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711.
R. Brad Mills Andrew M. Paterson David R.S. Lean John P. Smol Greg Mierle Jules M. Blais 《Environmental pollution (Barking, Essex : 1987)》2009,157(11):2949-2956
Total mercury concentration was analyzed in 171 lakes from pre-industrial (>30 cm depth; Hgpre-industrial) and present-day sediments (0.5–1 cm; Hgpresent-day). Numerous hot or cold spots of sediment mercury enrichment (Hg EF; Hgpre-industrial/Hgpresent-day) were evident as determined by local tests of autocorrelation, although in most cases, the maximum correlation among sites was not the nearest neighbor, indicating a strong influence of watershed characteristics. Hg EF was correlated with the area of open water (ha) (r = 0.91, p = 0.035), mine tailings (r = 0.94, p = 0.019), and organic deposits in surficial geology of the watershed (r = −0.91, p = 0.034). Through use of local rather than global regression coefficients, R2 increased from 0.20 (p = 0.005) to 0.60 (p = 0.013). A broad spatial pattern (>500 km) observed only in Hgpre-industrial was best explained by mean annual precipitation (shared variance = 3.5%), while finer spatial patterns only observed in Hgpresent-day and Hg EF were best explained by pH (average shared variance = 10.8%). 相似文献
712.
Past experience shows that inappropriate agricultural development in wetlands can undermine sustainability and may have profound social and economic repercussions for people dependent on the range of ecosystem services provided by those wetlands. Nonetheless, there is escalating pressure to expand agriculture within wetlands due to increasing population, in conjunction with efforts to increase food security. This paper describes the development of a semi-analytical framework for identifying, organizing and analyzing the complex factors that link people, agriculture and wetland ecosystems — an index of Working Wetland Potential (WWP). The method is based on a form of multi-criteria analysis that integrates biophysical and socio-economic aspects of wetland utilization. The WWP index emerges from the aggregation of two values: the first arising from an appraisal of both the biophysical and socio-economic suitability of using the wetland for agriculture; and the second resulting from an assessment of the possible hazards, in relation to both social welfare and the ecological character of the wetland. Hence, the approach provides a way to explicitly integrate biophysical and social aspects of wetland utilization in a single index to enable an initial assessment of the suitability of using a wetland for agriculture. Results from three contrasting wetlands in sub-Saharan Africa are presented. 相似文献
713.
714.
In this study, fertilized Japanese medaka (Oryzias latipes) embryos were exposed from fertilization to 5 d post-hatch using static non-renewal assays to aqueous suspensions of titanium dioxide nanoparticles (nTiO2) ranging in nominal concentrations between 0 and 14 μg mL−1. The average size of the nTiO2 in the stock solution before addition to the test treatments was 87 nm (±14 nm). TiO2 materials accumulated in a concentration dependent manner on the chorionic filaments of developing medaka embryos with evidence of pericardial edema occurring during embryo development. However, no significant (p > 0.05) increases in mortality relative to control treatments were observed for the nTiO2 exposed embryos. A concentration dependent increase in cumulative percent hatch was observed at 11 d, indicating that exposure to increasing concentrations of nTiO2 resulted in the premature hatch of medaka embryos. Post-hatch, a significant proportion of sac fry from the nTiO2 exposure groups exhibited moribund swimming behavior and these individuals also experienced greater mortality at 15 d post-hatch. Combined, these results demonstrate that exposure to nTiO2 can impact the development of early life stages of fish. 相似文献
715.
Two aluminum water treatment residuals (Al-WTRs) from water treatment plants in Manatee County, FL and Punta Gorda, FL were evaluated as potential permeable reactive barrier (PRB) media to reduce groundwater phosphorus (P) losses. Short-term (<24 h) P sorption kinetics and long-term P sorption capacity were determined using batch equilibration studies. Phosphorus desorption was characterized following P loadings of 10, 20, 30, 40 and >70 g kg−1. Sorption and desorption studies were conducted on the <2.0 mm material and three size fractions within the <2.0 mm material. The effect of dissolved organic carbon (DOC) on P retention was determined by reacting Al-WTRs with P-spiked groundwater samples of varying initial DOC concentrations. Phosphorus sorption kinetics were rapid for all size fractions of both Al-WTRs (>98% P sorption effectiveness at shaking times ?2 h). The effect of DOC was minimal at <150 mg DOC L−1, but modest reductions (<22%) in P sorption effectiveness occurred at 587 mg DOC L−1. The P sorption capacities of the Manatee and Punta Gorda Al-WTRs (<2.0 mm) are ∼44 g kg−1 and >75 g kg−1, respectively, and the lifespan of an Al-WTR PRB is likely many decades. Desorption was minimal (<2% of the P sorbed) for cumulative P loadings <40 g kg-l, but increased (<9% of the P sorbed) at cumulative P loads >70 g kg−1. The <2.0 mm Manatee and Punta Gorda Al-WTRs are regarded as ideal PRB media for P remediation. 相似文献
716.
Bojan Gasic Matthew MacLeod Martin Scheringer Konrad Hungerbuhler 《Atmospheric environment (Oxford, England : 1994)》2010,44(35):4489-4496
We investigate the long-range transport potential (LRTP) of five different classes of hypothetical chemical pollutants (volatile, multimedia, semivolatile, particle-associated and hydrophilic) during a low pressure weather event using a novel 2 (x- and z-axis)-Dimensional Multi-Media Meteorological Model (2D4M). The atmosphere (z-axis) is described by three atmospheric layers, where two layers constitute the boundary layer and the third layer the free troposphere. The 2D4M can describe distinct weather events on a regional scale and calculate the LRTP of chemicals as a function of time during these events. Four weather factors are used to model weather events and their influence on the atmospheric transport of chemicals: (1) temperature, (2) wind speed and mixing dynamics of the troposphere, (3) hydroxyl radical concentrations and (4) precipitation. We have modeled the impact of variability in each of these factors on LRTP of pollutants during a front event associated with a low pressure period that interrupts a dominant high pressure system. The physico-chemical properties of the pollutant determine which specific weather factors contribute most to variability in transport potential during the event. Volatile and multimedia chemicals are mainly affected by changing atmospheric mixing conditions, wind speeds and OH radical concentrations, while semivolatile substances are also affected by temperature. Low-vapor-pressure pollutants that are particle-associated, and water-soluble pollutants are most strongly affected by precipitation. Some chemical pollutants are efficiently transported from the boundary layer into the upper troposphere during the modeled low pressure event and are transported by much higher wind speeds than in the boundary layer. Our model experiments show that the transport potential of volatile, multimedia and semivolatile compounds is significantly increased during a front event as a result of efficient tropospheric mixing and fast wind speeds in the upper troposphere, whereas low-volatility and hydrophilic chemicals are largely scavenged from the atmosphere. In future LRTP assessment of chemical contaminants as required by the Stockholm Convention and the convention on long-range transboundary air pollution, it is therefore advised to prioritize volatile, multimedia and semivolatile chemicals that are identified in initial screening. 相似文献
717.
Perceptions of climate change,multiple stressors and livelihoods on marginal African coasts 总被引:1,自引:0,他引:1
Matthew Bunce Sergio Rosendo Katrina Brown 《Environment, Development and Sustainability》2010,12(3):407-440
Studies of multiple stressors in Africa often focus on vulnerable inland communities. Rising concentrations of the world’s
poor live in coastal rural–urban areas with direct dependencies on marine as well as terrestrial ecosystem goods and services.
Using participatory methods we elicited perceptions of stressors and their sources, impacts and consequences held by coastal
communities in eastern Africa (Mtwara in Tanzania and Maputo in Mozambique). Respondent-informed timelines suggest wars, economic
policies and natural increase have led to natural resource-dependent populations in marginal, previously little-inhabited
lowland coastal areas. Respondents (n = 91) in interviews and focus groups rank climate stressors (temperature rise/erratic rain) highest amongst human/natural
stressors having negative impacts on livelihoods and wellbeing (e.g., cross-scale cost of living increases including food
and fuel prices). Sources of stress and impacts were mixed in time and space, complicating objective identification of causal
chains. Some appeared to be specific to coastal areas. Respondents reported farms failing and rising dependence on stressed
marine resources, food and fuel prices and related dependence on traders and credit shrunk by negative global market trends.
Development in the guise of tourism and conservation projects limited access to land–sea livelihoods and resources in rural–urban
areas (coastal squeeze). Mental modelling clarified resource user perceptions of complex linkages from local to international
levels. We underline risks of the poor in marginal coastal areas facing double or multiple exposures to multiple stressors,
with climate variability suggesting the risks of climate change. 相似文献
718.
Electrochemical systems provide a low cost, versatile, and controllable platform to potentially treat contaminants in water, including chlorinated solvents. Relative to bare metal or noble metal amended materials, dimensionally stable electrode materials such as mixed metal oxide coated titanium (Ti/MMO) have advantages in terms of stability and cost, important factors for sustainable remediation solutions. Here, we report the use of Ti/MMO as an effective cathode substrate for treatment of trichloroethene (TCE). TCE degradation in a batch reactor was measured as the decrease of TCE concentration over time and the corresponding evolution of chloride; notably, this occurred without the formation of commonly encountered chlorinated intermediates. The reaction was initiated when Ti/MMO cathode potentials were less than -0.8 V vs. the standard hydrogen electrode, and the rate of TCE degradation increased linearly with progressively more negative potentials. The maximum pseudo-first-order heterogeneous rate constant was approximately 0.05 cm min(-1), which is comparable to more commonly used cathode materials such as nickel. In laboratory-scale flow-though column reactors designed to simulate permeable reactive barriers (PRBs), TCE concentrations were reduced by 80-90%. The extent of TCE flux reduction increased with the applied potential difference across the electrodes and was largely insensitive to the spacing distance between the electrodes. This is the first report of the electrochemical reduction of a chlorinated organic contaminant at a Ti/MMO cathode, and these results support the use of this material in PRBs as a possible approach to manage TCE plume migration. 相似文献
719.
720.
Brown GS Betty RG Brockmann JE Lucero DA Souza CA Walsh KS Boucher RM Tezak MS Wilson MC 《Journal of environmental monitoring : JEM》2007,9(7):666-671
Vacuum filter socks were evaluated for recovery efficiency of powdered Bacillus atrophaeus spores from two non-porous surfaces, stainless steel and painted wallboard and two porous surfaces, carpet and bare concrete. Two surface coupons were positioned side-by-side and seeded with aerosolized Bacillus atrophaeus spores. One of the surfaces, a stainless steel reference coupon, was sized to fit into a sample vial for direct spore removal, while the other surface, a sample surface coupon, was sized for a vacuum collection application. Deposited spore material was directly removed from the reference coupon surface and cultured for enumeration of colony forming units (CFU), while deposited spore material was collected from the sample coupon using the vacuum filter sock method, extracted by sonication and cultured for enumeration. Recovery efficiency, which is a measure of overall transfer effectiveness from the surface to culture, was calculated as the number of CFU enumerated from the filter sock sample per unit area relative to the number of CFU enumerated from the co-located reference coupon per unit area. The observed mean filter sock recovery efficiency from stainless steel was 0.29 (SD = 0.14, n = 36), from painted wallboard was 0.25 (SD = 0.15, n = 36), from carpet was 0.28 (SD = 0.13, n = 40) and from bare concrete was 0.19 (SD = 0.14, n = 44). Vacuum filter sock recovery quantitative limits of detection were estimated at 105 CFU m(-2) from stainless steel and carpet, 120 CFU m(-2) from painted wallboard and 160 CFU m(-2) from bare concrete. The method recovery efficiency and limits of detection established in this work provide useful guidance for the planning of incident response environmental sampling for biological agents such as Bacillus anthracis. 相似文献