菲和铬(Ⅵ)单一及复合暴露对土壤微生物多样性的影响

有机物和重金属已成为我国土壤环境中常见的2类污染物质,二者间复合污染引起的土壤生态环境风险不容忽视。本研究以多环芳烃模式物菲和典型重金属铬(VI)作为受试物质,采用PCR-DGGE分子指纹图谱技术,探讨这2种污染物单一及复合暴露对土壤微生物群落多样性的影响,并选用主成分分析、聚类分析和戴斯系数3种算法对微生物群落相似性进行了比较。结果表明,在暴露实验第1天,菲单一暴露低浓度组中微生物群落相似性产生了极为明显的变化,而到第7天时,菲和铬(VI)单一暴露高浓度组均对微生物群落结构相似性产生最大程度的影响;采用香农指数法评价微生物群落的多样性,发现在暴露实验第7天,菲和铬(VI)单一暴露高浓度组对微生物群落多样性的影响比复合暴露高浓度组更强,二者复合暴露的相互作用方式表现为拮抗效应。本研究证明低浓度菲短期暴露的效应高于高浓度暴露结果,因而多环芳烃菲自身及其在复合暴露中所扮演的角色尤其值得关注。     

基于Duane曲线的可靠性增长模型

在阐述复杂武器装备系统在研制中,通常要经过实验——分析——改进的过程,即可靠性增长过程。由于产品处于改进阶段,每个阶段的产品的寿命所对应的总体就是不同的。因此估计最后阶段的可靠度及其置信限就有了一定的困难,讨论基于Duane曲线的指数可靠性增长模型——ERG模型。完全寿命方案下,给出了利用枢轴量构建置信限的推断方法,并证明了构建的置信限具有最优性。     

基于5G技术的配网差动保护应用

差动保护具有良好的可靠性、选择性和速动性,但受制于保护通道的建设,差动保护在配电网中仍未被广泛使用。本文介绍了1种基于5G技术的配网差动保护,利用5G技术实现差动保护数据交互,有效解决了配网差动保护通道建设难题。现场测试表明,差动保护可依托5G网络实现信息交互,但交互时延不稳定是制约实际应用的关键问题。     

宁东地区660MW机组锅炉燃煤掺烧试验研究

宁东地区某燃煤发电厂由于燃用的设计煤种供应紧张,急需掺烧经济性较好的非设计煤种来改善经营状况,但是,燃用非设计煤种可能会导致锅炉设备的安全无法保障,锅炉运行经济性降低和污染物排放量发生明显变化,因此需要进行相应的混煤掺烧试验研究。本文通过选取合适且经济的煤种与电厂常规设计煤种进行掺烧试验,全面分析混煤掺烧对锅炉设备安全性、经济性和环保性的影响,为电厂扩大煤种适应性范围提供决策依据。     

灌浆套筒连接预制拼装桥墩抗剪性能对比试验研究

灌浆套筒连接预制拼装桥墩抗弯性能得到了广泛研究,但抗剪性能研究较少.为对比分析灌浆套筒连接预制拼装桥墩抗剪性能,制作了2个相同缩尺比的现浇和预制拼装桥墩模型.通过拟静力方式测到了两类结构极限承载力、变形和耗能能力等抗震性能指标.对比分析结果表明,预制桥墩与现浇桥墩破坏模式存在显著差异,但是预制桥墩具备与现浇桥墩相近的耗...     

Nonlinear and competitive sorption of apolar compounds in black carbon-free natural organic materials

Numerous studies have reported a spectrum of sorption phenomena in soils, sediments, and organic matter isolates of those materials that are inconsistent with a partition model proposed in the late 1970s and early 1980s, a model predicated on a hypothesis that sorption is linear and noncompetitive. To explain these nonideal phenomena, prior studies have proposed a hard-soft (glassy-rubbery) model for SOM (soil and sediment organic matter), while others have attributed them singularly to BC (black carbon: soot and charcoal) particles present in topsoils and sediments. In this study, we demonstrated nonideal sorption behavior (isotherm nonlinearity, competitive effects) for a group of apolar compounds in a large set of natural and model organic materials, including a commercial lignin and humic acids from different sources. Complete oxidation of samples by an acidic dichromate method was taken to signify the absence of BC. (However, polymethylene units are stable even if functionalized on both ends, making the technique unreliable for quantifying BC.) Other samples were inferred free of BC by their source and method of preparation. Characterization by thermalanalytical methods indicated the glassy character of the organic materials. The origin of the nonideal behaviors appears to be the glassy character of these materials. Sorption nonlinearity increased or decreased by changing temperature, cosolvent content, or degree of cross-linking by metal ions as predicted for organic solids in a glassy state. We conclude that macromolecular humic substances in the environment may exhibit nonideal sorption behavior in soils and sediments, quite apart from any such behaviors attributable to BC.     

饮用水砷污染治理研究进展

简述了饮用水中砷污染的来源和危害,砷在水环境的存在形态和毒性,分析了当前饮用水不同除砷方法的研究进展。     

最优环境工程方案遴选模型的建立与应用

根据层次分析法的原理,建立了遴选最优环境工程方案的层次结构模型。模型兼顾了效益与投资,不仅简化了专家或决策者的判断难度,而且判断结果直观,各方案的优劣对比清晰。给合某啤酒废水治理工程项目,介绍了层次分析模型应用于工程方案遴选中的计算过程。结果表明,应用此模型对环境工程方案进行优选比较科学、简便。     

Combined toxicity of three chlorophenols 2,4-dichlorophenol, 2,4,6-trichlorophenol and pentachlorophenol to Daphnia magna

The toxicity of single and combined mixtures of 2,4-dichlorophenol (2,4-DCP), 2,4,6-trichlorophenol (2,4,6-TCP), and pentachlorophenol (PCP) to Daphnia magna was studied. The toxicity ranking of these three single chlorophenols (CPs) to Daphnia magna was PCP > 2,4-DCP > 2,4,6-TCP. The toxic units (TU) approach was used to estimate the combined effects in experiments, the median effective concentration (EC(50)) values were 0.87-1.21 and 0.46-0.59 for binary and ternary mixtures, respectively. Response surface models of General Linear Models (R(2) > 0.90, residual deviation < 3.25) were established for all three binary mixtures. The toxicity for ternary mixtures based on the EC(50)-value and 10% effective concentration (EC(10))-value fixed mixture ratio presented a synergism. The risk based on the single CP's toxicity test may be underestimated. In addition, four approaches (concentration addition, toxicity equivalency factors, effect summation, and independent action) were used for the calculation of combined effects of the mixture. The experimental results showed that concentration addition and toxicity equivalency factor approaches were effective methods for calculation of additive effects of mixtures from binary systems of CPs; while independent action and effect summation (low simulated tail) predicted lower toxicity than experimental results. Limitations of the traditional focus on the effects of single agents were highlighted; hazard assessments ignoring the possibility of joint action of CPs will almost certainly lead to significant underestimations of risk.     

生物炭在土壤中的老化及其吸附重金属的研究进展

综述了生物炭在土壤中的老化机制及主要影响因素方面的研究进展,指出生物炭的理化性质和结构表征在土壤中发生变化是其老化机制,生物炭的特性、土壤特性和环境条件等因素共同影响着生物炭的老化。总结了老化生物炭在土壤中对重金属吸附的影响,生物炭在老化过程中理化性质和结构表征的变化影响了生物炭-土壤体系对重金属的吸附,并且吸附能力因老化方式和重金属不同而存在差异。提出了开展多种重金属共存条件下老化生物炭的吸附效果和机理研究、针对生物炭田间实际老化过程对土壤重金属的吸附行为开展季节性和多年长期观测研究,以及对生物炭修复的重金属污染土壤在生物炭老化过程中可能造成的环境和健康风险开展综合、长期的跟踪研究与评估等展望。