Experimental evaluation of emission factors of cement kilns burning hazardous wastes

Cement industry is an interesting way to eliminate combustible wastes. Thermal valorization is maximal, conditions of combustion are especially favorable to the destruction and the trapping of pollutants, and there are neither ultimate residues (slag) nor aqueous rejects. Moreover the properties of the cement are not modified. Nevertheless the increased use of substitution fuel may lead to deal with unusual amounts of heavy metals. Tests were realized on several rotary cement kilns with varying substitution ratios of fossil fuels by wastes. Mass balances were fitted over the whole plant, and emission factors were explained.     

Enhanced solubilization of arsenic and 2,3,4,6 tetrachlorophenol from soils by a cyclodextrin derivative

The application of extracting aqueous solutions with cyclodextrins in several soil remediation technologies has been increasingly studied but little is known about their removal capacities toward the inorganic species. Herein, the effectiveness of cyclodextrins (CDs) in extracting arsenic, copper, and iron from a mining soil is presented. In a preliminary test of four types of CD aqueous solutions, only the addition of carboxylmethyl-beta-cyclodextrin CMCD (a cyclodextrin derivative) led to a significant enhancement in arsenic removal. An increase in the concentration of copper and iron in the leachates was also observed with CMCD. Kinetic study of arsenic release was carried out at two temperatures (20 and 35 degrees C). The arsenic concentration in the leachates increases with increasing cyclodextrin concentration. At an 80 mM CMCD concentration, arsenic, copper, and iron released in filtrates were about 20-, 1,000-, and 4,000-fold greater, respectively, than that obtained using deionized water. In the soil system, the CMCD capacity removal was found to be higher for cations than for arsenic. Because the tetrachlorophenol can co-occur with arsenic and copper in several contaminated sites, its solubilization by CMCD was also investigated. Extraction experiments were performed to extract 2,3,4,6 tetrachlorophenol (TeCP) in spiked soil with CMCD. The results of batch experiments have shown that CMCD could significantly increase the TeCP extraction from soil. CD sorption on soils as quantified by a fluorescence technique was low, indicating no significant loss of CD during the leaching experiments. The use of CMCD as a flushing agent to enhance the removal of both inorganic and organic pollutants from mixed-contaminated soils appears as a promising remediation method.     

Seasonal abundance and toxicity of the dinoflagellate Gambierdiscus spp. (Dinophyceae), the causative agent of ciguatera in Tahiti, French Polynesia

The benthic dinoflagellate Gambierdiscus spp. is the primary causative agent of ciguatera fish poisoning in French Polynesia. However, the initiation of ciguatera outbreaks and the factors that control ciguatoxin production in this dinoflagellate are still poorly understood. In this paper, we present some original data concerning the seasonal abundance and toxicity of natural populations of Gambierdiscus spp. based on a long-term survey in a ciguateric site of the island of Tahiti. From February 1993 to December 1997, Gambierdiscus spp. population densities were monitored weekly in the Atimaono barrier reef of Papara in relation to temperature and salinity. Densities peaked at 4992 cells g⁻¹ in October 1994 and constituted ≥1000 cells g⁻¹ on several occasions. A total of 58 blooms were recorded in the area, of which 65% occurred in 1995 and 1996 alone. Our data confirmed the high endemicity of Gambierdiscus spp. in the Papara area. Refined analysis of our raw data by a principal-component analysis of processes (PCAP) revealed a seasonality in cell densities from February 1993 to May 1995. During this period, Gambierdiscus spp. populations tended to reach maximum abundance at the beginning and end of the hot season. In contrast, salinity did not appear to be a determining factor in the seasonal abundance of this dinoflagellate. The noticeable increase in both peak densities and frequency of blooms further noticed in 1995 and 1996 was preceded by unusually high water temperatures in January to April 1994, concomitant with a severe coral-bleaching episode. During the course of the study, a total of 303 × 10⁶ cells obtained from 48 successive blooms was harvested. Toxicity screening revealed that toxin production was maximum from October 1994 through December 1996. No correlation was found between toxicity of these blooms and their biomass nor the seasonal pattern of temperatures. It is suggested that the toxicity of naturally-occurring blooms of Gambierdiscus spp. and, consequently, the severity of ciguatera incidents in a given area, is mainly dependent on the clonal nature of cells which coexist within local populations of this dinoflagellate. Received: 12 October 1998 / Accepted: 15 June 1999     

SPATIAL VARIATIONS OF WATER LOSS DURING DROUGH A CASE STUDY1

ABSTRACT: A regional water conservation system for drought management involves many uncertain factors. Water received from precipitation may stay on the ground surface, evaporate back into the atmosphere, or infiltrate into the ground. Reliable estimates of the amount of evapotranspiration and infiltration are not available for a large basin, especially during periods of drought. By applying a geographic information system, this study develops procedures to investigate spatial variations of unavailable water for given levels of drought severity. Levels of drought severity are defined by truncated values of monthly precipitation and daily streamflow to reflect levels of water availability. The greater the truncation level, the lower the precipitation or streamflow. Truncation levels of monthly precipitation are recorded in depth of water while those of daily streamflow are converted into monthly equivalent water depths. Truncation levels of precipitation and streamflow treated as regionalized variables are spatially interpolated by the unbiased minimum variance estimation. The interpolated results are vector values of precipitation and streamflow at a grid of points covering the studied basin. They are then converted into raster‐based values and expressed graphically. The image subtraction operation is used to subtract the image of streamflow from that of precipitation at their corresponding level of drought severity. It is done on a cell‐by‐cell basis resulting in new attribute values to form the spatial image representing a spatial distribution of potential water loss at a given level of drought severity.     

Duplication of chromosome 11 centromere in fetal and maternal karyotypes: A new variant?

Fetal chromosome analysis in a 39-year-old mother revealed a chromosome 11 aberration interj ireted as a duplication of the centromere. This was also found in the mother's karyotype, raising the possibility that the abnormality was a new variant of no clinical consequence.     

Recycling of crushed waste rock as backfilling material in coal mine: effects of particle size on compaction behaviours

Environmental Science and Pollution Research - Crushed waste rocks can be used as materials for backfilling goafs, so as to achieve the simultaneous goals of processing solid waste and controlling...     

Spatial Variability of Nitrate Concentrations Under Diverse Conditions in Tributaries to a Lake Watershed1

Abstract: Nitrate‐nitrogen (NO₃‐N) concentrations in stream water often respond uniquely to changes in inter‐annual conditions (e.g., biological N uptake and precipitation) in individual catchments. In this paper, we assess (1) how the spatial distribution of NO₃‐N concentrations varies across a dense network of nonnested catchments and (2) how relationships between multiple landscape factors [within whole catchments and hydrologically sensitive areas (HSAs) of the catchments] and stream NO₃‐N are expressed under a variety of annual conditions. Stream NO₃‐N data were collected during two synoptic sampling events across >55 tributaries and two synoptic sampling periods with >11 tributaries during summer low flow periods. Sample tributaries drain mixed land cover watersheds ranging in size from 0.150 to 312 km² and outlet directly to Cayuga Lake, New York. Changes in NO₃‐N concentration ratios between each sampling event suggest a high degree of spatial heterogeneity in catchment response across the Cayuga Lake Watershed, ranging from 0.230 to 61.4. Variations in NO₃‐N concentrations within each of the large synoptic sampling events were also high, ranging from 0.040 to 8.7 mg NO₃‐N/l (March) and 0.090 to 15.5 mg NO₃‐N/l (October). Although Pearson correlation coefficients suggest that this variability is related to multiple landscape factors during all four sampling events, partial correlations suggest percentage of row crops in the catchments as the only similar factor in March and October and catchment area as the only factor during summer low flows. Further, the strength of the relationships is typically lower in the HSAs of catchment. Advancing current understanding of such variations and relationships to landscape factors across multiple catchments – and under a variety of biogeochemical and hydrological conditions – is important, as (1) nitrate continues to be employed as an indicator of regional aquatic ecosystem health and services and (2) a unified framework approach for understanding individual catchment processes is a rapidly evolving focus for catchment‐based science and management.     

A Retrospective Look at the Water Resource Management Policies in Nassau County,Long Island,New York1

Abstract: The residents of Nassau County Long Island, New York receive all of their potable drinking water from the Upper Glacial, Jameco/Magothy (Magothy), North Shore, and Lloyd aquifers. As the population of Nassau County grew from 1930 to 1970, the demand on the ground‐water resources also grew. However, no one was looking at the potential impact of withdrawing up to 180 mgd (7.9 m³/s) by over 50 independent water purveyors. Some coastal community wells on the north and south shores of Nassau County were being impacted by saltwater intrusion. The New York State Legislature formed a commission to look into the water resources in 1972. The commission projected extensive population growth and a corresponding increase in pumping resulting in a projected 93.5 to 123 mgd (4.1 to 5.5 m³/s) deficit by 2000. In 1986, the New York Legislature passed legislation to strengthen the well permit program and also establish a moratorium on new withdrawals from the Lloyd aquifer to protect the coastal community’s only remaining supply of drinking water. Over 30 years has passed since the New York Legislature made these population and pumping projections and it is time to take a look at the accuracy of the projections that led to the moratorium. United States Census data shows that the population of Nassau County did not increase but decreased from 1970 to 2000. Records show that pumping in Nassau County was relatively stable fluctuating between 170 and 200 mgd (7.5 to 8.8 m³/s) from 1970 to 2004, well below the projection of 242 to 321 mgd (10.6 to 14.1 m³/s). Therefore, the population and water demand never grew to projected values and the projected threat to the coastal communities has diminished. With a stable population and water demand, its time to take a fresh look at proactive ground‐water resource management in Nassau County. One example of proactive ground‐water management that is being considered in New Jersey where conditions are similar uses a ground‐water flow model to balance ground water withdrawals, an interconnection model to match supply with demand using available interconnections, and a hydraulic model to balance flow in water mains. New Jersey also conducted an interconnection study to look into how systems with excess capacity could be used to balance withdrawals in stressed aquifer areas with withdrawals in unstressed areas. Using these proactive ground‐water management tools, ground‐water extraction could be balanced across Nassau County to mitigate potential impacts from saltwater intrusion and provide most water purveyors with a redundant supply that could be used during water emergencies.     

Methodology to Assess Silicone (Bio)Degradation and its Effects on Microbial Diversity

The behavior of silicone elastomers in landfills has not been well studied. Their impact on the environment is not known and, consequently, it has not been possible to establish robust Life Cycle Assessments of these materials. In the first part of this study, a methodology for assessing silicone degradation pathways is described. The chemical and biological parameters were considered separately. Firstly, parameters such as pH, redox potential and cation concentration were monitored and then degradation in aerobic and anaerobic conditions was investigated. Any impacts on microbial diversity were also taken into account, using bio-molecular tools. In the second part, a case study on the degradation of Room Temperature Vulcanizable silicone elastomers was performed to validate this methodology. The results indicate that condensation catalysts play a key role at their end-of-life, in both chemical and biological degradation. Moreover, these compounds have a significant effect on microbial communities (similarities with blank samples <5?%). As a consequence, the choice of catalyst should be carefully considered to assess any environmental impacts.     

Variations of 210Po and 210Pb in various marine organisms from Western English Channel: contribution of 210Po to the radiation dose

Measurements of (210)Po were carried out in various marine matrices (mussels, oysters, seaweed, fish, and abalones) and in seawater at several points along the French coast, over a period of 2 years (2003-2005). These measurements contribute to a better knowledge of this element, since few recent data exist for the French coast. Marked seasonal variations have been revealed in some species and there are differences according to the way of life of these species. Activities in mussels (Mytilus edulis) and oysters (Crassostrea gigas) are similar and varying between 90 and 600 Bq kg(-1) (d.w.). Activities in macroalgae (Fucus serratus) are lowest, between 4 and 16 Bq kg(-1) (d.w.). In oyster, abalone (Haliotis tuberculata) and fish (Solea solea, Sparus sp.), the strongest activities are measured in the digestive glands, the gills and the gonads. (210)Po/(210)Pb ratios in all cases have values of more than one for all species. From a significant number of measurements, CFs were calculated for seaweed (between 4.6 x 10(3) and 5.0 x 10(3)) and for molluscs, with highest CFs (>10(5)) found for the digestive gland and gills of the oysters, the digestive gland of the abalones and the liver of fish. Finally, the activities measured have made it possible to estimate the internal dose from chronic exposure due to (210)Po received by the marine organisms (0.05 microGh(-1) for macroalgae, between 0.70 and 1.5 microGh(-1) for mussels and oyster), and the contribution of seafood to the dose received by humans (46-129 microSvy(-1)).