Optimum parameters for fault detection and diagnosis system of batch reaction using multiple neural networks

Batch process usually differs from the continuous process because of its time-varying variables and the process parameters. An early detection and isolation of faults in the process will help to reduce the process upsets and keep it safe and reliable. This paper discusses on the application of multi-layer perceptron neural network in detecting various faults in batch chemical reactor based on an esterification process that involves the reaction of ethanol and acetic acid catalyzed by sulfuric acid. A multi-layer feed forward neural network with double hidden layers has been used in the neural network architecture. The detection was based on the different patterns generated between normal and faulty conditions. An optimum network configuration was found when the network produced the minimal error with respect to the training, testing and data validation.     

Effects of Stonewalled Terracing Techniques on Soil-Water Conservation and Wheat Production Under Mediterranean Conditions

A field plot experiment was conducted in the Palestinian Autonomous Areas to study the effect of stonewalled terracing on soil and water conservation as compared to the nonterraced areas. Effects of the wheat canopy were considered as a second treatment. The experiment was undertaken over a period of two seasons (2000 and 2001). The results of the experiment found that the mean soil erosion was significantly lower (P < 0.05) in the terraced plots than in those that were nonterraced (182 kg/ha and 3525 kg/ha during the first season, 1769 kg/ha and 5057 kg/ha during the second season for terraced and nonterraced plots, respectively). A similar trend was observed with respect to runoff in areas under the same treatments. The wheat canopy showed lower, but not significant runoff and erosion in most of the cases for both seasons. Due to better soil and water conservation, the terraced plots obtained significantly higher total plant dry matter than nonterraced plots (1570 and 630 kg/ha in 2000, 2545 and 889 kg/ha in 2001 for terraced and nonterraced treatment, respectively). The runoff coefficient was 20% and 4% for the nonterraced and terraced plots, respectively. Rainstorms with intensity ≥4 mm/hand rainfall ≥10 mm are more likely to cause runoff and erosion.     

Water input requirements of the rapidly shrinking Dead Sea

The deepest point on Earth, the Dead Sea level, has been dropping alarmingly since 1978 by 0.7 m/a on average due to the accelerating water consumption in the Jordan catchment and stood in 2008 at 420 m below sea level. In this study, a terrain model of the surface area and water volume of the Dead Sea was developed from the Shuttle Radar Topography Mission data using ArcGIS. The model shows that the lake shrinks on average by 4 km²/a in area and by 0.47 km³/a in volume, amounting to a cumulative loss of 14 km³ in the last 30 years. The receding level leaves almost annually erosional terraces, recorded here for the first time by Differential Global Positioning System field surveys. The terrace altitudes were correlated among the different profiles and dated to specific years of the lake level regression, illustrating the tight correlation between the morphology of the terrace sequence and the receding lake level. Our volume-level model described here and previous work on groundwater inflow suggest that the projected Dead Sea–Red Sea channel or the Mediterranean–Dead Sea channel must have a carrying capacity of >0.9 km³/a in order to slowly re-fill the lake to its former level and to create a sustainable system of electricity generation and freshwater production by desalinization. Moreover, such a channel will maintain tourism and potash industry on both sides of the Dead Sea and reduce the natural hazard caused by the recession.     

Delineation of groundwater potentials of Sfax region,Tunisia, using fuzzy analytical hierarchy process,frequency ratio,and weights of evidence models

Environment, Development and Sustainability - Groundwater in semiarid regions is of extreme importance due to limited water resources and increasing population demand. Hence, a better knowledge of...     

Metals in a northern Nile Delta lake: water,suspended particulates,sediments, and biota

Lake Edku is one of the important fishing areas in the Nile Delta. It is exposed to different quantities of serious pollutants in particular metals. To overall appraise the risk and status of metals in the lake, a comprehensive study of total concentrations of cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), and zinc (Zn) in sediments and spatial-temporal variations of these metals in the dissolved and suspended particulates, and some tissues of Tilapias niloticus, was conducted from ten sampling sites during 2016. Results showed that none of the investigated metals exceeded the limits considered as hazardous for aquatic life in water. The highest concentrations of Cd, Cu, Ni, and Zn were observed in suspended particulate matter, which may precipitate on the surface of the sediments. Potential ecological risk analysis of the majority of the investigated metals in the sediment indicated that Lake Edku posed a low ecological risk. The estimated values of all metals in tissues of Tilapia niloticus were below the international permissible limits. Moreover, the potential risk of metals to human via the consumption of Tilapia niloticus was estimated using the weekly intake levels, which was lower than the WHO’s safe provisional tolerant weekly intake levels. These results prove the importance of performing measurements of contaminants in various compartments of Lake Ecosystem including sediment, biota, and suspended particulate matter for proper management.     

Modified APHA closed-tube reflux colorimetric method for TOC determination in water and wastewater

The analysis of total organic carbon (TOC) by the American Public Health Association (APHA) closed-tube reflux colorimetric method requires potassium dichromate (K₂Cr₂O₇), silver sulfate (AgSO₄), and mercury (HgSO₄) sulfate in addition to large volumes of both reagents and samples. The method relies on the release of oxygen from dichromate on heating which is consumed by carbon associated with organic compounds. The method risks environmental pollution by discharging large amounts of chromium (VI) and silver and mercury sulfates. The present method used potassium monochromate (K₂CrO₄) to generate the K₂Cr₂O₇ on demand in the first phase. In addition, miniaturizing the procedure to semi microanalysis decreased the consumption of reagents and samples. In the second phase, mercury sulfate was eliminated as part of the digestion mixture through the introduction of sodium bismuthate (NaBiO₃) for the removal of chlorides from the sample. The modified method, the potassium monochromate closed-tube colorimetry with sodium bismuthate chloride removal (KMCC-Bi), generates the potassium dichromate on demand and eliminates mercury sulfate. The semi microanalysis procedure leads to a 60% reduction in sample volume and ≈?33.33 and 60% reduction in monochromate and silver sulfate consumption respectively. The LOD and LOQ were 10.17 and 33.90 mg L^?1 for APHA, and 4.95 and 16.95 mg L^?1 for KMCC-Bi. Recovery was between 83 to 98% APHA and 92 to 104% KMCC-Bi, while the RSD (%) ranged between 0.8 to 5.0% APHA and 0.00 to 0.62% KMCC-Bi. The method was applied for the UV-Vis spectrometry determination of COD in water and wastewater. Statistics was done by MINITAB 17 or MS Excel 2016.

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Coffee,its roasted form,and their residues cause birth failure and shorten lifespan in dengue vectors

Environmental Science and Pollution Research - In dengue mosquitoes, successful embryonic development and long lifespan are key determinants for the persistence of both virus and vector. Therefore,...     

Risk assessment and remediation suggestion of impacted soil by produced water associated with oil production

Produced water is water trapped in underground formations that is brought to the surface along with oil or gas production. Oilfield impacted soil is the most common environmental problem associated with oil production. The produced water associated with oil-production contaminates the soil and causes the outright death of plants, and the subsequent erosion of topsoil. Also, impacted soil serves to contaminate surface waters and shallow aquifers. This paper is intended to provide an approach for full characterization of contaminated soil by produced water, by means of analysis of both the produced water and the impacted soil using several recommended analytical techniques and then identify and assay the main constituents that cause contamination of the soil. Gialo-59 oilfield (29N, 21E), Libya, has been chosen as the case study of this work. The field has a long history of petroleum production since 1959, where about 300,000 bbl of produced water be discharged into open pit. Test samples of contaminated soil were collected from one of the disposal pits. Samples of produced water were collected from different points throughout the oil production process, and the analyses were carried out at the labs of Libyan Petroleum Institute, Tripoli, Libya. The results are compared with the local environmental limiting constituents in order to prepare for a plan of soil remediation. The results showed that the main constituents (pollutants) that impact the soil are salts and hydrocarbon compounds. Accordingly; an action of soil remediation has been proposed to remove the salts and degradation of hydrocarbons.     

Quality assessment of various bottled waters marketed in Saudi Arabia

This study focuses on the chemical analysis of the available brands of domestic bottled water in Riyadh City, Saudi Arabia. The distribution of the chemical constituents (major, minor, and trace elements) is determined and compared with the chemical content labeled on the bottles and with drinking water standards of Saudi Arabian, World Health Organization, and U.S. Environmental Protection Agency. The obtained results indicated that except for fluoride and bromate, the concentrations of dissolved salts, soluble cations and anions, nitrate, and trace elements of most bottled waters on sale were within the permissible limits set by standards used. On the other hand, the comparison between determined and reported label values recorded a substantial variation in some parameter values. Results indicated that more than 18 % of the sampled bottled waters exceeded the allowable limits for drinking water. Generated Piper diagrams revealed that the majority of investigated waters were sodium chloride–sulfate type; however, the hydrochemical modeling indicated that all water samples were undersaturated for anhydrite, gypsum, and halite.     

Combustion in porous media and its applications – A comprehensive survey

The rapid advances in technology and improved living standard of the society necessitate abundant use of fossil fuels which poses two major challenges to any nation. One is fast depletion of fossil fuel resources; the other is environmental pollution. The porous medium combustion (PMC) has proved to be one of the technically and economically feasible options to tackle the aforesaid problems to a remarkable extent. PMC has interesting advantages compared with free flame combustion due to the higher burning rates, the increased power dynamic range, the extension of the lean flammability limits, and the low emissions of pollutants. This article provides a comprehensive picture of the global scenario of research and developments in PMC and its applications that enable a researcher to decide the direction of further investigation. The works published so far in this area are reviewed, classified according to their objectives and presented in an organized manner with general conclusions. A separate section is devoted for the numerical modeling of PMC.