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921.
Thalita B. Zanoni Eloísa Silva de Paula Guilherme Julião Zocolo Maria Valnice B. Zanoni Danielle Palma de Oliveira 《毒物与环境化学》2013,95(9):1506-1517
Incubation of guanosine and Sudan III induces the formation of a stable adduct, which may be identified using a spectrophotometric technique and mass spectroscopy. The high nucleophilicity of the C8 position and its proximity to N7 makes the site susceptible to a nucleophilic attack, which explains the SN2 reaction detected between guanosine and Sudan III dye. In addition, direct interaction of Sudan III with calf thymus DNA was monitored using a simple spectrophotometric technique. The results presented indicate that a simple modification of the chemical structure of Sudan I (monoazo dye) to Sudan III (diazo dye) markedly alters reactivity towards nitrogenous DNA bases. 相似文献
922.
P. C. Roebeling L. Costa L. Magalhães-Filho V. Tekken 《Journal of Coastal Conservation》2013,17(3):389-395
Coastal zones experience increased rates of coastal erosion, due to rising sea levels, increased storm surge frequencies, reduced sediment delivery and anthropogenic transformations. Yet, coastal zones host ecosystems that provide associated services which, therefore, may be lost due to coastal erosion. In this paper we assess to what extent past and future coastal erosion patterns lead to losses in land cover types and associated ecosystem service values. Hence, historical (based on CORINE land cover information) and projected (based on Dynamic and Interactive Vulnerability Assessment - DIVA - simulations) coastal erosion patterns are used in combination with a benefits transfer approach. DIVA projections are based on regionalized IPCC scenarios. Relative to the period 1975–2050, a case study is provided for selected European coastal country member states. For historical (1975–2006) coastal erosion trends, we observe territory losses in coastal agricultural, water body and forest & semi-natural areas – total coastal erosion equaling over 4,500 km2. Corresponding coastal ecosystem service values decrease from about €22.3 billion per year in 1975 to about €21.6 billion per year in 2006. For future (2006–2050) coastal erosion projections, total territory losses equal between ~3,700 km2 and ~5,800 km2 – coastal wetland areas being affected most severely. Corresponding coastal ecosystem service values decrease to between €20.1 and €19.4 billion per year by 2050. Hence, we argue that the response strategy of EU member states to deal with coastal erosion and climate change impacts should be based on the economic as well as the ecological importance of their coastal zones. 相似文献
923.
Tanya M. Silveira Catarina Frazão Santos Francisco Andrade 《Journal of Coastal Conservation》2013,17(4):825-832
In the winter of 2006/2007 approximately 200,000 m3 of high quality sand from the dredging of the local marina were placed at the ocean-side beaches in the vicinity of a tourism development in Tróia, Portugal. The beach-quality sediment provided a source of “sand of opportunity” which was used to increase the dry-beach width of the highly used coastal stretch. The sediment was placed along approximately 600 m of shoreline and a monitoring program has since being carried out twice a year. High-resolution topographic surveys and sediment analysis are being conducted to evaluate the performance and response of the fill to the local forcing factors and ultimately to evaluate the effectiveness of the fill project. Two years after the nourishment, the sediment has been distributed both cross-shore and alongshore. The pre-nourishment beach slope was attained and the new shoreline has acquired a natural shape. Berm width increased by a maximum of 100 m, and a set of new dune ridges has developed, due to sand accumulation promoted by the settlement of vegetation. In conclusion, 2 years after its completion, the beach nourishment in Tróia can be viewed as a successful project in which the beneficial use of dredged material resulted in: 1) area for increased dune field growth and development, 2) enhancement of potential shorebird nesting areas and habitat, and 3) increased area for recreation purposes. 相似文献
924.
A simple and rapid method has been optimised to determine glyoxal and methylglyoxal in atmospheric particulate matter by extraction and derivatisation with 2,4-dinitrophenylhydrazine solutions. Minimal sample preparation was required by mixing a portion of filter charged with atmospheric particulate matter with 5?mL of a saturated solution of 2,4-dinitrophenylhydrazine (1.6?g?L?1) in acetonitrile and acidified by H2SO4 (50?µL?L?1). Chromatographic analyses were carried out 1?h after derivatisation solution was mixed. Finally, the proposed method was applied to quantify these dicarbonyls in atmospheric particulate matter samples, which were obtained as part of a large field study to characterise atmospheric aerosol from a rural area of Madrid. Glyoxal concentrations averaged 0.24?ng?m?3, whereas mean values of methyl glyoxal were around 0.95?ng?m?3. Methyl glyoxal levels showed a clear relationship with the particulate matter levels, whereas glyoxal data did not show such a correlation. This could indicate that both dicarbonyls come from different sources. 相似文献
925.
Ernesto Bonilla Rocío Contreras Shirley Medina-Leendertz Marylu Mora Virginia Villalobos Milagros Paz 《毒物与环境化学》2013,95(4):742-747
The effect of resveratrol was studied on the life span and motor activity of Drosophila melanogaster treated with manganese (Mn). Two days after emerging from the pupa, male wild type D. melanogaster were fed for 13 days with corn media containing 15?mM Mn. Thereafter, Drosophila were divided into six groups of 300 flies each: (1) the flies remained treated with Mn; (2) began treatment with 0.43?mM resveratrol (Mn-resveratrol group); (3) received no additional treatment (Mn-no treatment group); (4) simultaneously fed with Mn and resveratrol (Mn?+?resveratrol group). In addition, a control (5) with no treatment and another group (6) fed only with resveratrol after emerging from the pupa were included. All Mn-treated flies (group 1) were dead on the 25th day. The life span in the resveratrol group was 91?±?0.33 days (mean?±?S.E.M.) and in Mn-resveratrol flies was 83?±?2 days. These two values were significantly higher than those detected in the control (5) and Mn-no treatment (group 3) flies whose life span were 68?±?0.33 and 67?±?2.31 days, respectively. The Mn?+?resveratrol-fed flies had a markedly higher life span (31?±?1.53 days) than Mn-fed flies (23?±?0.88 days). In the flies that received Mn (Mn and Mn?+?resveratrol groups), the motor activity decreased significantly with respect to control (groups 5) and the Mn–resveratrol and resveratrol groups. In conclusion, resveratrol increased significantly the life span of Mn-treated D. melanogaster. 相似文献
926.
João Porteiro Helena Calado Margarida Pereira Adriano Quintela Tomáz Dentinho 《国际发展与全球生态学杂志》2013,20(2):192-200
The Sete Cidades Lake (437 ha) is located in a volcanic crater of São Miguel Island (Azores). The watershed is 1923 ha, and 25% of it is covered with water. Extreme logging and the use of fertilizers in the cattle grazing areas have caused sedimentation and eutrophication of the main water body (Carlson Trophic State Index TSI = 40–50 mesoeutrophy). To deal with the issue, a linear programming model was created to generate efficient land-use scenarios for different amounts of phosphorus release. The model was calibrated for the present situation and then simulated to obtain 29 scenarios. It allowed us to derive parameters for each scenario. Then a multiobjective program was used to derive an acceptable weight for each indicator. The dominant solutions were discovered and discussed with different stakeholders. 相似文献
927.
Identifying and mapping local bycatch hotspots of loggerhead sea turtles using a GIS-based method: implications for conservation 总被引:1,自引:0,他引:1
Giulia Cambiè Noela Sánchez-Carnero Toni Mingozzi Ramón Muiño Juan Freire 《Marine Biology》2013,160(3):653-665
Fisheries bycatch of marine megafauna is a worldwide conservation issue. In this study, we propose a method for generating reliable maps of sea turtle bycatch hotspots. Based on a well-defined area of fishing effort determined from the longline sets monitored in 2007 and 2010, we calculated the fishing area with the highest turtle bycatch density for both years. Our results show that it is important to consider all the components of fishing effort (area, number of hooks and soak time) in order to standardize the bycatch events, and thus the spatial density of the captures can be considered an index of abundance and aggregation of the species. Moreover, the high-resolution level of the analyses was useful for investigating the cumulative effect of the longline sets, which often overlap, and made it possible to correctly map the capture density and the intensity of the fishing effort at any given location. 相似文献
928.
The "pyroclimatic hypothesis" proposed by F. Biondi and colleagues provides a basis for testable expectations about climatic and other controls of fire regimes. This hypothesis asserts an a priori relationship between the occurrence of widespread fire and values of a relevant climatic index. Such a hypothesis provides the basis for predicting spatial and temporal patterns of fire occurrence based on climatic control. Forests near the Mexico-United States border offer a place to test the relative influence of climatic and other controls in mountain ranges that are ecologically similar and subject to broadly similar top-down climatic influence, but with differing cultural influences. We tested the pyroclimatic hypothesis by comparing fire history information from the Mesa de las Guacamayas, a mountain range in northwestern Chihuahua, with previously published fire data from the Chiricahua Mountains, in southeastern Arizona, approximately 150 km away. We developed a priori hypothetical models of fire occurrence and compared their performance to empirical climate-based models. Fires were frequent at all Mesa de las Guacamayas study sites through the mid-20th century and continued uninterrupted to the present at one site, in contrast to nearly complete fire exclusion after 1892 at sites in the Chiricahua Mountains. The empirical regression models explained a higher proportion of the variability in fire regime associated with climate than did the a priori models. Actual climate-fire relationships diverged in each country after 1892. The a priori models predicted continuing fires at the same rate per century as prior to 1892; fires did in fact continue in Mexico, albeit with some alteration of fire regimes, but ceased in the United States, most likely due to changes in land use. The cross-border comparison confirms that a frequent-fire regime could cease without a climatic cause, supporting previous arguments that bottom-up factors such as livestock grazing can rapidly and drastically alter surface fire regimes. Understanding the historical patterns of climate controls on fire could inform the use of historical data as ecological reference conditions and for future sustainability. 相似文献
929.
Araceli Loredo-Treviño Gerardo Gutiérrez-Sánchez Raúl Rodríguez-Herrera Cristóbal N. Aguilar 《Journal of Polymers and the Environment》2012,20(1):258-265
Plastics are present in a lot of aspects of everyday life. They are very versatile and resistant to microbial attack. Polyurethanes
are used in several industries and are divided in polyester and polyether polyurethanes and there are different types among
them. Despite their microbial resistance, they are susceptible to the attack of fungi and bacteria but the mechanism to elucidate
its biodegradation are unknown. There are reports from bacteria and fungi that are capable of degrading polyurethane but the
studies about the enzymes that attack the plastic are focused on bacterial enzymes only. The enzymes reported are of type
esterase and protease mainly since these enzymes are very unspecific and can recognize some regions in the polyurethane molecule
and hydrolyze it. Fungal enzymes have been studied prior the 1990s decade but recently, some authors report the use of filamentous
fungi to degrade polyurethane and also report some characteristics of the enzymes involved in it. This review approaches polyurethane
biodegradation by focusing on the enzymes reported to date. 相似文献
930.
Rodrigo Goyannes Gusmão Caiado Osvaldo Luiz Gonçalves Quelhas Daniel Luiz Mattos Nascimento Rosley Anholon Walter Leal Filho 《国际发展与全球生态学杂志》2018,25(4):312-326
In recent years, sustainability issues are gaining greater prominence among organizations and their stakeholders around the world. This paper aims to verify the sustainability performance of Brazilian organizations in performance measures and to propose sustainable guidelines with the intention of directing future efforts to the transition to sustainable development. The research utilized a triangulated approach by collecting qualitative and quantitative data acquired through multiple collection methods of a theoretical literature review, documentary analysis of corporate reports, questionnaire survey and semi-structured interviews with industry professionals and academic researchers. The results show that internal organizational factors are the main inductors of the sustainable environment in organizations, and sustainability must be tied to strategic planning, starting from upper management to lower levels. It is essential to use sustainable performance measurement systems in order to respond to external and internal levers and serve as benchmarking for future corporate operations and strategies. In addition, it is the responsibility of organizations to focus their efforts on environmental protection, reduction of energy, corporate reputation, quality management, customer satisfaction and investor relations, as they are considered to be more important and have a relationship of dependence on organizational sustainability. The findings will be of value to professionals and academics who want to start measuring and for continuously improving the sustainability performance of their organizations according to the technical, economic, environmental, social and governance dimensions. This research work also helps to understand the perceptions and expectations of stakeholders. 相似文献