Increasing chloride concentration causes retention of mercury in melted Arctic snow due to changes in photoreduction kinetics

Mercury(Hg) in the Arctic is a significant concern due to its bioaccumulative and neurotoxic properties, and the sensitivity of Arctic environments. Previous research has found high levels of Hg in snowpacks with high chloride(Cl~-) concentrations. We hypothesised that Cl~- would increase Hg retention by decreasing Hg photoreduction to Hg(0) in melted Arctic snow. To test this, changes in Hg photoreduction kinetics in melted Alert, NU snow were quantified with changing Cl~- concentration and UV intensity. Snow was collected and melted in Teflon bottles in May 2014, spiked with 0–10 μg/g Cl~-, and irradiated with 3.52–5.78 W·m~(-2) UV(280–400 nm)radiation in a Luz Chem photoreactor. Photoreduction rate constants(k)(0.14–0.59 hr~(-1)) had positive linear relationships with [Cl~-], while photoreduced Hg amounts(Hg(Ⅱ)_(red)) had negative linear relationships with [Cl~-](1287–64 pg in 200 g melted snow). Varying UV and[Cl~-] both altered Hg(Ⅱ)_(red) amounts, with more efficient Hg stabilisation by Cl~- at higher UV intensity, while k can be predicted by Cl- concentration and/or UV intensity, depending on experimental parameters. Overall, with future projections for greater snowpack Cl~- loading,our experimental results suggest that more Hg could be delivered to Arctic aquatic ecosystems by melted snow(smaller Hg(Ⅱ)_(red) expected), but the Hg in the melted snow that is photoreduced may do so more quickly(larger k expected).     

Disentangling technological innovations: a micro-econometric analysis of their determinants

On the basis of a unique firm-level dataset from the German manufacturing sector, this paper empirically examines the determinants of environmental and non-environmental product and process innovations. The micro-econometric analysis with multivariate probit models points to an extremely high relevance of R&D activities for all technological innovation types, as well as to the relevance of a few market pull factors. The estimation results additionally reveal the importance of organisational measures for environmental product and process innovations. In this regard, not only certified environmental management systems, but also specific process- and product-related environmental organisational measures and even general organisational measures, such as the certification of a quality management system according to ISO 9001, play a crucial role. The estimation results therefore suggest the encouragement of firm-internal R&D activities and organisational measures by (environmental) policy in order to stimulate environmental technological innovations, which are able to both limit the environmental burden and contribute to the technological modernisation of the economy.     

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Negotiating weights for burden sharing rules in international climate negotiations: an empirical analysis

Environmental Economics and Policy Studies - We have collected data from a world-wide survey among COP delegates to empirically investigate preferences for certain burden sharing rules among key...