Maßnahmen zur Dioxinminderung an Müllverbrennungsanlagen

The 17th BlmSchV fixed the emission limit of 0.1 ng TE/m_n ³ for PCDD/F’s produced as a result of waste- and special waste incinerators. This article introduces the different measures implemented to uphold this limit, and discusses their advantages and disadvantages. Methods of optimising the incineration conditions are among the primary measures. Different geometry’s for conventional oven incineration rooms were discussed, and an effective modernisation method was introduced (Temelli nozzles). The chemical and technical basis of an often discussed gasification method, as well as the characteristics of three specialised techniques (Coke Burn technique, Thermo-Select technique and Noell-DBI technique) are explained in this article. Alongside the secondary measures of hot-dust filtration and inhibition being added to the washers in an attempt to achieve PCDD/F adsorption. The most important tertiary measures, namely the SCR technique, along with a variety of coke adsorption techniques are introduced, with their advantages and disadvantages. New techniques such as DeDioxin and Medisorbon are also addressed.     

The Role of Organic Matter in Natural Aquatic Systems: Analytical Constraints

The dissolved organic matter in aquatic systems consists of a heterogeneous mixture of compounds with wide ranging chemical properties and diverse origins. the presence of organic matter (OM) in surface and ground waters has important implications with regard to the mobility and therefore fate of many potential organic and inorganic pollutants. the majority of the analytical approaches in current use require exhaustive pre-treatment steps which may lead to the formation of artefacts within the sample. an analytical technique based upon gel permeation chromatography is proposed as a more reliable procedure for the characterisation of naturally occurring dissolved organic matter.     

Nachhaltige Entwicklung von Managementstrategien: Multikriterielle Bewertungs- und Entscheidungshilfe-Instrumente im Umweltbereich

Zur Unterstützung von Bewertungs- und Entscheidungsprozessen über die Nachhaltigkeit von Managementstrategien, deren Auswirkungen durch unterschiedlich dimensionierte Indikatoren gemessen werden, gibt es verschiedene mathematische Methoden. In diesem Beitrag werden die Prinzipien dieser sog. multikriteriellen Bewertungs- und Entscheidungshilfeinstrumente beispielhaft anhand einer Auswahl von Strategien für ein Nachhaltiges Wassermanagement vorgestellt, sowie Vor- und Nachteile herausgearbeitet. Es wird gezeigt, dass sich die Verfahren insbesondere in Transparenz, Objektivit?t und durch den Grad an Partizipation durch Akteure z.T. erheblich unterscheiden. W?hrend die Hassediagrammtechnik sich an den naturwissenschaftlich begründbaren Datenmatrix orientiert und somit eine objektive und transparente Bewertung und Datenanalyse liefert, haben Konkordanzanalyse, Nutzwertanalyse, PROMETHEE und AHP ihre St?rken in der M?glichkeit, Akteure bzw. Stakeholder am Entscheidungsprozess partizipieren zu lassen. *** DIRECT SUPPORT *** A00OI029 00003     

Optimality of parental investment: The influence of nursing on reproductive success of mother and female young house mice

Summary The amount of parental milk investment determines not only the number of young the parent can produce, but also affects the offspring's fitness. The antagonism between quantity and quality of offspring was investigated in laboratory mice.In nursing first litters containing 2,4, ..., 14 pups, mothers invested increasing amounts of milk. This mainly extended the intervals between their first and second litters and slightly increased the size of their second litters, whilst third litters were not affected. In the female young, the decreasing amount each individual received as a result of increasing litter size led to delayed birth and reduced the size of their first litters. The intervals between their first and second litters and the size of the second litters were also affected, although to a lesser extent.Taking these results into consideration on a standard lifetime pattern of reproduction, the effects were calculated on net reproductive rates as an expression of fitness. Death rates were assumed that referred to population equilibrium or population growth. In both situations, the fitness curves of mothers and young showed that the actual level of milk investment and the level yielding optimal reproduction were in agreement. There was no significant deviation towards increased investment, as might result from parent-offspring conflict.     

Radioactivity of the soil in Vojvodina (northern province of Serbia and Montenegro)

The widespread public belief that during the bombardment of Vojvodina (Yugoslavia) this region was contaminated by depleted uranium has recently raised public concern with respect to the potential contamination of agricultural products due to soil radioactivity. Based on the gamma-spectrometric analysis of 50 soil samples taken from the region of Vojvodina we concluded that there is no increase of radioactivity that could endanger the food production. Taking into account the transfer factors of 137Cs to plants, the measured activity concentrations of this isotope should not endanger the health safety of the produced food. No traces of depleted uranium have been found. The natural radioactivity levels are compared with the results form other countries.     

Chemical and biological characterization of non-extractable sulfonamide residues in soil

For sulfonamides, the formation of non-extractable residues has been identified by laboratory testing as the most relevant concentration determining process in manured soil. Therefore, the present study has been focused on the chemical and biological characterization of non-extractable residues of ¹⁴C-labeled sulfadiazine or sulfamethoxazole. In laboratory batch experiments, the test substances were spiked via standard solution or test slurry to microbially active soil samples. After incubation periods of up to 102 d, a sequential extraction technique was applied. Despite the exhaustive extraction procedure, sulfadiazine residues mainly remained non-extractable, indicating the high affinity to the soil matrix. The remobilization of non-extractable ¹⁴C-sulfadiazine residues was monitored in the activated sludge test and the Brassica rapa test. Only small amounts (<3%) were transferred into the extractable fractions and 0.1% was taken up by the plants. In the Lumbricus terrestris test A, the release of non-extractable ¹⁴C-sulfamethoxazole residues by the burrowing activity of the earthworms was investigated. The residues mainly remained non-extractable (96%). The L. terrestris test B was designed to study the immobilization of ¹⁴C-sulfamethoxazole in soil directly after the test slurry application. The mean uptake by earthworms was 1%. Extractable and non-extractable residues amounted to 5% and 93%, respectively. Consequently, the results of all tests confirmed the high affinity of the non-extractable sulfonamide residues to the soil matrix.     

Influence of suspended clay minerals and humic matter on the solid phase extraction efficiency of selected pesticides from water

The purpose of this investigation was to determine the influence of humic acids (HA) and Ca-montmorillonite (CaM) on the solid-phase extraction (SPE) efficiency of atrazine, alachlor and alpha-cypermethrin from water samples at various pH-values. The nature and intensity of binding of the studied pesticides to CaM were determined by X-ray diffraction analysis and termogravimetric analysis (TGA) test. The studied pesticides eluted from discs were analysed by thin-layer chromatography (TLC). The effects of CaM and humic acid were generally pH-dependent and acted independently in extraction efficiency influence. Lower recovery of pesticides was observed at higher pH values when CaM was > or =0.1 g and was attributed to greater dispersion of clay, increased surface area and subsequent adsorption. Concentrations of dissolved organic carbon (DOC) in humic acid had less effect on the extraction efficiency when water was at pH 8 compared to water at pH 2, which was probably due to greater nonpolar interactions of the pesticides to the charge-neutralized humic acid molecule.