An Investigation into the Influence of C. moschata Leaves Extract on Physicochemical and Biological Properties of Biodegradable PCL/PLA Blend Film

Journal of Polymers and the Environment - Poly ε-caprolactone (PCL) synthesized by ring-opening polymerization method, and then it blended with polylactic acid (PLA). The blend was loaded with...     

Investigation of biomass waste biochar production to act as matrix for urea

Journal of Material Cycles and Waste Management - In this work, the synthesis of biochar from several biomass wastes to act as matrix for urea was investigated. The objective was to select the most...     

Impacts of mycotoxin on biohydrogen production from waste dry fruits

Journal of Material Cycles and Waste Management - Discarded dry fig and raisin, which exporting companies have to claim and destroy, were subjected to batch dark fermentation at 37 °C...     

Measurement of sustainability performance in Brazilian organizations

In recent years, sustainability issues are gaining greater prominence among organizations and their stakeholders around the world. This paper aims to verify the sustainability performance of Brazilian organizations in performance measures and to propose sustainable guidelines with the intention of directing future efforts to the transition to sustainable development. The research utilized a triangulated approach by collecting qualitative and quantitative data acquired through multiple collection methods of a theoretical literature review, documentary analysis of corporate reports, questionnaire survey and semi-structured interviews with industry professionals and academic researchers. The results show that internal organizational factors are the main inductors of the sustainable environment in organizations, and sustainability must be tied to strategic planning, starting from upper management to lower levels. It is essential to use sustainable performance measurement systems in order to respond to external and internal levers and serve as benchmarking for future corporate operations and strategies. In addition, it is the responsibility of organizations to focus their efforts on environmental protection, reduction of energy, corporate reputation, quality management, customer satisfaction and investor relations, as they are considered to be more important and have a relationship of dependence on organizational sustainability. The findings will be of value to professionals and academics who want to start measuring and for continuously improving the sustainability performance of their organizations according to the technical, economic, environmental, social and governance dimensions. This research work also helps to understand the perceptions and expectations of stakeholders.     

Evolution and decay of gravity wavefields in weak-rotating environments: a laboratory study

Gravity waves are prominent physical features that play a fundamental role in transport processes of stratified aquatic ecosystems. In a two-layer stratified basin, the equations of motion for the first vertical mode are equivalent to the linearised shallow water equations for a homogeneous fluid. We adopted this framework to examine the spatiotemporal structure of gravity wavefields weakly affected by the background rotation of a single-layer system of equivalent thickness \(h_{\ell }\), via laboratory experiments performed in a cylindrical basin mounted on a turntable. The wavefield was generated by the release of a diametral linear tilt of the air–water interface, \(\eta _{\ell }\), inducing a basin-scale perturbation that evolved in response to the horizontal pressure gradient and the rotation-induced acceleration. The basin-scale wave response was controlled by an initial perturbation parameter, \({\mathcal{A}}_{*} = \eta _{0}/h_{\ell }\), where \(\eta _{0}\) was the initial displacement of the air–water interface, and by the strength of the background rotation controlled by the Burger number, \({\mathcal{S}}\). We set the experiments to explore a transitional regime from moderate- to weak-rotational environments, \(0.65\le {\mathcal{S}} \le 2\), for a wide range of initial perturbations, \(0.05\le {\mathcal{A}}_{*}\le 1.0\). The evolution of \(\eta _{\ell }\) was registered over a diametral plane by recording a laser-induced optical fluorescence sheet and using a capacitive sensor located near the lateral boundary. The evolution of the gravity wavefields showed substantial variability as a function of the rotational regimes and the radial position. The results demonstrate that the strength of rotation and nonlinearities control the bulk decay rate of the basin-scale gravity waves. The ratio between the experimentally estimated damping timescale, \(T_{d}\), and the seiche period of the basin, \(T_{g}\), has a median value of \(T_{d}/T_{g}\approx 11\), a maximum value of \(T_{d}/T_{g}\approx 10^{3}\) and a minimum value of \(T_{d}/T_{g}\approx 5\). The results of this study are significant for the understanding the dynamics of gravity waves in waterbodies weakly affected by Coriolis acceleration, such as mid- to small-size lakes.     

Potential toxicity of leachate from the municipal landfill in view of the possibility of their migration to the environment through infiltration into groundwater

Environmental Geochemistry and Health - Leachate from landfills is a product of complex biological and physicochemical processes occurring during waste storage. In the present study, the toxicity...     

Pollution profiles and physicochemical parameters in old uncontrolled landfills

The long-term effectiveness of the geological barrier beneath municipal-waste landfills is a critical issue for soil and groundwater protection. This study examines natural clayey soils directly in contact with the waste deposited in three landfills over 12 years old in Spain. Several physicochemical and geological parameters were measured as a function of depth. Electrical conductivity (EC), water-soluble organic carbon (WSOC), Cl⁻, NH₄⁺, Na⁺ and exchangeable NH₄⁺ and Na⁺ were used as parameters to measure the penetration of landfill leachate pollution. Mineralogy, specific surface area and cationic-exchange capacities were analyzed to characterize the materials under the landfills. A principal component analysis, combined with a Varimax rotation, was applied to the data to determine patterns of association between samples and variables not evident upon initial inspection. The main factors explaining the variation in the data are related to waste composition and local geology. Although leachates have been in contact with clays for long time periods (13-24 years), WSOC and EC fronts are attenuated at depths of 0.2-1.5 m within the clay layer. Taking into account this depth of the clayey materials, these natural substrata (>45% illite-smectite-type sheet silicates) are suitable for confining leachate pollution and for complying with European legislation. This paper outlines the relevant differences in the clayey materials of the three landfills in which a diffusive flux attenuation capacity (A_c) is defined as a function (1) of the rate of decrease of the parameters per meter of material, (2) of the age and area of the landfill and (3) of the quantity and quality of the wastes.     

Microbial communities to mitigate contamination of PAHs in soil—possibilities and challenges: a review

Background, aim, and scope  

Although highly diverse and specialized prokaryotic and eukaryotic microbial communities in soil degrade polycyclic aromatic hydrocarbons (PAHs), most of these are removed slowly. This review will discuss the biotechnological possibilities to increase the microbial dissipation of PAHs from soil as well as the main biological and biotechnological challenges.     

Retention of Cd, Zn and Co on hydroxyapatite filters

This study qualifies and quantifies the immobilization of Cd, Zn and Co, (used as models of bivalent metal ions due to their relevant toxicity) in filters of synthetic hydroxyapatite (HAP) [Ca5(PO4)3OH]. They were flushed with solutions containing Cd (1 x 10(-5)M), Zn and Co (1 x 10(-4)M) at constant pH (8.6) and ionic strength (0.01 M). The concentration of these metal ions in the outlet was measured by ICP-OEM spectroscopy. The software PHREEQC (version 2.4.2) was used to model sorption process and the potential effect of salinity (KCl), pH, alkalinity (NaHCO3) and hardness (CaCl2) over the efficiency of the treatment. Results showed an excellent retention capacity of HAP for Cd, Zn and Co. Sorption data were successfully described considering a mix model of surface complexation onto phosphate surface groups, ionic exchange in surface calcium sites and the precipitation of ZnO. Co exchange and surface complexation constants (Kex and Kc) were taken from previous experiments, while KexCd=0.32 and KcCd=0.63 were estimated from our modeling results. Predictive values of metal ion sorption show that: (a) an increase in hardness does not play a significant role in the retention capacity of these metals on HAP; (b) an increase in alkalinity promotes the precipitation of MeCO3 which could alter the hydrodynamic of the column; (c) a decrease in pH and an increase in salinity inhibit ZnO precipitation enhancing Zn and Cd adsorption and decreasing Co retention on HAP.     

Ferronickel slag as free-draining rockfill dike material: a novel waste solution for mining regions

Journal of Material Cycles and Waste Management - Mining sites are vulnerable to erosion and siltation of rivers. While the construction of rockfill dikes can mitigate siltation, existing rockfill...