Energy Analysis of Sugarcane Production in Morocco

An energy analysis of sugarcane production in small and large farms was made in Morocco. Total energy expenditures were 64.90 and 47.83 GJ/ha and energy outputs were 100.80 and 85.80 GJ/ha in large and small farms, respectively. The output/input energy ratios were 1.6 and 1.8. The energy intensity lies between 0.7 and 0.8 MJ/kg and is one of the highest among sugarcane producing countries. Irrigation is the most energy consuming operation with about 50% of total energy inputs. Electricity, fertilizers, fuel, and machinery are the main energy inputs. The influence of the different inputs is discussed and practical measures for energy saving and environmental conservation based on energy analysis are discussed.     

Phenol removal from aqueous environments by natural & chemically modified kaolin clay

Natural, acid and base modified kaolin clays were studied for the sake of phenol and 4-chlorophenol removal from aqueous environments and their application to real ground and industrial wastewater samples. Scanning electron microscope (SEM), infrared spectroscopy (IR), X-ray diffraction (XRD), Thermo Gravimetric Analysis (TGA), Differential Thermal Analysis (DTA), and Surface area analysis were employed for characterization of the adsorbents microstructure. Operating factors such as adsorbent dose, solution pH, initial phenol concentration, and contact time were studied. The experimental data displayed that the increase of the adsorbent dose, contact time, and pH value from 2 to 7 increases the efficiency of the removal process. Optimal conditions for phenolic removal were; contact time of 300 min, primary phenol solution of 25 mg/L, pH 7 and 2.5 g/L as an appropriate adsorbent dose using crude (natural), acid modified and base modified kaolin clays. The higher phenolic removal efficiencies were obtained at 5 mg/L as 90, 97, 96.2%, respectively, for the adsorbents in the previously mentioned order. The adsorption capacity in the removal of phenol and 4-chlorophenol were 7.481 and 4.195, 8.2942 and 3.211, and 8.05185 and 18.565 mg/g, respectively, for the adsorbents in the same mentioned order. The adsorption equilibrium data were fitted and analyzed with four isotherm models, namely, Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich isotherm equations. The adsorption process of phenol on studied adsorbents was exothermic, spontaneous and thermodynamically favorable proved by the negative values of their thermodynamic parameters ΔH° and ΔG°. The correlation coefficient (R²) for all concentrations was higher than 0.94, which indicates that in the studied system, the data suitably fit the first-order kinetics. The % desorption capacity was amounted to 96%, 91.11%, and 87.06% of adsorbed phenol, respectively, for the adsorbents in the previous order using 0.1N NaOH and 10% V/V ethanol solutions as eluents at 25°C, indicating the reusability of the adsorbents. Kaolin and its modified forms can be introduced as eco-friendly and low-cost adsorbents in water remediation implementation.     

Production of bio-fertilizer by biotransformation of poultry waste enriched with molasses and algae

This research work consists on valorizing poultry waste by biotransformation into biofertilizers, associating this agro-industrial waste with algae (abundant natural resources) and molasses (a by-product of the sugar refining industry) ensuring a good contribution of nutritional chemical elements and obtaining a balanced formulation. A total of seven different formulations of the above three components, were examined in a simplex centroid design. A fungal inoculum of Aspergillus niger was used as a fermentation agent for better quality of biotransformation. The monitoring of this biotransformation is ensured during 15 days by following the evolution of physicochemical and microbiological parameters and, to understand the bioconversion of the simple compounds of the biofertilizer mixture such as short aliphatic chains, sugar, and amino acids into soluble mineral compounds, a Fourier transform infrared spectroscopy (FTIR) analysis was carried out before and after biotransformation. Finally, germination and fertilization tests were performed to evaluate the efficiency of the final product on a barley crop. The overall results of the present study showed that the mixture which contained 68.75% poultry waste, 12.5% molasses, and 18.75% algae presented the better microbiological and chemical safety criteria required for a good biofertilizer according to NF U44-551 standard.     

Graviola attenuates DMBA-induced breast cancer possibly through augmenting apoptosis and antioxidant pathway and downregulating estrogen receptors

Breast cancer is a global public health problem where it is the second most prevalent cancer. Historical cancer treatment with graviola has been reported. This study aimed to investigate the protective effects of graviola on 7,12-dimethylbenz[a]anthracene (DMBA)–induced rat breast cancer. Fifty female Wistar rats were allocated into four groups: control group (gastro-gavaged by sesame oil), DMBA-treated group (gastro-gavaged a single dose of DMBA [50 mg/kg body mass, diluted in 1 ml sesame oil]) at the age 57 days, DMBA+G37-treated group (gastro-gavaged a single dose of DMBA [50 mg/kg body mass, diluted in 1 ml sesame oil]) at the age of 57 days plus graviola (200 mg/kg body mass) two times weekly (p.o.) at the age of 37 days till the end of the experiment, and DMBA+G57-treated group (received a single dose of DMBA [50 mg/kg body mass, diluted in 1 ml sesame oil]) plus graviola (200 mg/kg body mass) two times weekly at the age of 57 days until the end of the experiment. After the 30-week experimental period, blood samples were collected. Then, animals were sacrificed to determine the apoptotic indices, antioxidant status, and mammary gland tumor marker (CA 15-3). The DMBA upregulated the expression of one of the main anti-apoptotic genes: B-cell lymphoma protein 2 (BCL2) and estrogen receptor alpha (ER-α) gene. Moreover, it significantly increased breast lipid peroxidation and serum CA 15-3 but decreased breast antioxidant enzymatic activities (glutathione peroxidase, glutathione S-transferase, catalase, and superoxide dismutase). Nevertheless, administration of DMBA and graviola especially DMBA+G37 induced apoptosis through at least 1.5-fold in gene expression levels of pro-apoptotic genes: BCL2-associated X protein (BAX), tumor suppressor gene (P53), and cysteinyl-aspartic acid-protease-3 (caspase-3). A critical role of P53 in the regulation of the BCL2 and BAX has been reported. These proteins can determine if the cell undergoes apoptosis or cancels the process. Once the BAX gene activates caspase-3, there is no irreversible way toward cell death. Also, graviola ameliorated the DMBA effects on antioxidant enzymatic activities and tumor marker CA 15-3. This study concludes that graviola ameliorated DMBA-induced breast cancer potentially through upregulating apoptotic genes, downregulating the ER-α gene, increasing antioxidants, and decreasing lipid peroxidation levels.

     

Particulate matters and gaseous pollutants in indoor environment and Association of ultra-fine particulate matters (PM1) with lung function

Environmental Science and Pollution Research - Real-time particulate matters (PM1, PM2.5, PM4, PM7, PM10, and TSP) with AEROCET 531S (USA), gaseous pollutants (NO2 and TVOC) with Aeroquel 500 gas...     

Adsorption and thermodynamic parameters of chlorantraniliprole and dinotefuran on clay loam soil with difference in particle size and pH

The behavior of chlorantraniliprole (CAP) and dinotefuran (DNF) insecticides was investigated in clay loam soil, a common type of the Egyptian soil. Effect of temperature, pH and particle size of the soil on the adsorption process was studied. Adsorption isotherm by bulk soil and its constituents; humic acid (HA), clay, silt and sand fractions was measured using batch equilibration technique. The results showed that the adsorption of the insecticides tested was significantly affected by the temperature and was a spontaneous interfacial process in the soil. Freundlich model accurately predicted the adsorption behavior of both insecticides. The interaction between soil and insecticides was endothermic and the highest adsorption for CAP and DNF was obtained at pH 9. However, the effect of pH on the adsorption of DNF was lower than that of CAP. Sorption of CAP and DNF on HA fraction was significantly greater than on clay fraction and bulk soil. In addition, the adsorption was significantly increased with particle size decrease. It could be inferred that the adsorption of CAP and DNF on clay loam soil was physical in nature and greatly influenced by the soil components, pH and temperature.     

Preparation and Characterization of Polyaniline and Ag/ Polyaniline Composite Nanoporous Particles and Their Antimicrobial Activities

Polyaniline (PANI) and Ag/PANI nanoporous composite were prepared by an oxidative polymerization method. The oxidation process of PANI nanoparticles was occurred using (NH₄)₂S₂O₈ while the oxidation process of Ag/PANI nanoporous composite was occurred using AgNO₃ under the effect of artificial radiation. The structural, morphological, and optical properties of the PANI and Ag/PANI nanoporous structures were studied using different characterization tools. The results confirm the formation of polycrystalline nanoporous PANI and spherical nanoporous composite of Ag/PANI particles. Antibacterial activity tests against gram-positive bacteria, Bacillus subtilis and Staphylococcus aureus, and gram-negative bacteria, Escherichia coli, and Salmonella species were carried out using different concentrations of PANI nanoparticles and Ag/PANI nanoporous composites. PANI has not antibacterial effect against all studied pathogens. In contrast, Ag/PANI nanoporous composites possessed antibacterial activity that is identified by the zone of inhibition. The inhibition zones of bacteria are in order; Salmonella species?>?S. aureus?>?B. subtilis?>?E. coli. The inhibition zones of all bacteria increased with increasing concentrations of Ag/PANI nanoporous composites from 200 to 400 ppm then decreased with further increasing of the dose concentrations to 600 ppm. Finally, a simplified mechanism based on the electrostatic attraction is presented to describe the antimicrobial activity of Ag/PANI nanoporous composite.     

Effect of dietary phytogenics (herbal mixture) supplementation on growth performance,nutrient utilization,antioxidative properties,and immune response in broilers

Environmental Science and Pollution Research - This experiment was conducted to study that effect of a phytogenics (herbal mixture) supplementation as alternative to antibiotics on the growth...     

An extensive review on restoration technologies for mining tailings

Development of mineral resources and the increasing mining waste emissions have created a series of environmental and health-related issues. Nowadays, the ecological restoration of mining tailings has become one of the urgent tasks for mine workers and environmental engineers all over the world. Aim of the present paper is to highlight the previous restoration techniques and the challenges encountered during the restoration of mine tailings. As it is a common practice that, before restoring of tailings, the site should be evaluated carefully. Studies showed that the mine tailings’ adverse properties, including excessive heavy metal concentration, acidification, improper pH value, salinization and alkalization, poor physical structure and inadequate nutrition, etc., are the major challenges of their restoration. Generally, four restoration technologies, including physical, chemical, phytoremediation, and bioremediation, are used to restore the mining tailings. The working mechanism, advantages, and disadvantages of these techniques are described in detail. In addition, selection of the suitable restoration techniques can largely be carried out by considering both the economic factors and time required. Furthermore, the ecosystem restoration is perceived to be a more promising technology for mine tailings. Therefore, this extensive review can act as a valuable reference for the researchers involved in mine tailing restoration.     

Experimental investigation of dust pollutants and the impact of environmental parameters on PV performance: an experimental study

The accumulation of dust pollution on the photovoltaic (PV) module can have a significant effect on the productivity and efficiency of PV systems in different locations in the world. Dust which accumulated over time on the PV module and is based on weather conditions led to the reduction in the effectiveness of solar cells. The aim of this research was to experimentally investigate the effect of the natural dust and the effects of environmental parameters on PV performance. The experiments were conducted to propose a model for the current, voltage, power and efficiency and to simulate the effect of environmental parameters on PV performance. The natural dust investigated consisted of different compounds: SiO₂ (45.53 %), CaO (24.62 %), Al₂O₃ (10.83 %), Fe₂O₃ (10.46 %), MgO (6.33 %), K₂O (0.87 %), TiO₂ (0.45 %), SO₃ (0.24 %), MnO₂ (0.21), Cr₂O₃ (0.23 %), SrO (0.13 %) and NiO (0.09 %). It was found that the most accurate correlation is a polynomial from seventh degree for current, voltage, power and efficiency, fourth degree for solar radiation and temperature, cubic degree for humidity and wind velocity. The coefficients of general model are 0.6343, 0.0110, 0.0 and 0.0001 for PV module, respectively, with 0.0011 fitting factor. The proposed model has been validated using models in the literature.