yılmaz Fatih Aksoy 《International Journal of Green Energy》2020,17(13):884-893
ABSTRACT Stirling engines maintain attraction because of their high energy conversion efficiencies. In this study, experimental comparison of a beta-type Stirling engine for two different rhombic-drive mechanisms was presented. In one of the rhombic mechanisms, spur gears were used and the gear shaft was supported in bearings from one side. In the other mechanism, two helical gears were placed on crankshafts and the crankshafts were supported in bearings from both sides. Rhombus lengths of the mechanisms were determined as 66 mm and 80 mm to provide same constant compression ratio of 2.5 for both configurations. Both mechanisms were used in the same beta-type Stirling engine having same cylinder, piston and displacer dimensions. Performance parameters of the engines were evaluated at different helium charge pressures (2–4 bar) and hot-end temperatures (400–600°C). The hot-end of the displacer cylinder was heated by a liquefied petroleum gas (LPG) burner. The engine power increased by 132%, friction losses and gear noses were reduced by supporting the rhombic-drive mechanism from both side and using helical gears. The maximum output torque and power of the engine were obtained as 13.14 Nm at 428 rpm engine speed and 663 W at 800 rpm engine speed, respectively, at 600°C hot-end temperature and 4 bar charge pressure. 相似文献
66.
Akpınar Süleyman Anlı Seher Taş 《Journal of Material Cycles and Waste Management》2023,25(4):2159-2170
Journal of Material Cycles and Waste Management - The present study investigated the potential of utilizing the cutting dust waste generated in the sizing process of volcanic tuff stones as an... 相似文献
67.
Demirel Bayık Gülçin Altın Ahmet 《Journal of Material Cycles and Waste Management》2023,25(1):376-388
Journal of Material Cycles and Waste Management - A lab-prepared cellulosic oil sorbent—used for oil spill cleanup—was pyrolyzed in a quartz, pipe-type horizontal furnace at different... 相似文献
68.
Pence Ihsan Kumaş Kazım Siseci Melike Cesmeli Akyüz Ali 《Environmental science and pollution research international》2023,30(9):22631-22652
Environmental Science and Pollution Research - In Turkey, facilities for the use of biomass resources in energy production are increasing, and new conversion facilities are commissioned every year... 相似文献
69.
Yılmaz Şakir Zengin Adem Akbulut Yeliz Şahan Tekin 《Environmental science and pollution research international》2019,26(20):20454-20468
Environmental Science and Pollution Research - In the present study, a poly (vinylbenzyl chloride) grafted Fe3O4 nanoparticle (Fe3O4@PVBC) was prepared by surface-initiated reversible addition... 相似文献
70.
Erman Çakıt 《International journal of occupational safety and ergonomics》2018,24(2):286-293
This study aimed to (a) evaluate strength requirements and lower back stresses during lifting and baggage handling tasks with the 3D Static Strength Prediction Program (3DSSPP) and (b) provide additional analyses using rapid entire body assessment (REBA) and the NASA task load index (TLX) to assess the risks associated with the tasks. Four healthy female shuttle drivers of good health aged between 55 and 60 years were observed and interviewed in an effort to determine the tasks required of their occupations. The results indicated that lifting bags and placing them in a shuttle were high risk for injury and possible changes should be further investigated. The study concluded there was a potential for injury associated with baggage storing and retrieval tasks of a shuttle driver. 相似文献