Comprehensive Study Regarding Greenhouse Gas Emission from Iron Ore Based Production at the Integrated Steel Plant SSAB Tunnplåt AB

During the years 2001–2002, a comprehensive study regarding CO₂ emissions related to the steel production for the integrated steel making production route, was carried out. The study was financed by SSAB and carried out by a research group with members from SSAB, MEFOS and LTU. The aim was to study the emissions from the existing system and how these could be influenced by process changes and by process modifications. The calculations were made using a global spreadsheet model for calculating the CO₂ emissions, developed from an existing Energy and Process Integration model of the same system. The calculated cases included the existing BF/BOF route as well as integration of other processes, e.g., an electric arc furnace, DR processes, COREX and a new future smelting reduction process concept (Sidcomet). All new existing alternative ore based process technologies would increase the specific CO₂ emission from the system. A technology transfer to scrap based metallurgy would significantly decrease the emission level, but is not feasible for SSAB, due to the future product mix and the structure of scrap availability. In a 5–20 year perspective, the existing steel making process route with the use of magnetite ore for pellet production has the lowest specific CO₂ emission. In a long-term perspective, 20–50 years, alternative process routes, e.g., based on H₂ and DRI, could be of interest. Studies on such changes are, however, big projects and should be carried out as joint European and/or international efforts.     

In-situ application of colloidal activated carbon for PFAS-contaminated soil and groundwater: A Swedish case study

Soil and groundwater contamination by per- and polyfluoroalkyl substances (PFAS) has been a significant concern to human health and environmental quality. Remediation of contaminated sites is crucial to prevent plume expansion but can prove challenging due to the persistent nature of PFAS combined with their high aqueous mobility. In this case study, we investigated the potential of colloidal activated carbon (CAC) for soil stabilization at the pilot scale, aiming to entrap PFAS and prevent their leaching from soil into groundwater. Monitoring of the site revealed the presence of two potential sources of PFAS contamination at concentrations up to 23 μg L⁻¹ for ∑₁₁PFAS in groundwater. After CAC application, initial results indicated a 76% reduction of ∑₁₁PFAS and high removal rates for long-chain PFAS, such as perfluorooctane sulfonic acid and perfluorooctanoic acid. A spike in concentrations was noticed 6 months after injection of CAC, showing a rebound of the plume and a reduction of treatment effectiveness. Based on long-term monitoring data, the treatment effectiveness for ∑₁₁PFAS dropped to 52%. The rebound of concentrations was attributed to the plume bypass of the barrier due to the presence of high conductivity zones, which likely occurred because of seasonal changes in groundwater flow directions or the CAC application at the site. This demonstrates the need for a detailed and accurate hydrogeological understanding of contaminated sites before designing and applying stabilization techniques, especially at sites with high geologic and hydrologic complexity. The results herein can serve as a guideline for treating similar sites and help avoid potential pitfalls of remedial efforts.