全文获取类型
收费全文 | 123篇 |
免费 | 1篇 |
国内免费 | 2篇 |
专业分类
安全科学 | 2篇 |
废物处理 | 5篇 |
环保管理 | 8篇 |
综合类 | 5篇 |
基础理论 | 26篇 |
污染及防治 | 50篇 |
评价与监测 | 21篇 |
社会与环境 | 9篇 |
出版年
2022年 | 6篇 |
2021年 | 7篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2017年 | 4篇 |
2016年 | 10篇 |
2015年 | 6篇 |
2014年 | 8篇 |
2013年 | 11篇 |
2012年 | 9篇 |
2011年 | 10篇 |
2010年 | 10篇 |
2009年 | 10篇 |
2008年 | 10篇 |
2007年 | 5篇 |
2006年 | 5篇 |
2005年 | 1篇 |
2002年 | 1篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1993年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
排序方式: 共有126条查询结果,搜索用时 219 毫秒
111.
Alkaline CuO oxidation has been used on molecular-level analyses of phenols from organic matter in the last decades. This method, originally developed by Hedges and Ertel [Hedges, J.I., Ertel, J.R., 1982. Characterization of lignin by gas capillary chromatography of cupric oxide oxidation products. Anal. Chem. 54, 174-178] has several drawbacks that have limited is wider utilization. In this paper, we propose a modification of the method using a solid-phase extraction (SPE) instead of a liquid-liquid extraction. The SPE procedure using C18 cartridges was optimized to obtain high recoveries. The sequential elution with acetonitrile and methanol was found to be the most appropriate procedure. Recoveries of the 12 phenols in individual standard solutions ranged from 84% to 113% with relative standard deviation (RSD) lower than 12%. Experiments with a mixed standard solution highlighted the competition between the different phenols for the adsorbing sites. Recoveries decreased with polarity, reaching 30% for p-hydroxybenzoic acid when present at a concentration of 2.5 x 10(-3)M. A sample soil subjected to a CuO oxidation was used to test the reproducibility of the SPE method and good results were achieved, RSD ranged between 0.4% and 28.3%. The performance of the CE method was also evaluated by correlation coefficients (higher than 0.9920), linearity (higher than 99.902%) and limit of detection (ranging from 2.64 x 10(-6) to 1.25 x 10(-5)M). SPE procedure presents several advantages such as fast sample preparation, good recoveries, good accuracy, low sample handling and safety improvement due to reduced solvent/sample exposure and glassware management. 相似文献
112.
113.
Oscar Amin Laura Comoglio Carla Spetter Claudia Duarte Ra��l Asteasuain Rub��n Hugo Freije Jorge Marcovecchio 《Environmental monitoring and assessment》2011,175(1-4):63-73
The study deals with the determination of physico-chemical parameters, inorganic nutrients, particulate organic matter, and photosynthetic pigments on a monthly basis during an annual cycle from nine sampling sites of the coastal zone of a high-latitude ecosystem (Tierra del Fuego, Argentina). Nitrites and phosphates concentrations were similar to other systems of the south Atlantic coast (median, 0.30 and 1.02 ??M, respectively), while nitrates were higher in all sampling periods (median, 45.37 ??M), and silicates were significantly smaller (median, 7.76 ??M). Chlorophyll a and phaeopigments have shown median values of 0.38 and 0.85 mg m???3, respectively, while saturated values of dissolved oxygen were recorded throughout the study. The analysis reflected that nutrient enrichment seems to be linked to an anthropogenic source, the presence of peatlands areas, and a sink of Nothofagus pumilio woods. The area could be characterized in three zones related to (1) high urban influence, (2) natural inputs of freshwater, and (3) mixed inputs coming from moderate urban impacts. 相似文献
114.
Alexander Tilley Ariadna Burgos Agustinha Duarte Joctan dos Reis Lopes Hampus Eriksson David Mills 《Ambio》2021,50(1):113
A greater understanding of gendered roles in fisheries is necessary to value the often-hidden roles that women play in fisheries and households. We examine women’s contributions to household food and income using focus group discussions, market surveys, and landings data in six communities in Timor-Leste. Women were actively fishing more days per month than men. Gleaning was the most frequent activity and 100% of trips returned with catch for food and/or income. Mollusc and crab catches were common and exploitation appeared targeted on a dynamic reappraisal of changing food values and changing estimates of group needs. With as many as 80% of households in coastal areas involved in fishing, and at least 50% of women fishing, this highlights the current lack of women’s engagement as a critical gap in fisheries management approaches. The current androcentric dialogue limits social-ecological understanding of these systems and the potential for their effective stewardship.Electronic supplementary materialThe online version of this article (10.1007/s13280-020-01335-7) contains supplementary material, which is available to authorized users. 相似文献
115.
Eiró Luciana Guimarães Ferreira Maria Karolina Martins Frazão Déborah Ribeiro Aragão Walessa Alana Bragança Souza-Rodrigues Renata Duarte Fagundes Nathalia Carolina Fernandes Maia Lucianne Cople Lima Rafael Rodrigues 《Environmental science and pollution research international》2021,28(28):37001-37015
Environmental Science and Pollution Research - Lead (Pb) is one of the most toxic and abundant elements in the earth’s crust, which is pointed out that the intoxication caused by it... 相似文献
116.
Duarte Gilson Tristão de Alencar Nääs Irenilza da Silva Lima Nilsa Duarte 《Environmental science and pollution research international》2021,28(45):63977-63988
Environmental Science and Pollution Research - A large portion of urban emissions in developing countries come from old gasoline vehicles driven in metropolitan areas. The present study aimed to... 相似文献
117.
Kendall M Duarte A Rocha-Santos T Hamilton R Williams I 《Journal of environmental monitoring : JEM》2002,4(6):890-896
Total suspended particulate (TSP) samples were collected weekly over a period of one year at four European sites during 1995/6. Two sites were in London-a Central London site (CL, St Paul's Cathedral) and a suburban North London site (NL, Bounds Green); the other two sites were in Porto, Portugal and Vienna, Austria. TSP was collected using a low volume sampler. Organic carbon (OC) and elemental carbon (EC) concentrations were measured using a thermal-optical carbon analyser. Parallel samplers collected TSP for subsequent GC-MS analysis of thirty-nine combustion-associated organic compounds; 16 polyaromatic hydrocarbons (PAHs) and 23 n-alkanes. OC and EC correlate well at all sites (r2 = 0.39-0.65), although the London inter-site correlations were low, suggesting that local sources of OC and EC have a significant influence on local concentrations. Concentrations do not vary widely across the four urban sites, despite the significant differences in urban characteristics. Seasonal patterns of OC:EC ratios were similar at the London and Vienna sites, with highest ratios in autumn and winter, and annual mean OC:EC ratios were identical at these sites. The Carbon Preference Index (CPI) indicated vehicle emissions to have a stronger influence over particulate concentrations at the Vienna and central London sites; there was a stronger biogenic signature in north London and Porto. In addition, two PAH compounds (pyrene and fluoranthene) previously associated with diesel exhaust, were correlated with OC and EC concentrations at the London and Vienna sites. 相似文献
118.
Ana Marçalo Luísa Mateus José Henrique Duarte Correia Pedro Serra Rob Fryer Yorgos Stratoudakis 《Marine Biology》2006,149(6):1509-1518
Observations from the purse seine fishery off northern Portugal are used to describe the early dynamics of sardine (Sardina pilchardus) stress reactions and identify likely stressors during the commercial fishing operation. Sardine blood and muscle were sampled from the onset of fishing (school identification and encircling) to the end of fish transfer onboard (90–120 min later). The evolution of haematocrit, haemoglobin, cortisol, glucose, ionic concentrations, ATP and its catabolites were modelled using linear mixed models as a function of time spent in the net, biological (sex, reproductive state and condition) and operational variables (catch, light level and phase of fishing operation). Significant linear trends with time were detected for most stress variables and mean concentrations after 2 h in the net were similar to literature values corresponding to acute stress reactions for teleosts. Biological variables were rarely significant and explained a small proportion of variation, while operational variables were never significant. For each stress variable, levels varied considerably between trips but the temporal evolution was common across trips. Random trip effects were uncorrelated among most biochemical variables, suggesting that distinct factors affected each stress variable during the sampled trips. However, the linear trend with time spent in the net observed for most stress variables indicates that the duration of the fishing operation is an important stressor in purse seine fishing due to the progressive water volume restriction, crowding and manipulation associated to the fishing method. 相似文献
119.
La Fuente Carla I. A. de Souza Andressa Tamyris Tadini Carmen C. Augusto Pedro Esteves Duarte 《Journal of Polymers and the Environment》2021,29(6):1908-1920
Journal of Polymers and the Environment - In this study cassava starch modified by ozone technology and cellulose nanofibres were used to produce films. These nanocomposites were produced by... 相似文献
120.
Alvarenga P Palma P Gonçalves AP Fernandes RM de Varennes A Vallini G Duarte E Cunha-Queda AC 《Environmental geochemistry and health》2008,30(2):95-99
An acid metal-contaminated soil from the Aljustrel mining area (a pyrite mine located in SW Portugal in the Iberian Pyrite
Belt) was subjected to chemical characterisation and total metal quantification (Cd, Cr, Cu, Ni, Pb and Zn). Water-soluble
metals were determined and a sequential extraction procedure was used to investigate metal speciation. Two bioavailable metal
fractions were determined: a mobile fraction and a mobilisable fraction. Soil ecotoxicity was studied using a battery of bioassays:
plant growth test and seed germination with cress (Lepidium sativum L.), earthworm (Eisenia fetida) mortality, E. fetida avoidance behaviour, luminescent inhibition of Vibrio fischeri and Daphnia magna immobilisation. Although the total content of Cu, Zn and Pb in the soil was large (362, 245 and 1,250 mg/kg dry matter, respectively),
these metals were mostly structurally bound (87% for Cu, 81% for Zn and 89% for Pb) and, therefore, scarcely bioavailable.
Nonetheless, the D. magna immobilization test using soil leachate showed an EC50 (48 h) of 36.3% (v/v), and the luminescent inhibition of V. fischeri presented an EC20 (15 min) of 45.2% and an EC20 (30 min) of 10.7% (v/v), suggesting a considerable toxic effect. In the direct exposure bioassays, E. fetida avoided the mine soil at the highest concentrations (50%, 75% and 100% v/v). At the same soil concentrations, cress showed
negligible growth. The results suggest the need to use a battery of toxicity tests, in conjunction with chemical methods,
in order to assess the quality of mine-contaminated soils correctly. 相似文献