Monitoring of growth and physiological activities of biofilm during succession on polystyrene from activated sludge under aerobic and anaerobic conditions

The present research work monitored the successive biofilm development and its catabolic role in the degradation of polystyrene (PS). PS material was artificially colonized with biofilm by incubating it with activated sludge under aerobic and anaerobic conditions. Biofilm formation was monitored by gravimetric weight analysis, spectrophotometric absorbance technique, heterotrophic plate count, and scanning electron microscopy under aerobic and anaerobic conditions. The wet weight (1.59 and 1.17 g) and dry weight (0.41 and 0.08 g) of a biofilm showed a significant constant increase under aerobic and anaerobic conditions, respectively, from first till 9 weeks of incubation. Plate count of the selected bacteria (Escherichia coli, Salmonella typhimurium, Shigella dysenteriae, Pseudomonas aeruginosa) considerably declined (90–99 %) in the biofilm after seventh and fifth weeks of incubation under aerobic and anaerobic conditions, respectively, indicating a positive shift from pathogenic to beneficial microbial community. While most probable number index of fecal coliforms and E. coli in the sludge showed more reduction (98 and 99 %) under aerobic as compare to anaerobic conditions (86 and 91 %) after 9 weeks of biofilm formation on PS cubes. Correspondingly, the decreasing levels of chemical oxygen demand and biochemical oxygen demand (up to 73 %) showed signs of sludge digestion. Scanning electron microscope coupled with energy dispersive X-ray spectroscope revealed nature of PS media containing high carbon content. However, biofilm development proved to be involved in the biochemical transformation of the PS medium as indicated by Fourier transform infrared spectroscopy.     

Monitoring the impact of urban effluents on mineral contents of water and sediments of four sites of the river Ravi, Lahore

We assessed the impact of urban effluents on the concentrations of selected minerals (Cd, Cr, Cu, Fe, Pb, Zn, Mn, Ni, and Hg) in river Ravi before and after its passage through Lahore city. Water and sediment samples were collected from three lowly to highly polluted downstream sites (Shahdera (B), Sunder (C), and Balloki (D)) alongside the least polluted upstream site (Siphon (A)) during high and low river flow seasons. All the mineral concentrations increased up to site C but stabilized at site D, showing some recovery as compared to the third sampling site. The trend of mean mineral concentration was significantly higher during the low than the high flow season at all the sites. The mean Hg concentrations approached 0.14 and 0.12 mg/l at site A which increased (%) up to 107 and 25 % at site B, 1,700 and 1,317 % at site C, and 1,185 and 1,177 % at site D during low and high river flows, respectively. All mineral concentrations were much higher in the sediment than the water samples. Mean Cd (917 %), Cr (461 %), Cu (300 %), Fe (254 %), Pb (179 %), Zn (170 %), Mn (723 %), Ni (853 %), and Hg (1,699 %) concentrations were higher in riverbed sediments sampled from site C in comparison with the sample collected at site A during low flow season. The domestic and industrial discharges from Lahore city have created undesirable water qualities during the low river flow season. As majority of the mineral levels in the river Ravi were higher than the permissible and safe levels, this is of immediate concern for riverine fish consumers and the users of water for recreation and even irrigation. The use of these waters may pose health risks, and therefore, urgent intervention strategies are needed to minimize river water pollution and its impact on fish-consuming communities of this study area and beyond.     

Assessment of Groundwater Quality in a Structurally Deformed Granitic Terrain in Hyderabad, India

Geochemical study of groundwater from a structurally deformed granitic terrain near Hyderabad (India) was carried out to understand and evaluate the hydrogeochemical processes and quality of groundwater. Several trace elements (Fe, Mn, Be, Al, V, Cr, Co, Ni, Cu, Zn, As, Sr, Mo, Cd, Sb, Ba, Pb, U) along with major ions and minor elements were precisely estimated in shallow and drilled wells to know the suitability of water for drinking and irrigation purposes. Analytical data shows that pH and major ion chemistry in dug wells and bore wells do not vary significantly, while some trace elements (Fe, Mn, Al, Be, Co, Pb, U and Zn) vary in dug wells and bore wells, which can be attributed to differential mineral weathering and dissolution/precipitation reactions along fractures/joints. Although the water is not potable, it was found to be suitable for irrigation with little danger in the development of harmful level of exchangeable sodium. It is inferred that the chemical composition of the groundwater in this region is likely to have its origin from silicate weathering reactions and dissolution/precipitation processes supported by rainfall and groundwater flow.     

Spatio-temporal variations in water quality of Nullah Aik-tributary of the river Chenab, Pakistan

This study reports the spatio-temporal changes in water quality of Nullah Aik, tributary of the Chenab River, Pakistan. Stream water samples were collected at seven sampling sites on seasonal basis from September 2004 to April 2006 and were analyzed for 24 water quality parameters. Most significant parameters which contributed in spatio-temporal variations were assessed by statistical techniques such as Hierarchical Agglomerative Cluster Analysis (HACA), Factor Analysis/Principal Components Analysis (FA/PCA), and Discriminant Function Analysis (DFA). HACA identified three different classes of sites: Relatively Unimpaired, Impaired and Less Impaired Regions on the basis of similarity among different physicochemical characteristics and pollutant level between the sampling sites. DFA produced the best results for identification of main variables for temporal and spatial analysis and separated eight parameters (DO, hardness, sulphides, K, Fe, Pb, Cr and Zn) that accounted 89.7% of total variations of spatial analysis. Temporal analysis using DFA separated six parameters (E.C., TDS, salinity, hardness, chlorides and Pb) that showed more than 84.6% of total temporal variation. FA/PCA identified six significant factors (sources) which were responsible for major variations in water quality dataset of Nullah Aik. The results signify that parameters identified by statistical analyses were responsible for water quality change and suggest the possibility of industrial, municipal and agricultural runoff, parent rock material contamination. The results suggest dire need for proper management measures to restore the water quality of this tributary for a healthy and promising aquatic ecosystem and also highlights its importance for objective ecological policy and decision making process.     

Development of a novel mathematical model using a group contribution method for prediction of ionic liquid toxicities

A new mathematical model has been developed that expresses the toxicities (EC₅₀ values) of a wide variety of ionic liquids (ILs) towards the freshwater flea Daphnia magna by means of a quantitative structure-activity relationship (QSAR). The data were analyzed using summed contributions from the cations, their alkyl substituents and anions. The model employed multiple linear regression analysis with polynomial model using the MATLAB software. The model predicted IL toxicities with R² = 0.974 and standard error of estimate of 0.028. This model affords a practical, cost-effective and convenient alternative to experimental ecotoxicological assessment of many ILs.     

Influence of hydrological runoff and catchment characteristics on accumulation floatable litter load in gross pollutant trap (GPT)

Journal of Material Cycles and Waste Management - The accumulation of floatable litter load captured in gross pollutant trap (GPT) due to the hydrological runoff has become challenging due to rapid...     

CLIMATOLOGICAL WATERSHED CALIBRATION1

ABSTRACT: This study tests the hypothesis that climatic data can be used to develop a watershed model so that stream flow changes following forest harvest can be determined. Measured independent variables were precipitation, daily maximum and minimum temperature, and concurrent relative humidity. Computed variables were humidity deficit, saturated vapor pressure, and ambient vapor pressure. These climatic variables were combined to compute a monthly evaporation index. Finally, the evaporation index and monthly precipitation were regressed with measured monthly stream flow and the monthly estimates of stream flow were combined for the hydrologic year. A regression of predicted versus measured annual stream flow had a standard error of 1.5 inches (within 6.1 percent of the measured value). When 10, 15, and 20 years of data were used to develop the regression equations, predicted minus measured stream flow for the last 7 years of record (1972–1978) were within 16.8, 11.5, and 9.7 percent of the measured mean, respectively. Although single watershed calibration can be used in special conditions, the paired watershed approach is expected to remain the preferred method for determining the effects of forest management on the water resource.     

Managing post-conflict demolition wastes in Gaza Strip: a case study on May 2021 conflict

Gaza Strip is considered as one of the armed conflicts prone areas in Middle East. Several intensive conflicts occurred in Gaza Strip in 2008, 2012, 2014 and 2021. These conflicts caused massive destroying the infrastructures, facilities, and buildings, which affected all services and activities in Gaza Strip. One of the major post-conflict issues in Gaza strip is the management of resulted demolition waste including its removal, sorting, recycling, and material recovery. In May 2021, over than 370,000 tons of demolition waste composed of rubbles and debris was generated during 11 days of armed conflict. The accumulated previous experience of rubbles and debris removal and recycling in Gaza Strip supported to perform a quick management approach for safe removal of the post-conflict demolition waste and reuse/recycle the resulted waste materials in various applications. The sorting and transporting process of concreate and non-concreate rubble elements of the waste were carried out in cooperation between local and international agencies as emergency recovery-funded projects. The most proportion of rubbles are concrete aggregates, thus, the material recovery was conducted through crushing process for concrete rubbles and then reusing it for road rehabilitation or producing concrete building blocks. The large concrete blocks reused to be placed for shoreline protection for specific area along Gaza beach. The recycling of post-conflict demolition waste management projects in Gaza Strip brought economic and social benefits through the reuse and recycle of resources and creation of job opportunities. In conclusion, although the post-conflict demolition waste management is quite different from municipal/industrial waste management in Gaza Strip, it is conducted through applying similar techniques of disaster waste management in waste removal, and those of construction and demolition (C&D) waste management in sorting, crushing, and sieving for recycling.

     

Investigating effect of proton-exchange membrane on new air-cathode single-chamber microbial fuel cell configuration for bioenergy recovery from Azorubine dye degradation

Environmental Science and Pollution Research - One of the biggest challenges of using single-chamber microbial fuel cells (MFCs) that utilize proton-exchange membrane (PEM) air cathode for...