Effect of OH/NCO Molar Ratio on Properties of Soy-Based Polyurethane Networks

Polyurethane networks from soybean oil have a number of valuable properties, which are determined by their chemical composition and cross-linking density. Changing the molar ratio of reacting groups can vary the latter. In this work we have varied the NCO/OH molar ratio (isocyanate index) from 1.05 to 0.40 in a soy polyol/MDI system, and tested physical and mechanical properties. The degree of swelling in toluene increased from 52–206% by decreasing isocyanate index from 1.05–0.4. The sol fractions and network densities determined from swelling in toluene were compared with ones obtained using the network formation theory based on branching processes. The comparison of experimental sol fractions and network densities with those predicted by theory of network formation suggest that 5–10% of bonds are lost in cycles and that high entanglement contributions increase the network densities. Polymers prepared with NCO/OH ratios from 1.05–0.8 were glassy while the others were rubbery, and that was reflected in their properties. Glass transition temperature (DSC) of the networks decreased from 64–7°C, tensile strength from 47–0.3 MPa, and elongation at break increased from 7–232%. The activation energy of the glass transition, determined from dielectric spectra, varied from 222–156 kJ/mol as the molar ratio of NCO to OH groups decreased from 1.05–0.4.     

CFD simulations of ammonia dispersion using “dynamic” boundary conditions

Ammonia is stored in liquid form at ambient temperature and under high pressure. During an accident, ammonia will flash out of the vessel and disperse in the surrounding area. This paper provides a comparison of the results obtained by the FLADIS field experiments and those of CFD modeling by Fluent 6.3. FLADIS experiments were carried out by the Risø National Laboratory using pressure liquefied ammonia. Time series of meteorological conditions as wind speed, wind direction and source strength were determined from the experimentally measured data and used as the inflow boundary conditions. Furthermore, for more realistic simulation of air flow in the computation domain for the desired atmospheric stability, periodic boundary conditions were used on both side boundaries. The initial two-phase flow of the released ammonia was also included. The liquid phase was modeled as droplets using discrete particle modeling, i.e., the Euler–Lagrangian approach for continuous and discrete phases.     

Waste brick dust as a prospective eco-friendly alternative component of artificial soils for ecotoxicological studies

Environmental Science and Pollution Research - Current artificial soils for ecotoxicological studies contain non-renewable materials that must be mined, and their production and processing consume...     

Lead isotopes in environmental sciences: a review

Lead (Pb) isotopic analyses proved to be a very efficient tool for tracing the sources of local and global Pb pollution. This review presents an overview of literature published on the use of Pb isotopic analyses of different environmental matrices (atmospheric aerosols, lichens, tree rings, peat deposits, lake, stream, marine sediments, soils, etc.). In order to gain more insight, the isotopic compositions of major sources of Pb in the environment as determined by several authors are described in detail. These include, above all, the former use of leaded gasoline, coal combustion, industrial activities (e.g., metallurgy) and waste incineration. Furthermore, this review summarises analytical techniques (especially ICP-MS) used for the determination of Pb isotopes in environmental samples.     

Trends in seasonal precipitation and temperature in Slovenia during 1951–2007

A quality-controlled and enhanced database of 38 temperature and 52 precipitation stations was developed for Slovenia, a transitional area between Mediterranean, Alpine and continental climatic regimes, covering the period 1951–2007. Mean annual temperatures significantly increased in nearly all of Slovenia (except western areas) at rates between 0.15 and 0.36 °C/decade. Warming was most intense strongest in summer and spring in north-eastern Slovenia (0.3–0.4 °C/decade) and weakest in autumn. Precipitation trends were heterogeneous. Annual precipitation decreased significantly in the north-western part, at 3–6 % per decade. During spring and summer, decrease in rainfall by 3–6 % was detected in western Slovenia. No significant trends were found for the autumn season. In winter, precipitation decreased, by 3–12 % per decade, in particular in north-western Slovenia. As observed also elsewhere in Central Europe, changes in large-scale atmospheric circulation patterns may have contributed to the observed long-term warming and drying in Slovenia. However, the strong warming in summer and spring, that is almost twice the trend observed in neighbouring countries, could be enhanced by drier soils caused by the decrease in winter precipitation in Slovenia.