Adsorption of antimony(V) by floodplain soils, amorphous iron(III) hydroxide and humic acid

Antimony (Sb) emissions to the environment are increasing, and there is a dearth of knowledge regarding Sb fate and behaviour in natural systems. In particular, there is a lack of understanding of sorption of the oxidised Sb(V) species onto soils and soil phases. In this study sorption of Sb(V) by two organic rich soils with high levels of oxalate extractable Fe was examined over the pH range of 2.5-7. Furthermore, the sorption behaviour of Sb(V) was examined in two phases mimicking those dominant in the experimental soils, namely a solid humic acid and an amorphous Fe(OH)3, across the same pH range. Sorption of Sb by the soils and the humic acid fitted a Freundlich type isotherm, with the equation parameters reflecting changes in bonding affinity corresponding to pH changes. The soils sorbed >75% of the added Sb in all trials, and 80-100% at pH values less than approximately 6.5. The Fe(OH)3 retained >95% of the added Sb in all experiments. The humic acid sorbed up to 60% of the added Sb at acidic pH values, but sorption decreased to zero at higher pH values. Further adsorption studies are recommended, such as examining the effects of ion competition and changes in ionic strength.     

Statistical Evaluation of Variables Affecting Occurrence of Hydrocarbons in Aquifers Used for Public Supply,California

The variables affecting the occurrence of hydrocarbons in aquifers used for public supply in California were assessed based on statistical evaluation of three large statewide datasets; gasoline oxygenates also were analyzed for comparison with hydrocarbons. Benzene is the most frequently detected (1.7%) compound among 17 hydrocarbons analyzed at generally low concentrations (median detected concentration 0.024 μg/l) in groundwater used for public supply in California; methyl tert‐butyl ether (MTBE) is the most frequently detected (5.8%) compound among seven oxygenates analyzed (median detected concentration 0.1 μg/l). At aquifer depths used for public supply, hydrocarbons and MTBE rarely co‐occur and are generally related to different variables; in shallower groundwater, co‐occurrence is more frequent and there are similar relations to the density or proximity of potential sources. Benzene concentrations are most strongly correlated with reducing conditions, regardless of groundwater age and depth. Multiple lines of evidence indicate that benzene and other hydrocarbons detected in old, deep, and/or brackish groundwater result from geogenic sources of oil and gas. However, in recently recharged (since ~1950), generally shallower groundwater, higher concentrations and detection frequencies of benzene and hydrocarbons were associated with a greater proportion of commercial land use surrounding the well, likely reflecting effects of anthropogenic sources, particularly in combination with reducing conditions.     

Conjunctive Water Use in Confined Basalt Aquifers: An Evaluation Using Geochemistry,a Numerical Model,and Historical Water Level

As withdrawals from deep compartmentalized aquifers increasingly exceed recharge throughout the western United States, conjunctive water use management alternatives have become an applied research priority. This study highlights both details and limitations of the role of irrigation canal seepage as groundwater recharge, revealing the regional limitations of canal seepage as a dependable source of recharge in overdrawn aquifers. A suite of geochemical indicators were used together with a numerical model to evaluate current and future management scenarios focused on recharge derived from seepage from a region‐wide irrigation canal system. Twenty‐five years of static groundwater level data were used to relate spatial trends determined using geochemistry and groundwater modeling with “on‐the‐ground” management practices, which vary based on acreage, crop, and irrigation scheduling. Increasing groundwater age determined using isotope analysis, and declines in potentiometric heads, each correlate with increasing distance from the canal reaches. Predictive modeling indicates that if pumping is gradually reduced, as has been suggested by management agencies, that recharge from canal seepage will be negligible by 2035 due to regional groundwater through‐flow and the pattern of potentiometric head recovery. Unfortunately, historic hydrographs suggest that under current groundwater development conditions most wells are not sustainable, irrespective of proximity to the canal.     

An independent review and prioritization of past radionuclide and chemical releases from the Los Alamos National Laboratory--implications for future dose reconstruction studies

From 1999 through 2010, a team of scientists and engineers systematically reviewed approximately eight million classified and unclassified documents at Los Alamos National Laboratory (LANL) that describe historical off-site releases of radionuclides and chemicals in order to determine the extent to which a full-scale dose reconstruction for releases is warranted and/or feasible. As a part of this effort, a relative ranking of historical airborne and waterborne radionuclide releases from LANL was established using priority index (PI) values that were calculated from estimated annual quantities released and the maximum allowable effluent concentrations according to The U.S. Nuclear Regulatory Commission (USNRC). Chemical releases were ranked based on annual usage estimates and U.S. Environmental Protection Agency (USEPA) toxicity values. PI results for airborne radionuclides indicate that early plutonium operations were of most concern between 1948 and 1961, in 1967, and again from 1970 through 1973. Airborne releases of uranium were found to be of most interest for 1968, from 1974 through 1978, and again in 1996. Mixed fission products yielded the highest PI value for 1969. Mixed activation product releases yielded the highest PI values from 1979 to 1995. For waterborne releases, results indicate that plutonium is of most concern for all years evaluated with the exception of 1956 when (90)Sr yielded the highest PI value. The prioritization of chemical releases indicate that four of the top five ranked chemicals were organic solvents that were commonly used in chemical processing and for cleaning. Trichloroethylene ranked highest, indicating highest relative potential for health effects, for both cancer and non-cancer effects. Documents also indicate that beryllium was used in significant quantities, which could have lead to residential exposures exceeding established environmental and occupational exposure limits, and warrants further consideration. In part because of the close proximity of residents to LANL, further study of historical LANL releases and the potential impact to public health is recommended for those materials with the largest priority index values; namely, plutonium, uranium, and selected chemicals.     

Quantifying potential profit from material recycling: a case study in brick manufacturing

Efforts to increase the use of waste materials as substitutes for virgin primary materials in industry are considered an important step toward sustainable industrial development. Some industries, however, have struggled to increase the recycling of materials for a variety of reasons. This study proposes a new approach to searching for recycling across industry boundaries. By focusing on an entire industry, the locations where economic and environmental benefit exists can be identified. This research identifies brick manufacturing facilities in the United States that are most likely to gain substantial economic benefit from the recycling of waste products. The results of this case study indicate that an industry-based approach can provide economically feasible pathways towards sustainable industrial development, especially for data rich manufacturing nations like the United States.     

Efficiency of cassava steep liquor for bioremediation of diesel oil-contaminated tropical agricultural soil

Soil artificially contaminated with diesel oil, treated with cassava steep liquor (CSL) and designated EXPS. Similar polluted soil without CSL amendment (CSS1) and uncontaminated soil (CSS2) served as controls. There were dramatic changes in the physico-chemistry of systems EXPS and CSS1 with utilization of the inorganic nutrients to near-depletion in the former than the latter. In contrast, the properties of CSS2 remained relatively stable throughout the investigated period. Similarly, the population densities of microflora in the polluted soils showed an initial decrease between days 0 and 5 before assuming an increasing trend with percent hydrocarbon-utilizers ranging significantly (P < 0.05) from 0.56 to 6.6, 0.1 to 2.46 and 0.56 to 0.26, respectively for EXPS, CSS1, and CSS2. In EXPS, the residual oil decreased from 98,045 to 1,102.3 mg/kg soil at day 35 representing about 98.88% degradation. The corresponding value for CSS1 was 98,106.1 to 52,110 mg/kg soil, amounting to 46.88% oil disappearance. The GC fingerprints of alkane fractions of the recovered oil reduced significantly by day 15 for EXPS with near-similar results of CSS1. However, by day 35, there was complete disappearance of all peaks including the pristane and phytane molecules in the former whereas in CSS1, there were no observable changes. The germination and growth profiles of maize seed plants as evidence of recovery of oil-impacted soils were poor in CSS1 (10%) with pronounced abnormal morphology when compared with the data obtained for EXPS (74%) and CSS2 (80%). These results suggest that CSL could be an indispensable tool in bioremediation of environments contaminated with hydrocarbons. The technology of application is simple, rapid and cost-effective and may be appropriate for use in developing countries to ameliorate the problems of petroleum pollution.     

Noninvasive fetal genome sequencing: a primer

We recently demonstrated whole genome sequencing of a human fetus using only parental DNA samples and plasma from the pregnant mother. This proof-of-concept study demonstrated how samples obtained noninvasively in the first or second trimester can be analyzed to yield a highly accurate and substantially complete genetic profile of the fetus, including both inherited and de novo variation. Here, we revisit our original study from a clinical standpoint, provide an overview of the scientific approach, and describe opportunities and challenges along the path toward clinical adoption of noninvasive fetal whole genome sequencing. © 2013 John Wiley & Sons, Ltd.     

A global strategy for forest utilization: mitigating climate change without unduly constraining utilization

Mitigation and Adaptation Strategies for Global Change - The objective of the study was to outline a global scheme for furthering mitigation of climate change in the Managed Forest subsector of the...     

Optimizing carbon sequestration in commercial forests by integrating carbon management objectives in wood supply modeling

This paper provides a methodology for generating forest management plans, which explicitly maximize carbon (C) sequestration at the forest-landscape level. This paper takes advantage of concepts first presented in a paper by Meng et al. (2003; Mitigation Adaptation Strategies Global Change 8:371–403) by integrating C-sequestration objective functions in existing wood supply models. Carbon-stock calculations performed in Woodstock^TM (RemSoft Inc.) are based on C yields generated from volume table data obtained from local Forest Development Survey plots and a series of wood volume-to-C content conversion factors specified in von Mirbach (2000). The approach is used to investigate the impact of three demonstration forest-management scenarios on the C budget in a 110,000 ha forest in south-central New Brunswick, Canada. Explicit demonstration scenarios addressed include (1) maximizing timber extraction either by clearcut or selection harvesting for greatest revenue generation, (2) maximizing total C storage in the forest landscape and in wood products generated from harvesting, and (3) maximizing C storage together with revenue generation. The level of clearcut harvesting was greatest for scenario 1 (≥15 × 10⁴ m³ of wood and ≥943 ha of land per harvesting period), and least for scenario 2 (=0 m³ per harvesting period) where selection harvesting dominated. Because softwood saw logs were worth more than pulpwood ($60 m⁻³ vs. $40 m⁻³) and were strategic to the long-term storage of C, the production of softwood saw logs exceeded the production of pulpwood in all scenarios. Selection harvesting was generally the preferred harvesting method across scenarios. Only in scenario 1 did levels of clearcut harvesting occasionally exceed those of selection harvesting, mainly in the removal of old, dilapidated stands early in the simulation (i.e., during periods 1 through 3). Scenario 2 provided the greatest total C-storage increase over 80 years (i.e., 14 × 10⁶ Mg C, or roughly 264 Mg ha⁻¹) at a cost of $111 per Mg C due to lost revenues. Scenarios 3 and 1 produced reduced storage rates of roughly 9 × 10⁶ Mg C and 3 × 10⁶ Mg C, respectively; about 64% and 22% of the total, 80-year C storage calculated in scenario 2. The bulk of the C in scenario 2 was stored in the forest, amounting to about 76% of the total C sequestered.