Determination of first-order landfill gas modeling parameters and uncertainties

Using first-order kinetic empirical models to estimate landfill gas (LFG) generation and collection rates is well recognized in the literature. The uncertainty in the estimated LFG generation rates is a major challenge in evaluating performance of LFG collection and LFG to energy facilities. In this investigation, four methods for quantifying first-order LFG generation model parameters, methane generation potential, L₀, and methane generation rate constant, k, were evaluated. It was found that the model is insensitive to the approach taken in quantifying the parameters. However, considering the recognition of using the model in the literature, the optimum method to estimate L₀ and k is to determine L₀ using disposed municipal solid waste composition and laboratory component specific methane potential values. The k value can be selected by model fitting and regression using the first-order model if LFG collection data are available. When such data are not available, k can be selected from technical literature, based on site conditions. For five Florida case-study landfills L₀ varied from 56 to 77 m³ Mg⁻¹, and k varied from 0.04 to 0.13 yr⁻¹ for the traditional landfills and was 0.10 yr⁻¹ for the wet cell. Model predictions of LFG collection rates were on average lower than actual collection. The uncertainty (coefficient of variation) in modeled LFG generation rates varied from ±11% to ±17% while landfills were open, ±9% to ±18% at the end of waste placement, and ±16% to ±203% 50 years after waste placement ended.     

Upper trapezius fatigue in carpet weaving: the impact of a repetitive task cycle

Introduction. Shoulder disorders are one of the most prevalent musculoskeletal disorders among carpet weavers. The most important cause of these disorders is muscle fatigue. The aim of the present study is to investigate the effect of carpet weaving characteristics on upper trapezius (UTr) muscle fatigue during a task cycle. Method. In this cross-sectional study, 9 women and 3 men participated. During an 80-min cycle of carpet weaving, a times-series model was applied to assess electromyography amplitude and frequency changes. Result. According to the joint analysis of electromyogram spectrum and amplitude method, the participants experienced 0% force decrease, 0.9% recovery, 18% force increase and 72% fatigue in the left UTr. Furthermore, the rates of force decrease, recovery, force increase and fatigue in the right UTr were 18%, 18%, 18% and 45%, respectively. Fatigue in the right and the left UTr was reported to be the dominant state during one carpet weaving task cycle. Conclusion. Task cycle appears to have a significant impact on UTr fatigue in participants, and UTr fatigue can be considered a serious risk factor in shoulder musculoskeletal disorders. Hence, further studies should focus on better workstations and work–rest periods during various subtasks.     

Application of a multi-plant QRA: A case study investigating the risk impact of the construction of a new plant on an existing chemical plant's risk levels

The construction of chemical clusters whereby a variety of chemical plants are located next to each other provides great economic benefits. However, in such clusters, due to the mere scale on which hazardous materials are processed, stored and handled, the potential of various accidents is much higher than in single companies. Furthermore, the close proximity of process installations and storage tanks in such areas gives rise to the risk of domino effects. Therefore, land use planning and layout design has always been a challenge within such clusters.In this paper, a Quantitative Risk Assessment (QRA) is carried out and used as a decision making tool to evaluate the acceptability of constructing a new chemical plant adjacent to an existing one. For this purpose, standard parameters such as individual risk and societal risk were quantified, before and after the new plant would come into operation. Given the experience of past accidents in the process industries, the likelihood of domino accidents in the two neighboring plants has also been analyzed.     

A risk-based decision making approach to determine fireproofing requirements against jet fires

API Publication 2218 is one of the most referred practices for fireproofing of onshore structural supports. Despite the extensive citation, it solely considers the effects of pool fire and rarely addresses jet fire outcomes. This absence of an explicit approach is common among all the other major references. Therefore, the basic objective of this paper is to introduce a new approach for determination of the necessity for fireproofing of structural supports against jet fires. For this purpose, the flame geometry and duration of jet fires are simulated for different leak sizes in identified fire potential sources. Then, following a worst-case analysis, those structures that may be impinged by long enough flames are screened out and then characterized by maximum impingement duration for fireproofing purpose. Moreover, each structure is assigned by a failure rate to estimate the degree of vulnerability through a detailed risk assessment. In this regard a new explanatory term called Structure Failure Rate (SFR) is introduced. This approach also enables researchers to quantify the effect of other protective systems (fire and gas detection, emergency shut-down, depressurization and firewalls) on the level of required fireproofing.     

Cl~-、SO_4~(2-)和PO_4~(3-)对异养反硝化污泥的胁迫效应

反硝化菌是反硝化作用的驱动者,探明Cl~-、SO_4~(2-)和PO_4~(3-)对异养反硝化污泥(HDS)的胁迫效应,有助于含盐废水生物脱氮技术的研发和优化.选用硝酸盐还原酶(周质酶)和碱性磷酸酯酶(胞内酶)作为指标,考察了不同Cl~-、SO_4~(2-)和PO_4~(3-)浓度对HDS酶活的影响;通过观测HDS中的活菌水平和细胞形态,考察了不同Cl~-、SO_4~(2-)和PO_4~(3-)浓度对HDS微生物细胞结构的影响.结果表明,Cl~-、SO_4~(2-)和PO_4~(3-)对HDS硝酸盐还原酶的半抑制浓度分别为0.15、0.12和0.05mol/L,对碱性磷酸酯酶的半抑制浓度为1.14、0.75和0.49mol/L;高浓度Cl~-、SO_4~(2-)和PO_4~(3-)导致HDS微生物细胞膜结构破损,通透性增加,细胞物质外泄.阴离子对HDS的胁迫可分为渗透胁迫和电荷胁迫,渗透胁迫造成HDS中功能酶失活,电荷胁迫造成HDS中细胞膜破损,细胞物质外泄.     

Monitoring of organic pollutants in marine environment by semipermeable membrane devices and mussels: accumulation and biochemical responses

This study involves the monitoring of organic pollutants using transplanted mussels (Mytilus galloprovincialis) as bioindicator organisms and semipermeable membrane devices (SPMDs) as passive samplers. Mussels and SPMDs were deployed to marinas, shipyards and shipbreaking yards on the coastal area of Turkey and retrieved after 60 days. Polycyclic aromatic hydrocarbons (PAH), polychlorinated biphenyls (PCB) and organochlorine pesticide (OCP) compounds were analysed with high-resolution GC-MS. Total PAH concentrations in SPMDs and mussels ranged from 200 to 4740 ng g sampler^?1 and from 7.0 to 1130 ng g^?1 in wet weight (ww). PCB and OCP concentrations in SPMDs changed between 0.04–200 and 4.0–26 ng g sampler^?1, respectively. The highest PCB (190 ng g^?1 ww) and OCP (200 ng g^?1 ww) concentrations in mussels were measured at shipyard stations. A strong correlation was observed between the PAH and PCB concentrations in SPMDs and mussels. Enzyme assays (acetylcholinesterase, ethoxyresorufin-O-deethylase, glutathione S-transferase, glutathion reductase and carboxylesterase activities) were performed as biomarkers to reveal the effects of pollution on the mussels. There was no clear relationship found between the enzyme levels and the pollutant concentrations in mussels. Integrated biomarker responses were calculated to interpret the overall effect of pollutants.

     

Sequential UV-biological degradation of chlorophenols

The sequential UV-biological degradation of a mixture of 4-chlorophenol (CP), 2,4-dichlorophenol (DCP), 2,4,6-trichlorophenol (TCP), and pentachlorophenol (PCP) was first tested with each pollutant supplied at an initial concentration of 50 mg l(-1). Under these conditions, the chlorophenols were photodegraded in the following order of removal rate: PCP>TCP>DCP>CP with only CP and DCP remaining after 40 h of irradiation. The remaining CP (41 mg l(-1)) and DCP (13 mg l(-1)) were then completely removed by biological treatment with an activated sludge mixed culture. Biodegradation did not occur in similar tests conducted with a non-irradiated mixture due to the high microbial toxicity of the solution. UV treatment lead to a significant reduction of the phytotoxicity to Lipedium sativum but no further reduction of phytotoxicity was observed after biological treatment. Evidence was found that the pollutants were partially photodegraded into toxic and non-biodegradable products. When the pollutants were tested individually (initial concentration of 50 mg l(-1)), PCP, TCP, DCP, 4-CP were photodegraded according to first order kinetic model (r2>99) with half-lives of 2.2, 3.3, 5.7, and 54 h, respectively. The photoproducts were subsequently biodegraded. This study illustrates the potential of UV as pre-treatment for biological treatment in order to remove toxicity and enhance the biodegradability of organic contaminants. However, it also shows that UV treatment must be carefully optimized to avoid the formation of toxic and/or recalcitrant photoproducts and results from studies conducted on single contaminants cannot be extrapolated to mixtures.     

土地利用变化下的生态系统服务敏感性研究——以克里雅绿洲为例

通过剖析传统的敏感性分析法,提出交叉敏感性概念,评价生态服务价值对土地利用类型转换的响应性。以克里雅绿洲为研究区域,以1991、2002 和2011 年三期遥感影像数据为基本信息源,运用交叉敏感性分析,计算生态系统服务价值对土地利用类型转换的敏感性,确定生态系统日趋敏感的土地利用变化过程,为土地管理对策提供参考依据。研究结果表明:20 a来,克里雅绿洲生态服务价值较敏感的土地利用转换类型相对稳定,主要集中在湿地和水体向荒漠和低覆盖度草地的转换;与1991 和2011 年相比,2002 年的交叉敏感性系数普遍上升,这主要是因为湿地、水体面积的减少加剧了研究区的生态脆弱性,从而表现出更大的敏感性;湿地和水体向耕地转换的交叉敏感性一直处于上升趋势,并不断接近于-1,表明生态服务价值对高强度的人为活动变得越来越敏感,从而警示地方管理部门采取必要措施制止此种转换的持续。     

SWOT analysis for socio-ecological landscape variation as a precursor to the management of the mountainous Kanshi watershed,Salt Range of Pakistan

Variations in geo-environmental attributes differ strongly from those of urban anthropogenic structures. Similarly, these types of structures are self-directed and arranged and prone to abrupt process-related changes and modifications. Thus, there are many reasons why planned urbanization forms in association with disturbances in ecosystem mobility. The current research highlights these variations in the context of social–cultural assessments within the Jhelum River watershed, which strongly expresses urbanization structure development mechanisms. The climate ranges from semi-arid to subhumid subtropical and sub-mountainous climate, though the extreme temperatures may rise as high as 49.4°C in June and may drop as low as ?1.6°C in January. The rainfall is low in the southwest and gradually increases towards the northeast, whereas the Salt Range is the major topographic feature that controls climatic impacts and promotes sustainable development. Cross-disciplinary methods are adopted in this investigation to assess the social–ecological landscape system (SELS) in terms of its mobility and degree of urbanization. The Sustainable Development Goals of the 2030 Agenda recognize that human livelihoods and the management of natural resources cannot be addressed separately. Investing in the sustainability of mountain communities and ecosystem conservation and protection will provide benefits for humanity as a whole. It pertains to the commensurate development of the SELS and its response to interruptions. Thus, a reliable SWOT analysis for management approaches is introduced that may enable the development of competencies that promote and lead towards rapid improvements in the sustainability of retrograde urban infrastructure, including watersheds.