Preliminary comparison of alternative designs for soil remediation by bioventilation

Computer simulation provides a powerful tool for comparing alternative designs of remediation processes. The software package FLUENT copes successfully with subsurface three-dimensional flow fields, multiple and directional permeabilities, wide spatial variations in subsurface gas velocities, and the presence of surface structures. FLUENT can provide an invaluable method for comparing remediation efficiencies among competing design alternatives. This article features case studies to illustrate the benefits that simulation studies provide before and during the initiation of remedial actions using bioventing.     

From place to emplacement: the scalar politics of sustainability

ABSTRACT

Sustainability has emerged as a central concept for discussing the current state of the human-environment system and planning for its future. To delve into the depths of sustainability means to talk about ecology, economy, and equity as fundamentally interconnected. However, each continues to be colonised by normative epistemologies of ecological sciences, neoclassical economics, and development, suggesting that with enough science and development, a more equitable sustainability is achievable. In our analysis, place emerges as an alternative epistemology through which to analyze sustainability. Place exists at multiple spatial and temporal scales, understood through direct observation of boundaries, processes and patterns, phenomenologically through individual experience, and as a complex hybrid: always emerging through interactions among individuals and institutions. Despite the ubiquity of place in the socio-ecological literature, the complexity of place in relation to sustainability is under-theorised, and in as much as sustainability happens or does not happen in real places rather than in policies and models, a place-based sustainability framework is necessary to move forward. To address this gap, we developed the emplacement framework, consisting of four domains: displacement, misplacement, replacement, and emplacement. Each domain is dynamic, constructing place as praxis, and reframing sustainability as a site of collective inquiry and choices. Our goal is to facilitate the active and on-going practices of place-based research and engagement among scholars, activists, and other community members by providing a structure for transdisciplinary dialogue and the application of transdisciplinary research to enable better decision-making.     

ROLE OF CARBONATE ROCKS IN MODIFYING FLOOD FLOW BEHAVIOR1

ABSTRACT. The interrelationships between the runoff characteristics of watersheds (expressed as the mean annual flood), standard basin parameters (area, drainage properties, and relief), and the parameters which describe the solutional modification of the basins (carbonate rock fractions, sinkhole development, and measures of internal drainage) were used to group 62 carbonate watersheds. Simple binary correlations were obtained by direct plotting of the data. This was followed by multivariate analyses: factor and cluster analyses. Following the cluster analysis, which separated the basins into three groups, the variance within each group was examined again by binary correlations and by factor analysis. Prediction equations for those basins underlain by dolomite rock [QBAR = 12.4 TOT^1.01] and for those basins underlain by carbonate rock with very little surface expression [QBAR = 43.5 TOT^0.87] were proposed. Basins underlain by karstic limestone had a large amount of variance within the data set; therefore no prediction equation could be obtained. (QBAR = mean annual flood, cfs; TOT = total length of all blue lines shown on topographic maps, miles.)     

GLYPHOSATE, OTHER HERBICIDES, AND TRANSFORMATION PRODUCTS IN MIDWESTERN STREAMS, 20021

ABSTRACT: The use of glyphosate has increased rapidly, and there is limited understanding of its environmental fate. The objective of this study was to document the occurrence of glyphosate and the transformation product aminomethylphosphonic acid (AMPA) in Midwestern streams and to compare their occurrence with that of more commonly measured herbicides such as acetochlor, atrazine, and metolachlor. Water samples were collected at sites on 51 streams in nine Midwestern states in 2002 during three runoff events: after the application of pre-emergence herbicides, after the application of post-emergence herbicides, and during harvest season. All samples were analyzed for glyphosate and 20 other herbicides using gas chromatography/mass spectrometry or high performance liquid chromatography/mass spectrometry. The frequency of glyphosate and AMPA detection, range of concentrations in runoff samples, and ratios of AMPA to glyphosate concentrations did not vary throughout the growing season as substantially as for other herbicides like atrazine, probably because of different seasonal use patterns. Glyphosate was detected at or above 0.1 μg/1 in 35 percent of pre-emergence, 40 percent of post-emergence, and 31 percent of harvest season samples, with a maximum concentration of 8.7 μg/1. AMPA was detected at or above 0.1 μg/1 in 53 percent of pre-emergence, 83 percent of post-emergence, and 73 percent of harvest season samples, with a maximum concentration of 3.6 μg/1. Glyphosate was not detected at a concentration at or above the U.S. Environmental Protection Agency's maximum contamination level (MCL) of 700 μg/1 in any sample. Atrazine was detected at or above 0.1 μg/1 in 94 percent of pre-emergence, 96 percent of post-emergence, and 57 percent of harvest season samples, with a maximum concentration of 55 μg/1. Atrazine was detected at or above its MCL (3 μg/1) in 57 percent of pre-emergence and 33 percent of post-emergence samples.     

Foraminifera as bioindicators in coral reef assessment and monitoring: the FORAM Index. Foraminifera in Reef Assessment and Monitoring

Coral reef communities are threatened worldwide. Resource managers urgently need indicators of the biological condition of reef environments that can relate data acquired through remote-sensing, water-quality and benthic-community monitoring to stress responses in reef organisms. The FORAM (Foraminifera in Reef Assessment and Monitoring) Index (FI) is based on 30 years of research on reef sediments and reef-dwelling larger foraminifers. These shelled protists are ideal indicator organisms because: Foraminifers are widely used as environmental and paleoenvironmental indicators in many contexts; Reef-building, zooxanthellate corals and foraminifers with algal symbionts have similar water-quality requirements; The relatively short life spans of foraminifers as compared with long-lived colonial corals facilitate differentiation between long-term water-quality decline and episodic stress events; Foraminifers are relatively small and abundant, permitting statistically significant sample sizes to be collected quickly and relatively inexpensively, ideally as a component of comprehensive monitoring programs; and Collection of foraminifers has minimal impact on reef resources.USEPA guidelines for ecological indicators are used to evaluate the FI. Data required are foraminiferal assemblages from surface sediments of reef-associated environments. The FI provides resource managers with a simple procedure for determining the suitability of benthic environments for communities dominated by algal symbiotic organisms. The FI can be applied independently, or incorporated into existing or planned monitoring efforts. The simple calculations require limited computer capabilities and therefore can be applied readily to reef-associated environments worldwide. In addition, the foraminiferal shells collected can be subjected to morphometric and geochemical analyses in areas of suspected heavy-metal pollution, and the data sets for the index can be used with other monitoring data in detailed multidimensional assessments.     

Quality design: a planning methodology for the integration of refugee and local health services,West Nile,Uganda

In an emergency, the international community responds to the immediate health needs of refugees through the establishment of action-oriented, life-saving services. Healthcare delivery is often managed with limited, if any, coordination with local health management structures. In situations where refugees remain in the host country for many years, sustainability issues inevitably arise. Refugee-hosting governments may ultimately be called upon to assume the management and funding of refugee services. Planning for service integration, while protecting against declines in service quality, is a challenge in the typically resource-poor host environments. This paper discusses these issues by presenting the experience of the West Nile districts in northern Uganda, and describes quality design as a relevant planning methodology. Quality design is a systematic planning approach that documents and directly incorporates the service users' self-defined expectations and needs.     

Fuzzy decision analysis for integrated environmental vulnerability assessment of the mid-Atlantic Region

A fuzzy decision analysis method for integrating ecological indicators was developed. This was a combination of a fuzzy ranking method and the analytic hierarchy process (AHP). The method was capable of ranking ecosystems in terms of environmental conditions and suggesting cumulative impacts across a large region. Using data on land cover, population, roads, streams, air pollution, and topography of the Mid-Atlantic region, we were able to point out areas that were in relatively poor condition and/or vulnerable to future deterioration. The method offered an easy and comprehensive way to combine the strengths of fuzzy set theory and the AHP for ecological assessment. Furthermore, the suggested method can serve as a building block for the evaluation of environmental policies.     

Modeling human-induced climatic change: A summary for environmental managers

The rapid increase in atmospheric concentrations of greenhouse gases has caused concern because of their potential to alter the earth's radiation budget and disrupt current climate patterns While there are many uncertainties associated with use of general circulation models (GCMs), GCMs are currently the best available technology to project changes in climate associated with elevated gas concentrations. Results indicate increases in global temperature and changes in global precipitation patterns are likely as a result of doubled CO₂. GCMs are not reliable for use at the regional scale because local scale processes and geography are not taken into account. Comparison of results from five GCMs in three regions of the United States indicate high variability across regions and among models depending on season and climate variable. Statistical methods of scaling model output and nesting finer resolution models in global models are two techniques that may improve projections. Despite the many limitations in GCMs, they are useful tools to explore climate-earth system dynamics when used in conjunction with water resource and ecosystem models. A variety of water resource models showed significant alteration of regional hydrology when run with both GCM-generated and hypothetical climate scenarios, regardless of region or model complexity. Similarly, ecological models demonstrate the sensitivity of ecosystem production, nutrient dynamics, and distribution to changes in climate and CO₂ levels. We recommend the use of GCM-based scenarios in conjunction with water resource and ecosystem models to guide environmental management and policy in a “no-regrets” framework or as part of a precautionary approach to natural resource protection.     

REGIONAL RAINFALL INTENSITY-DURATION-FREQUENCY CURVES FOR PENNSYLVANIA1

ABSTRACT: A statistical analysis of all available continuous hourly and 15-minute duration rainfall records for Pennsylvania was performed to develop an updated procedure to estimate design storms. As a resuit of this study, Pennsylvania was divided into five homogeneous rainfall regions and a set of rainfall intensity-duration curves developed for each region, for return periods of 1 to 100 years and durations ranging from 5 minutes to 24 hours. The PDT-IDF curves were judged to be a better representation of Pennsylvania rainfall than the nationwide TP-40 maps, particularly for storm events of 10-years and lower return periods. The average time distribution of 24-hour storms in Pennsylvania was found to be well represented by the SCS Type II distribution. The Corps of Engineers SPS 24-hour distribution was found to differ appreciably from both the SCS Type H and the Pennsylvania 24-hour storm distribution. For storm durations between 15 and 90 minutes the standard Yarnell intensity-duration curves closely resemble Pennsylvania storm distributions.     

Phthalate and alkyl phenol concentrations in soil following applications of inorganic fertiliser or sewage sludge to pasture and potential rates of ingestion by grazing ruminants

Soil concentrations of dioctyl phthalate (DOP) and the alkyl phenols, octyl phenol (OP) and nonyl phenol (NP), after repeated surface applications of sewage sludge to pastures, were investigated. Liquid sludge was applied at a rate of 2.25 tonnes dry matter (DM) per hectare to each of three treated (T) plots on three occasions during the summer and two occasions in the early spring over a period of 2.5 years. Control (C) plots were treated with inorganic fertiliser containing amounts of nitrogen equivalent to those applied to the treated plots. At between 69 and 81 days after the application of sludge, 15 separate soil samples were collected from one half of each of the plots (Experiment 1). Concentrations (microg g(-1)) of DOP were higher (P < 0.001) than those of NP, while those of OP were generally below detectable levels. Mean soil concentrations of DOP were not significantly different in T and C plots [0.233 vs. 0.155 microg g(-1); standard error of the difference (SED) = 0.046; not significant (NS)], partly because there was already a relatively large amount of DOP present. NP concentrations were, however, significantly higher in T than in C plots (0.021 vs. 0.013 microg g(-1) SED = 0.002; P < 0.05). There was no consistent change over time in the mean soil concentrations of these compounds when sampled at intervals of 3-6 months. Concentrations in soil samples collected at monthly intervals following sludge application indicated that the variation in concentrations of these endocrine-disrupting compounds (EDC) was unrelated to time since sludge application. Rates of soil ingestion, expressed as the percentage of DM intake represented by soil, were higher during the winter than the summer (5.40 vs. 1.17; SED = 0.360; P < 0.001) and estimated daily intakes of DOP and NP were up to 150 microg and 8 microg, respectively. It is concluded that the application of sewage sludge to pasture does not increase soil concentrations of phthalate (as DOP) or alkyl phenols. Thus, the risk of increased exposure to these EDC as a result of sludge application is small. However, the small effect of sludge application on soil concentrations may be largely a reflection of the relatively high concentrations of DOP already present in the soil, which may be biologically significant.