组态视角下企业绿色双元创新驱动路径北大核心CSCDCSSCI

绿色双元创新是企业获取绿色竞争优势的重要手段。基于TOE框架,探讨技术、组织、环境三方面要素对企业绿色双元创新绩效的组态效应以及不同要素之间的联动匹配关系。研究结果表明:驱动企业绿色双元创新需要技术、组织和环境多重因素的联动匹配。突破式绿色创新存在三条组态路径,分别是政府环境规制下技术因素与组织因素驱动型、市场绿色压力下技术因素与组织因素驱动型以及依托绿色技术能力的组织因素与环境因素驱动型,绿色技术能力、高管环保意识和高管绿色创新支持是突破式绿色创新的必要条件。渐进式绿色创新存在四条组态路径,分别是政府环境规制下绿色技术能力与组织因素驱动型、市场绿色压力下高管绿色创新支持与技术因素驱动型、依托绿色技术能力的高管环保意识与环境因素驱动型以及政府与市场双轮驱动下的绿色技术管理与组织因素驱动型。突破式绿色创新与渐进式绿色创新路径之间既存在差异也存在联系,但突破式绿色创新在技术、组织和环境方面的要求更高且更丰富。因此,企业应该根据自身实际情况,选择适宜的绿色双元创新实现路径,针对突破式绿色创新,应该进一步加强绿色技术能力、高管环保意识与高管绿色创新支持,关注企业内外部因素对突破式绿色创新的支撑情况。针对渐进式绿色创新,应重点关注绿色技术能力与高管绿色创新支持两个核心条件,有助于加快绿色产品和服务的优化升级。研究结果从多维交互视角系统归纳了企业绿色双元创新的差异化驱动路径,为促进企业绿色双元创新绩效提升提供了重要参考。     

A Variance Estimator for Constrained Estimates of Change in Relative Categorical Frequencies

Consistent estimators of change and state becomes an issue when sample data come from a mix of permanent and temporary observation units. A joint maximum likelihood estimator of state and change creates estimates of state that depend on antecedent viz. posterior survey results and may differ from estimates of state derived from a single-date analysis of the sample data. A constrained estimator of change in relative categorical frequencies that eliminates this potential inconsistency is proposed and a model based estimator of their sampling variance is developed. The performance of the constrained estimator is quantified against six criteria and a joint maximum likelihood estimator in simulated sampling from 15 populations with three combinations of permanent and temporary samples, four to six categorical class attributes, and constant size between sampling dates. Bias of the constrained estimators was negligible but larger than for joint maximum likelihood estimators. Mean absolute deviations and variances of constrained estimators were generally at par with the joint estimators. Constrained estimators of root mean square errors and achieved coverage of nominal confidence intervals of constrained estimators were occasionally better. A generalized variance function for the constrained estimates of change is provided as a computational shortcut.     

Development of monitoring technology for airborne particulate matter

Particulate matter suspended in the air has adverse effects onhuman health. Its level of concentration is an important parameter in evaluating the degree of hazard it poses to the atmosphere. Conventional methods used in measuring particulatematter are often filter-based, which indicates some disadvantagesbecause such a base requires labor and time. In this study, to achieve real-time measurements, a new electrical method was developed for measuring PM10 and PM2.5 concentrations. The basicprinciple is to electrically charge particles passing through thePM inlet using a corona charger and measure the currents createdby charged particles to obtain the number concentration of particulate matter. A new type inlet based on the particle cupimpactor configuration was designed and its performance was evaluated. A unipolar diffusion charger was developed and thecharger's efficiency was determined experimentally in terms ofPn, which represents the penetration through the charger,P, times the average charge number acquired by a particle,n, for different particle sizes. The correlation was constructed between the PM10 (or the PM2.5) mass concentrationsand the electrical currents due to particles, which were chargedby the diffusion charger.     

Laboratory and Field Assessment of Arsenic Testing Field Kits in Bangladesh and West Bengal, India

High concentrations of arsenic in ground waters in West Bengal and Bangladeshhave become a major cause for concern in recent years. Given the enormity and the severity of the problemof arsenic poisoning, a task of evaluating the commercially available arsenic detection field kits for their capabilities was undertaken. In the light of the findings, generic specificationswere recommended which could form the basis forindigenous manufacture of these kits in the arsenic affected countries. This article presents the results of the laboratory and fieldevaluation conducted in Bangladesh and West Bengalof five arsenic testing field kits. The salient features of the kits, their merits and limitationshave been brought out. Based on the criteria of kitdesign, quality of chemicals used, colourcomparator charts, detection range, time required for analysis, cost etc., a comparative ranking ofthe kits has been made to facilitate the choice of the kit to meet specific requirements.     

Recycling of petroleum-contaminated sand

The environmental impact of using petroleum-contaminated sand (PCS) as a substitute in asphalt paving mixtures was examined. An appreciable component of PCS is oily sludge, which is found as the dregs in oil storage tanks and is also produced as a result of oil spills on clean sand. The current method for the disposal of oily sludge is land farming. However, this method has not been successful as an oil content of < 1% w/w is required, and difficulty was encountered in reaching this target. The reuse of the sludge in asphalt paving mixtures was therefore considered as an alternative. Standard tests and environmental studies were conducted to establish the integrity of the materials containing the recycled sludge. These included physical and chemical characterization of the sludge itself, and an assessment of the mechanical properties of materials containing 0%, 5%, 22% and 50% oily sludge. The blended mixtures were subjected to special tests, such as Marshall testing and the determination of stability and flow properties. The experimental results indicated that mixtures containing up to 22% oily sludge could meet the necessary criteria for a specific asphalt concrete wearing course or bituminous base course. To maximize the assay from the recycled material, the environmental assessment was restricted to the 50% oily sludge mixture. Leachates associated with this particular mixture were assayed for total organic residue and certain hazardous metal contaminants. The results revealed that the organics were negligible, and the concentrations of the metals were not significant. Thus, no adverse environmental impact should be anticipated from the use of the recycled product. Our research showed that the disposal of oily sludge in asphalt paving mixtures could possibly yield considerable savings per tonne of asphalt concrete, and concurrently minimize any direct impact on the environment.     

Reduction and avoidance of lubricant mist demands an integrated assessment approach

A case study to identify major factors for lubricant mist exposure covered 15 metal machining sites. The investigation included milling, turning, drilling and grinding applications. Systematic analysis considered all relevant data concerning the machine tool, the lubricant and the suction plant. The efficiency of the implemented maintenance program at the installed filter systems was checked by concentration measurements immediately before and after service. All performed measurements of lubricant aerosol and vapor loads upstream and downstream of the installed filter systems were carried out according to VDI 2066 and BIA 3110, respectively. The selection criteria for the sites to be investigated, the systematic nature of the data acquisition and the procedure of the analysis are demonstrated in detail by performing comparisons between selected applications using emulsions and those employing straight oil for lubrication. The results of the study identify recirculation of ventilated air as the major source of workplace exposure to airborne lubricant emissions. More than 60% of the demisters investigated emit air at total lubricant loads (aerosols and vapor) above the limit of 20 mg m-3 at any time of operation; which also means immediately after service. A common reason for exceeded aerosol loads in recirculated air is e.g. the fact that the type of filter system applied is often not suitable for the separation problem. Loads of lubricant vapor are usually higher at the processes which use water emulsions as lubricant. In a quarter of the cases the limits were exceeded solely due to high vapor loads even immediately after service. The exposure can be reduced by replacing the lubricant, installation of a vapor separation plant or avoiding air recirculation. Maintenance time of the demisting system and aerosol separation efficiency of state-of-the-art demisting systems can be expanded by implementation of enhanced preliminary filter stages. This study confirms that appropriate service measures lower both aerosol emissions and lubricant vapor concentrations due to the reduction of exposed oil-wetted surfaces. The performed measurements show no significant relationship between loads of airborne lubricants and the type of machining process. Therefore, investigations at a much more detailed level have to be performed. However, the individual assessment of any workplace due to the complex situation remains essential.     

8-氨基喹啉-5-偶氮-对苯酚荧光光度法测定微量铬(Ⅵ)

在盐酸介质中,铬(Ⅵ)与AQAPOH形成可被氯仿萃取的荧光化合物,其λex/λem=295nm/400nm.线性范围为0-1.0μg Cr(Ⅵ)/25ml(水相),检测限为0.7μg/L.除Mn(Ⅶ)外,常见金属离子无干扰,可在数千倍Cr(Ⅲ)存在下测定废水中微量铬(Ⅵ).初步探讨了荧光反应的机理.     

江苏省环境监测系统进行监测分析质量大检查

由江苏省环保局、省监测站具体领导、并由省和各市监测站质量管理人员组成的“江苏省环境监测质量管理组”,于今年9月1日至13日分南北两片对全省十一个省辖市监测站实验室的监测分析质量进行了全面检查。     

湖北省召开大气环境监测网站工作会议

会议对全省网络建设基本情况、网站设置内容落实情况、监测质量保证及网站建设中存在的问题等作了全面总结,讨论和修订了《湖北省大气环境例行监测技术规定》.省中心站还表扬了多年来不间断监测、上报数据齐全、报表清晰和规矩的网站,同时对今后网站工作提出了要求.     

水处理中光催化反应器的研究进展

TiQ2光催化技术能有效降解水中有机污染物并使之彻底矿化，并且具有很好的杀菌和抑制病毒活性的作用，是一种极具应用前景的水处理技术．而实用高效的光催化反应器是光催化技术工业化应用需要解决的关键技术之一．本文就目前国内外光催化反应器的研究现状做了总结和评述，并指出了目前存在的问题和今后主要的研究方向．