Serial batch leaching procedure for characterization of coal fly ash

Although many leaching methods have been used for various purposes by research groups, industries, and regulators, there is still a need for a simple but comprehensive approach to leaching coal utilization by-products and other granular materials in order to estimate potential release of heavy metals when these materials are exposed to natural fluids. A serial batch characterization method has been developed at the National Energy Technology Laboratory that can be completed in 2–3 days to serve as a screening tool. The procedure provides an estimate of cumulative metals release under varying pH conditions, and leaching the sample at increasing liquid/solid ratios can indicate the rate at which this process will occur. This method was applied to eight fly ashes, adapted to the acidic or alkaline nature of the ash. The leachates were analyzed for 30 elements. The test was run in quadruplicate, and the relative standard deviation (RSD) was used as a measure of method reproducibility. RSD values are between 0.02 and 0.70, with the majority of the RSD values less than 0.3. The serial batch leaching procedure was developed as a simple, relatively quick, yet comprehensive method of estimating the risk of heavy metal release from fly ash when it is exposed to natural fluids, such as acid rain or groundwater. Tests on a random selection of coal fly ashes have shown it to be a reasonably precise method for estimating the availability and long-term release of cations from fly ash.     

Petroleum and hazardous chemical spills in Newark Bay, New Jersey, USA from 1982 to 1991

Newark Bay, New Jersey, is particularly vulnerable to ecological damage from petroleum and chemical spills, as a result of the enclosed nature and shallow depth of the bay, the high frequency of shipping traffic, and the numerous chemical and petroleum transfer terminals located alongs its shores. To evaluate the potential impacts to the natural resources of this coastal estuarine ecosystem, chemical and petroleum accidents reported to the US Coast Guard (USCG) between 1982 and 1991 were compiled to determine the frequency and volume of these incidents in Newark Bay and in each of its major tributaries. Records obtained from the USCG National Response Center's computerized database indicated that more than 1453 accidental incidents, resulting in the release of more than 18 million US gallons of hazardous materials and petroleum products, occurred throughout Newark Bay during this period of time. The bulk of the materials released to the aquatic environment consisted of petroleum products, specifically No. 6 Fuel Oil (103 spills, 12 829 272 US gal) and gasoline (207 spills, 48 816 US gal). The majority of the reported incidents occurred in the Arthur Kill and its tributaries, as well as in the Kill Van Kull and the Passaic River. The results of this study indicated that the accidental discharge of petroleum and hazardous chemicals represents a significant source of chemical pollution in Newark Bay. Based on the frequency of spills and the volume of materials released to the aquatic environment, it is likely that these events are having a deleterious effect on the Newark Bay ecosystem.     

Über die Entdeckung eines neuen riesigen Säugetiers im unteren Miozän Asiens

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Avian herbivory: an experiment, a field test, and an allometric comparison with mammals

Mechanistic studies on herbivore functional responses have largely taken place in mammals; very little has been done in herbivorous birds so far. Here we aim to fill that gap by experimentally quantifying the (short-term) functional response of a large avian herbivore, the Bewick's Swan (Cygnus columbianus bewickii). We explicitly distinguish between encounter-limited and handling-limited foraging by analyzing the results in the framework of the models of D. E. Spalinger and N. T. Hobbs, originally developed for mammalian herbivory. Bite size in captive swans was experimentally manipulated by varying sward height. The time interval between two bites increased with bite size, which supports the handling-limited model (process 3) and rejects the encounter-limited models (processes 1 and 2). Subsequently, we took the obtained functional response parameters into the field in order to predict, from measurements of sward height, (1) bite sizes, (2) handling times, and (3) short-term intake rates in free-ranging swans. Indeed, for all three variables, the observed values closely matched the experimentally based predictions. Finally, we review functional response parameters available in the literature on avian herbivores and scale them allometrically in relation to mammals. This analysis revealed that maximum bite sizes, and therefore maximum intake rates, in herbivorous birds are smaller than in herbivorous mammals. We hypothesize and provide evidence that birds compensate by longer daily foraging times.     

Estimating the quantity of solid waste generation in Oyo, Nigeria.

The study established waste multipliers that could be used in conjunction with the population figure of a city to estimate the quantity of solid waste generation in the developing world. Oyo, a traditional city in Nigeria was the focus of the study. Two sets of data were collected. The first was the information on the socio-economic attributes of residents obtained from 648 households through questionnaires administered using a systematic random sampling technique. The second was the measurement of waste generated in 25% of the households for a week in each of the 12 months of the year. The study established that 23.3% of the residents surveyed have educational qualifications beyond secondary school, with 51.2% engaged in occupations requiring very little or no formal education and 50.9% were in the low-income group. The daily per capita solid waste generation was 0.129 kg. The highest (9.8%) and lowest (6.5%) of the annual quantities of waste were produced in October and February, respectively. Similarly, 20.2% of the weekly generation was produced on Saturday and the 10.2% produced on Thursday was the lowest. Animal dung, which accounted for 18.0%, constituted the highest component of the total solid waste generated. The study further established that the organic component of the waste generation was 75.4%. The results of the regression analysis R2 significant at 0.001 showed that income, household size, social status, occupation, education and season of the year explained 88.8% of waste generation in Oyo. It was established that 50.90 tonnes of solid waste was generated per day in the city in 2005, and the daily generation in the year 2008 is estimated to be 55.20 tonnes. The study concluded that with an average annual population growth of 13 000 people for the town, an additional 1.3 acres of land will need to be legally acquired annually, implying that 10.92-19.68 hectares ill be required as dump site(s) over the next 20-30 years.     

Die Reste fossiler Tiere im Volksglauben und in der Sage

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