Serial batch leaching procedure for characterization of coal fly ash

Although many leaching methods have been used for various purposes by research groups, industries, and regulators, there is still a need for a simple but comprehensive approach to leaching coal utilization by-products and other granular materials in order to estimate potential release of heavy metals when these materials are exposed to natural fluids. A serial batch characterization method has been developed at the National Energy Technology Laboratory that can be completed in 2–3 days to serve as a screening tool. The procedure provides an estimate of cumulative metals release under varying pH conditions, and leaching the sample at increasing liquid/solid ratios can indicate the rate at which this process will occur. This method was applied to eight fly ashes, adapted to the acidic or alkaline nature of the ash. The leachates were analyzed for 30 elements. The test was run in quadruplicate, and the relative standard deviation (RSD) was used as a measure of method reproducibility. RSD values are between 0.02 and 0.70, with the majority of the RSD values less than 0.3. The serial batch leaching procedure was developed as a simple, relatively quick, yet comprehensive method of estimating the risk of heavy metal release from fly ash when it is exposed to natural fluids, such as acid rain or groundwater. Tests on a random selection of coal fly ashes have shown it to be a reasonably precise method for estimating the availability and long-term release of cations from fly ash.     

Estimating the quantity of solid waste generation in Oyo, Nigeria.

The study established waste multipliers that could be used in conjunction with the population figure of a city to estimate the quantity of solid waste generation in the developing world. Oyo, a traditional city in Nigeria was the focus of the study. Two sets of data were collected. The first was the information on the socio-economic attributes of residents obtained from 648 households through questionnaires administered using a systematic random sampling technique. The second was the measurement of waste generated in 25% of the households for a week in each of the 12 months of the year. The study established that 23.3% of the residents surveyed have educational qualifications beyond secondary school, with 51.2% engaged in occupations requiring very little or no formal education and 50.9% were in the low-income group. The daily per capita solid waste generation was 0.129 kg. The highest (9.8%) and lowest (6.5%) of the annual quantities of waste were produced in October and February, respectively. Similarly, 20.2% of the weekly generation was produced on Saturday and the 10.2% produced on Thursday was the lowest. Animal dung, which accounted for 18.0%, constituted the highest component of the total solid waste generated. The study further established that the organic component of the waste generation was 75.4%. The results of the regression analysis R2 significant at 0.001 showed that income, household size, social status, occupation, education and season of the year explained 88.8% of waste generation in Oyo. It was established that 50.90 tonnes of solid waste was generated per day in the city in 2005, and the daily generation in the year 2008 is estimated to be 55.20 tonnes. The study concluded that with an average annual population growth of 13 000 people for the town, an additional 1.3 acres of land will need to be legally acquired annually, implying that 10.92-19.68 hectares ill be required as dump site(s) over the next 20-30 years.     

INTERNATIONAL CONFERENCE ON WATER AND HUMAN HEALTH1

The following paper was presented by Dr. Abel Wolman at the Plenary Session of the 22nd Annual Conference of the American Water Resources Association in Atlanta, Georgia, November 10, 1986. Dr. Wolman is Professor Emeritus of Sanitary Engineering at The Johns Hopkins University. He was educated at Johns Hopkins and has received an Honorary Doctor of Engineering (1937) and Honorary Doctor of Laws (1969) from his alma mater. Dr. Wolman held a number of positions before joing the faculty of The Johns Hopkins University as Professor and Chairman of the Department of Sanitary Engineering (1937–1959). He has served as consultant for many studies and projects, in the United States and overseas, and has a long-term record of service to communities, states and governments. A long list of awards and honors include the Sedgwick Memorial Award, APHA; Arthur Sidney Bedell Award, WPCF; Hemisphere Award, inter-American Association of Sanitary Engineers; U.S. Award of the National Medal of Science; Tyler Award, Ecological Society of America; Ben Gurion Award from the State of israel; and the Gordon Maskew Fair Award, WPCA. He is author, co-author or editor of four books and over 3000 technical publications, most in refereed journals.     

Die Reste fossiler Tiere im Volksglauben und in der Sage

The Science of Nature -     

Financing Marine Protected Areas Through Visitor Fees: Insights from Tourists Willingness to Pay in Chile

Tourism is a financing mechanism considered by many donor-funded marine conservation initiatives. Here we assess the potential role of visitor entry fees, in generating the necessary revenue to manage a marine protected area (MPA), established through a Global Environmental Facility Grant, in a temperate region of Chile. We assess tourists’ willingness to pay (WTP) for an entry fee associated to management and protection of the MPA. Results show 97 % of respondents were willing to pay an entrance fee. WTP predictors included the type of tourist, tourists’ sensitivity to crowding, education, and understanding of ecological benefits of the MPA. Nature-based tourists state median WTP values of US$ 4.38 and Sun-sea-sand tourists US$ 3.77. Overall, entry fees could account for 10–13 % of MPA running costs. In Chile, where funding for conservation runs among the weakest in the world, visitor entry fees are no panacea in the short term and other mechanisms, including direct state/government support, should be considered.     

Skewed Riskscapes and Environmental Injustice: A Case Study of Metropolitan St. Louis

This article presents a case study of Toxics Release Inventory (TRI) air pollution exposure risks across metropolitan St. Louis. The first section critically reviews environmental justice research and related barriers to environmental risk management. Second, the paper offers a conventional analysis of the spatial patterns of TRI facilities and their surrounding census block group demographics for metropolitan St. Louis. Third, the article describes the use of an exposure risk characterization for 319 manufacturers and their air releases of more than 126 toxic pollutants. This information could lead to more practical resolutions of urban environmental injustices. The analysis of TRIs across metropolitan St. Louis shows that minority and low-income residents were disproportionately closer to industrial pollution sources at nonrandom significance levels. Spatial concentrations of minority residents averaged nearly 40% within one kilometer of St. Louis TRI sites compared to 25% elsewhere. However, one-fifth of the region's air pollution exposure risk over a decade was spatially concentrated among only six facilities on the southwestern border of East St. Louis. This disproportionate concentration of some of the greatest pollution risk would never be considered in most conventional environmental justice analyses. Not all pollution exposure risk is average, and the worst risks deserve more attention from environmental managers assessing and mitigating environmental injustices.     

Sources and major biogeochemical pathways of organic matter in the mangrove system of Rufiji estuary

Fatty acids were extracted from the surface sediments (10 cm) of three sampling sites of Rufiji estuary to infer their sources and biogeochemical pathways. The fatty acids ranging from C₈ to C₂₄ were distinguished from this study, and were broadly classified into saturated (SFAs), monounsaturated (MUFAs) and polyunsaturated fatty acids (PUFAs). SFAs were found to be the major fraction at station 1 and 3 where as at station 2, MUFAs dominated. A total of 19 fatty acids with a total concentration of 64.91 μg/g dry weight were characterised at station 1. C_16:0 was the most abundant fatty acid contributing 21.94% of total fatty acids (TFAs). C_22:2 was the second most abundant, which accounted for 9.46% of TFAs. Fatty acids ranging from C₁₂ to C₂₄ were identified at station 2. C₂₀ fatty acid was the most abundant fatty acid contributing 21.94%, followed by C_16:0. At station 3, fatty acids ranging from C₈ to C₂₄ were obtained. The PUFA C_20:5n-3 was the most abundant fatty acid contributing 21.65%, followed by C_24:0 (15.00% of TFAs). The ratio of lower molecular weight (LMW) to higher molecular weight (HMW) biomarkers was used as an indicators to distinguish higher plants organic matter from algae-derived fatty acids.     

Bioclimatic modelling of current and projected climatic suitability of coffee (<Emphasis Type="Italic">Coffea arabica</Emphasis>) production in Zimbabwe

Coffee is an important commodity crop in Zimbabwe and many other African countries in terms of its contribution to local and national economies. Coffee production in terms of productivity and quality face severe constraints due to climate change. A study was therefore carried out to understand and quantify the potential impact of climate change on the coffee sector in Zimbabwe using a bioclimatic modelling approach. Current climatically suitable areas were identified and compared with those areas identified to be climatically suitable under projected 2050 climatic conditions. The projected climatic conditions were obtained from climate predictions of two models: CCSM4 model and HadGEM2 model. Coffee production was found to be mostly sensitive to precipitation factors as these were the most important in determining climatic suitability of coffee production in Zimbabwe. The modelling showed that current coffee suitability varies spatially between the four coffee producing districts in Zimbabwe. Chipinge district has the largest area climatically suitable for coffee production followed by Chimanimani district with Mutare district having the smallest. The modelling predicted that there will be a spatial and quantitative change in climatic suitability for coffee production in Zimbabwe by 2050. The greatest changes are projected for Mutare district where over three quarters according to the CCSM4 model and the entire district according to the HadGEM2 model will turn marginal for coffee production. A westward shift in climatic suitability of coffee was observed for Chipinge and Chimanimani district. The models predicted a loss of between 30,000 ha (CCSM4) and 50,000 ha (HadGEM2) in areas climatically suitable for coffee production by 2050 in Zimbabwe. These changes are likely to be driven by changes in the distribution of precipitation received in the coffee areas. The study presents possible adaptation measures that can be adopted by the coffee sector in Zimbabwe and the region to maintain coffee productivity under a changing climate.