The use of 'exotic' framework structures in waste management

The use of porous framework materials in waste management applications has the potential to be a powerful tool in toxic metal remediation. The properties that these materials possess, including high surface area and ion-exchange capacity, are theoretically valuable. Furthermore, the flexibility of many of these frameworks allows the potential for immobilisation of waste materials with the framework of the material, in addition to the traditional capture in the pore structure. However, for either of these routes to be useful for waste management purposes, these structures must also be stable in any proposed storage media. This study examines the stability of a range of porous materials whose frameworks are made out of zinc and arsenic, both considered toxic minesite wastes, when exposed to aqueous media. The three frameworks examined (sodalite analogue Na(6)(H(2)O)(8)(ZnAsO(4))(6), open framework K(3)Zn(4)O(AsO(4))(3).3.5H(2)O, and an ABW type framework NH(4)ZnAsO(4)) all have similar hydrothermal synthetic routes and bulk framework compositions, but differ in counter ion used, pore size and complexity of structure. The phases were examined before and after storage in an aqueous environment, and their crystallinity and leaching were determined. All phases prepared were found to be extremely unstable outside their original synthetic environment, and very soluble when exposed to water, calling into question their practical use in any environment.     

Methane yield in source-sorted organic fraction of municipal solid waste

Treating the source-separated organic fraction of municipal solid waste (SS-OFMSW) by anaerobic digestion is considered by many municipalities in Europe as an environmentally friendly means of treating organic waste and simultaneously producing methane gas. Methane yield can be used as a parameter for evaluation of the many different systems that exist for sorting and pre-treating waste. Methane yield from the thermophilic pilot scale digestion of 17 types of domestically SS-OFMSW originating from seven full-scale sorting systems was found. The samples were collected during 1 year using worked-out procedures tested statistically to ensure representative samples. Each waste type was identified by its origin and by pre-sorting, collection and pre-treatment methods. In addition to the pilot scale digestion, all samples were examined by chemical analyses and methane potential measurements. A VS-degradation rate of around 80% and a methane yield of 300-400Nm(3) CH(4)/ton VS(in) were achieved with a retention time of 15 days, corresponding to approximately 70% of the methane potential. The different waste samples gave minor variation in chemical composition and thus also in methane yield and methane potential. This indicates that sorting and collection systems in the present study do not significantly affect the amount of methane produced per VS treated.     

U(VI) adsorption on aquifer sediments at the Hanford Site

Aquifer sediments collected via split-spoon sampling in two new groundwater wells in the 200-UP-1 operable unit at the Hanford Site were characterized and showed typical Ringold Unit E Formation properties dominated by gravel and sand. High iron-oxide content in Fe oxide/clay coatings caused the highest U(VI) adsorption as quantified by batch K(d) values, indicating iron oxides are the key solid adsorbent in the 200-UP-1 sediments that affect U(VI) fate and mobility. Even though U(VI) adsorption on the gravel-sized fraction of the sediments is considered to be negligible, careful characterization should be conducted to determine U(VI) adsorption on gravel, because of presence of Fe oxides coatings and diffusion-controlled adsorption into the gravel particles' interior surfaces. A linear adsorption isotherm was observed up to 10(-6) M (238 microg/L) of total U(VI) concentration in batch U(VI) adsorption tests with varying total U(VI) concentrations in spiked groundwater. U(VI) adsorption decreased with increasing concentrations of dissolved carbonate, because strong anionic aqueous uranium-carbonate complexes formed at high pH and high alkalinity conditions. Noticeable uranium desorption hysteresis was observed in a flow-through column experiment, suggesting that desorption K(d) values for aged uranium-contaminated sediments at the Hanford Site can be larger than adsorption K(d) values determined in short-term laboratory experiments and slow uranium release from contaminated sediments into the groundwater is expected.     

Mining taxation issues for the future

During the 1970s and 1980s the main concern of mining policies was to attract investment whilst at the same time balancing the interests of governments and companies. By the turn of the century a new spectrum of challenges faces governments and companies in the mining sector. The need for fiscal regimes to adapt to price cyclicity is to some extent superseded by the requirement that they adapt to a long-term decline of metal prices. The growing importance of environmental and community affairs in the mining sector will force governments to design coherent and comprehensive tax regulations to complement the wide range of initiatives being taken in these fields. Finally, the age-old problem of tax collection continues to raise its head in transition and developing economies.     

DEVELOPING CONFIDENCE IN CONCRETE REVETMENT PRODUCTS FOR BANK STABILIZATION1

ABSTRACT: There is a need to provide flood protection while maintaining stable bed and bank conditions in the riverine system, to stabilize earth embankment dams and spiliways, and to stabilize highway or railway embankments and levee systems. One approach to providing erosion protection and stabilization of channel banks, embankments and spill conveyances is with articulated concrete block systems. Numerous articulated concrete block systems are available for bank stabilization. However, prior to field installations few means are available to evaluate how well these block systems perform. To assist the designer in predicting site specific suitability, a series of hydraulic testing protocols have been developed to analyze block system performance. Two articulated block system testing protocols are presented to indicate how block hydraulic characteristics may be determined and provide performance assurance to both the designer and the owner.     

WEATHER AND CLIMATE EXTREMES,CLIMATE CHANGE,AND PLANNING: Views of Community Water System Managers in Pennsylvania's Susquehanna River Basin1

ABSTRACT: This research examines the sensitivity and vulnerability of community water systems (CWSs) to weather and climate in the Pennsylvania portion of the Susquehanna River Basin. Three key findings emerge from a survey of 506 CWS managers. First, CWSs are sensitive to extreme weather and climate, but that sensitivity is determined more by type of system than system size. CWSs that rely partly or wholly on surface water face more disruptions than do groundwater systems. Larger systems have more problems with flooding, and size is not a significant determinant of outages from storms or disruptions from droughts. Second, CWS managers are unsure about global warming. Few managers dismiss global warming; most think global warming could be a problem but are unwilling to consider it in their planning activities until greater scientific certainty exists. Third, the nature of the CWS, its sensitivity to weather and climate, and projected risks from weather and climate are insignificant determinants of how managers plan. Experienced, full-time managers are more likely to consider future weather and climate scenarios in their planning, while inexperienced and part-time managers are less likely to do so. Implications of these findings include support for efforts to move away from surface water, for clear communication of climate change information, and for the hiring and retention of full-time professional CWS managers.     

Centrifugal Bioreactors and Their Application in Remediation

A new approach to the maintenance of large microbial populations for bioremediation purposes has been developed in which a centrifugal bioreactor is used to immobilize microbial populations at extremely high density. The cells are ordered into a three‐dimensional array through which wastewater or groundwater volumes may be flowed, unimpeded by frits or screens. The process methodology is independent of the type, shape, or viability of the individual cells immobilized and, thus, may be adapted to many different bioremediation needs. The utilization of this new process has been explored for three different types of remediation: the removal of heavy metals from wastewater, the aerobic degradation of methyl‐tert‐butyl ether (MTBE), and the anaerobic reduction of nitrate to nitrogen gas. This article discusses the use of centrifugal bioreactors and their application in remediation. © 2001 John Wiley & Sons, Inc.