• Isotope dilution method was developed for the determination of 27 PPCPs in water.• The established method was successfully applied to different types of water samples.• The correction effect of corresponding 27 ILSs over 70 d was investigated.• Benefit of isotopic dilution method was illustrated for three examples. Pharmaceuticals and personal care products (PPCPs) are a unique group of emerging and non-persistent contaminants. In this study, 27 PPCPs in various water samples were extracted by solid phase extraction (SPE), and determined by isotope dilution method using liquid chromatography coupled to tandem triple quadruple mass spectrometer (LC-MS/MS). A total of 27 isotopically labeled standards (ILSs) were applied to correct the concentration of PPCPs in spiked ultrapure water, drinking water, river, effluent and influent sewage. The corrected recoveries were 73%–122% with the relative standard deviation (RSD)<16%, except for acetaminophen. The matrix effect for all kinds of water samples was<22% and the method quantitation limits (MQLs) were 0.45–8.6 ng/L. The developed method was successfully applied on environmental water samples. The SPE extracts of spiked ultrapure water, drinking water, river and wastewater effluent were stored for 70 days, and the ILSs-corrected recoveries of 27 PPCPs were obtained to evaluate the correction ability of ILSs in the presence of variety interferences. The recoveries of 27 PPCPs over 70 days were within the scope of 72%–140% with the recovery variation<37% in all cases. The isotope dilution method seems to be of benefit when the extract has to be stored for long time before the instrument analysis. 相似文献
Environmental Science and Pollution Research - In this study, the immature mice were taken to assess the potential neurological toxicity of lead (Pb) and di (n-butyl) phthalates (DBP) combination... 相似文献
Environmental Science and Pollution Research - The Yellow River Basin is an energy-rich area. The low-carbon development of the Yellow River Basin is one of the ways to achieve ecological... 相似文献
China’s large population and deteriorating environment have created great concern related to the sustainability of food production, especially since details related to this topic remain poorly studied. Thus, an integrated analysis of both crop yield and cultivated area is essential for gaining a better understanding of cereal grain production in China and for making corresponding policies designed to achieve food security. In this study, we adopt trend analysis of both provincial yield and cultivated area to assess the subsequent provincial-level cereal production sustainability between 1980 and 2011 with the goal of providing a better understanding of regional agricultural development. The results indicate that while maize shows the most promise for yield improvement, rice and wheat production is experiencing substantial yield stagnation among most provinces across mainland China. In addition, the trends in spatial patterns are prominently different from those of yields. The sizes of the main rice- and wheat-growing areas in China have declined greatly, suggesting that the related production of these cereals should attract more attention from land management planners and farmers. Specifically, the south-eastern coastal provinces have largely failed to sustain both crop yield and area, while the north-eastern provinces have witnessed thriving agricultural production during the last three decades. Moreover, we find that cereal production in China is significantly affected by governmental policies related to the agricultural sector. Thus, this analysis of food production in China will help policymakers to better understand how the potential implications of food security in China may be applicable to countries worldwide. 相似文献
Fresh leachate, generated in municipal solid waste incineration (MSWI) plants, contains various pollutants with extremely high strength organics, which usually requires expensive and complex treatment processes. This study investigated the feasibility of blending treatment of MSWI leachate with municipal wastewater. Fresh MSWI leachate was pretreated by coagulation–flocculation with FeCl3 2 g/L and CaO 25 g/L, plate-and-frame filter press, followed by ammonia stripping at pH above 12. After that, blending treatment was carried out in a full-scale municipal wastewater treatment plant (WWTP) for approximately 3 months. Different operational modes consisting of different pretreated leachate and methanol addition levels were tested, and their performances were evaluated. Results showed that throughout the experimental period, monitored parameters in the WWTP effluent, including COD (<60 mg/L), BOD5 (<20 mg/L), ammonium (<8 mg/L), phosphorus (<1.5 mg/L) and heavy metals, generally complied with the Chinese sewage discharged standard. Under the experimental conditions, a certain amount of methanol was needed to fulfill TN removal. An estimation of the operation cost revealed that the expenditure of blending treatment was much lower than the total costs of respective treatment of MSWI leachate and municipal wastewater. The outcomes indicated that blending treatment could not only improve the treatability of the MSWI leachate, but also reduce the treatment cost of the two different wastewaters. 相似文献
Environmental Science and Pollution Research - Groundwater pollution seriously threatens water resource safety due to high-intensity land use throughout the world. However, the relationship between... 相似文献
Environmental Science and Pollution Research - In this study, the degradation performance of nutrients in zeolite trickling filter (ZTF) with different influent C/N ratios and aeration conditions... 相似文献
Nanoplastics are widely distributed in freshwater environments, but few studies have addressed their effects on freshwater algae, especially on harmful algae. In this study, the effects of polystyrene (PS) nanoplastics on Microcystis aeruginosa (M. aeruginosa) growth, as well as microcystin (MC) production and release, were investigated over the whole growth period. The results show that PS nanoplastics caused a dose-dependent inhibitory effect on M. aeruginosa growth and a dose-dependent increase in the aggregation rate peaking at 60.16% and 46.34%, respectively, when the PS nanoplastic concentration was 100 mg/L. This caused significant growth of M. aeruginosa with a specific growth rate up to 0.41 d?1 (50 mg/L PS nanoplastics). After a brief period of rapid growth, the tested algal cells steadily grew. In addition, the increase in PS nanoplastics concentration promoted the production and release of MC. When the PS nanoplastic concentration was 100 mg/L, the content of the intracellular (intra-) and extracellular (extra-) MC increased to 199.1 and 166.5 μg/L, respectively, on day 26, which was 31.4% and 31.1% higher, respectively, than the control. Our results provide insights into the action mechanism of nanoplastics on harmful algae and the potential risks to freshwater environments.