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31.
Alan T. Herlihy Jean Sifneos Chris Bason Amy Jacobs Mary E. Kentula M. Siobhan Fennessy 《Environmental management》2009,44(2):369-377
We sampled 92 wetlands from four different basins in the United States to quantify observer repeatability in rapid wetland
condition assessment using the Delaware Rapid Assessment Protocol (DERAP). In the Inland Bays basin of Delaware, 58 wetland
sites were sampled by multiple observers with varying levels of experience (novice to expert) following a thorough training
workshop. In the Nanticoke (Delaware/Maryland), Cuyahoga (Ohio), and John Day (Oregon) basins, 34 wetlands were sampled by
two expert teams of observers with minimal protocol training. The variance in observer to observer scoring at each site was
used to calculate pooled standard deviations (SDpool), coefficients of variation, and signal-to-noise ratios for each survey. The results showed that the experience level of
the observer had little impact on the repeatability of the final rapid assessment score. Training, however, had a large impact
on observer to observer repeatability. The SDpool in the Inland Bay survey with training (2.2 points out of a 0–30 score) was about half that observed in the other three basins
where observers had minimal training (SDpool = 4.2 points). Using the results from the survey with training, we would expect that two sites assessed by different, trained
observers who obtain DERAP scores differing by more than 4 points are highly likely to differ in ecological condition, and
that sites with scores that differ by 2 or fewer points are within variability that can be attributed to observer differences. 相似文献
32.
Yung-Ping Tseng Gerard T. Kyle C. Scott Shafer Alan R. Graefe Timothy A. Bradle Michael A. Schuett 《Environmental management》2009,43(3):496-507
Along with the growing boating population and the number of boats in use on limited inland waterways, boater expectations
of setting density, safety perceptions, and the associated impacts on their experience (e.g., satisfaction) are becoming increasingly
important. The primary purpose of this article was to explore a recreational boating crowding–satisfaction model derived from
previous work using safety and enjoyment as mediating variables. We also tested our crowding–satisfaction model among day
and overnight users. Our analysis revealed no significant difference between day and overnight users for any of the relationships
tested in our model. Our final model indicated as respondents’ expectations for seeing people increased along with their feelings
of being crowded, they were more inclined to consider the conditions on the lake as being unsafe. They were also more inclined
to indicate that the number of people they had seen on the lake detracted from their boating experience. Respondents’ satisfaction
was tied to their perceptions of crowding. Mediating variables illustrated that the relationship was conditioned by perceptions
of safety and enjoyment. Analysis of the indirect effect observed in our study illustrate that when the number of people seen
on the lake exceed respondents’ expectations, their perceptions of safety and enjoyment both decline, resulting in lower satisfaction.
These findings have implications for managing recreational boating use on inland lake systems. Given the role played by expectations
in our model, efforts to communicate with boaters about conditions on these waterways is important for helping them plan their
boating experience and avoid situations they consider unsafe or unsatisfactory. 相似文献
33.
Prashant Kumar Alan Robins Rex Britter 《Atmospheric environment (Oxford, England : 1994)》2009,43(38):6110-6118
The distributions of nanoparticles (below 300 nm in diameter) change rapidly after emission from the tail pipe of a moving vehicle due to the influence of transformation processes. Information on this time scale is important for modelling of nanoparticle dispersion but is unknown because the sampling frequencies of available instruments are unable to capture these rapid processes. In this study, a fast response differential mobility spectrometer (Cambustion Instruments DMS500), originally designed to measure particle number distributions (PNDs) and concentrations in engine exhaust emissions, was deployed to measure particles in the 5–1000 nm size range at a sampling frequency of 10 Hz. This article presents results of two separate studies; one, measurements along the roadside in a Cambridge (UK) street canyon and, two, measurements at a fixed position (20 cm above road level), centrally, in the wake of a single moving diesel-engined car. The aims of the first measurements were to test the suitability and recommend optimum operating conditions of the DMS500 for ambient measurements. The aim of the second study was to investigate the time scale over which competing influences of dilution and transformation processes (nucleation, condensation and coagulation) affect the PNDs in the wake of a moving car. Results suggested that the effect of transformation processes was nearly complete within about 1 s after emission due to rapid dilution in the vehicle wake. Furthermore, roadside measurements in a street canyon showed that the time for traffic emissions to reach the roadside in calm wind conditions was about 45 ± 6 s. These observations suggest the hypothesis that the effects of transformation processes are generally complete by the time particles are observed at roadside and the total particle numbers can then be assumed as conserved. A corollary of this hypothesis is that complex transformation processes can be ignored when modelling the behaviour of nanoparticles in street canyons once the very near-exhaust processes are complete. 相似文献
34.
The use of NTA and EDDS for enhanced phytoextraction of metals from a multiply contaminated soil by Brassica carinata 总被引:2,自引:0,他引:2
The potential of nine different species to grow in the presence of metals (As, Cd, Cu, Pb and Zn) and to accumulate them in the shoots was assessed for each metal separately by germination and root length tests, and successively by hydroponic experiments. Of the nine species tested, Brassica carinata was the species that accumulated the highest amounts of metals in shoots without suffering a significant biomass reduction. To further evaluate the potential of B. carinata for chelant-enhanced phytoextraction of a natural, multiply metal-polluted soil (As, Cd, Cu, Pb and Zn), both hydroponic and pot experiments were carried out with nitrilotriacetic acid (NTA) or (S,S)-ethylenediamine disuccinic acid (EDDS) as complexing agents. The hydroponic study with solutions containing the five metals together showed that accumulation of Cd, Cu, Pb and Zn in shoots was higher following EDDS addition compared to NTA. EDDS was more effective than NTA in desorbing Cu, Pb and Zn from the soil, whereas As and Cd were poorly extracted. B. carinata plants were grown for 4 weeks in the multiply metal-contaminated soil and then the soil was amended with 5 mmol kg(-1) NTA or EDDS. All plants were harvested 1 week after amendment. In comparison to NTA, EDDS was more effective in enhancing the concentrations of Cu, Pb and Zn in B. carinata shoots (2- to 4-fold increase compared to the control). One week after chelant addition, the DTPA-extractable metal concentrations in the polluted soil were lower in the EDDS treatment in comparison with the NTA amendment. Even though B. carinata showed a reduced growth and a relatively low metal uptake, it demonstrated the ability to survive and tolerate the presence of more metals simultaneously. 相似文献
35.
Agricultural opportunities to mitigate greenhouse gas emissions 总被引:15,自引:0,他引:15
Johnson JM Franzluebbers AJ Weyers SL Reicosky DC 《Environmental pollution (Barking, Essex : 1987)》2007,150(1):107-124
Agriculture is a source for three primary greenhouse gases (GHGs): CO(2), CH(4), and N(2)O. It can also be a sink for CO(2) through C sequestration into biomass products and soil organic matter. We summarized the literature on GHG emissions and C sequestration, providing a perspective on how agriculture can reduce its GHG burden and how it can help to mitigate GHG emissions through conservation measures. Impacts of agricultural practices and systems on GHG emission are reviewed and potential trade-offs among potential mitigation options are discussed. Conservation practices that help prevent soil erosion, may also sequester soil C and enhance CH(4) consumption. Managing N to match crop needs can reduce N(2)O emission and avoid adverse impacts on water quality. Manipulating animal diet and manure management can reduce CH(4) and N(2)O emission from animal agriculture. All segments of agriculture have management options that can reduce agriculture's environmental footprint. 相似文献
36.
Vanderpool RW Byrd LA Wiener RW Hunike ET Labickas M Leston AR Tolocka MP McElroy FF Murdoch RW Natarajan S Noble CA Peters TM 《Journal of the Air & Waste Management Association (1995)》2007,57(1):14-30
Subsequent to the 1997 promulgation of the Federal Reference Method (FRM) for monitoring fine particulate matter (PM2.5) in ambient air, U.S. Environmental Protection Agency (EPA) received reports that the DOW 704 diffusion oil used in the method's Well Impactor Ninety-Six (WINS) fractionator would occasionally crystallize during field use, particularly under wintertime conditions. Although the frequency of occurrence on a nationwide basis was low, uncertainties existed as to whether crystallization of the DOW 704 oil may adversely affect a sampling event's data quality. In response to these concerns, EPA and the State of Connecticut Department of Environmental Protection jointly conducted a series of specialized tests to determine whether crystallized oil adversely affected the performance of the WINS fractionator. In the laboratory, an experimental setup used dry ice to artificially induce crystallization of the diffusion oil under controlled conditions. Using primary polystyrene latex calibration aerosols, standard size-selective performance tests of the WINS fractionator showed that neither the position nor the shape of the WINS particle size fractionation curve was substantially influenced by the crystallization of the DOW 704 oil. No large particle bounce from the crystallized impaction surface was observed. During wintertime field tests, crystallization of the DOW 704 oil did not adversely affect measured PM2.5 concentrations. Regression of measurements with crystallized DOW 704 versus liquid dioctyl sebacate (DOS) oil produced slope, intercept, and R2 values of 0.98, 0.1, and 0.997 microg/m3, respectively. Additional field tests validated the use of DOS as an effective impaction substrate. As a result of these laboratory and field tests, DOS oil has been approved by EPA as a substitute for DOW 704 oil. Since the field deployment of DOS oil in 2001, users of this alternative oil have not reported any operational problems associated with its use in the PM2.5 FRM. Limited field evaluation of the BGI very sharp cut cyclone indicates that it provides a viable alternative to the WINS fractionator. 相似文献
37.
Structure characterization and thermal stabilities of the isomers of the brominated flame retardant 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane 总被引:1,自引:1,他引:0
Arsenault G Lough A Marvin C McAlees A McCrindle R MacInnis G Pleskach K Potter D Riddell N Sverko E Tittlemier S Tomy G 《Chemosphere》2008,72(8):1163-1170
1,2-Dibromo-4-(1,2-dibromoethyl)cyclohexane (TBECH) is used primarily as an additive flame retardant. 1H NMR spectroscopy and an X-ray structure determination have revealed that a technical mixture consists largely of two (of the four possible) diastereomers, rac-(1R,2R)-1,2-dibromo-(4S)-4-((1S)-1,2-dibromoethyl)cyclohexane (alpha-TBECH) and rac-(1R,2R)-1,2-dibromo-(4S)-4-((1R)-1,2-dibromoethyl)cyclohexane (beta-TBECH), in a mole ratio of approximately 1:1. The two other possible isomers, gamma- and delta-TBECH, were not detected in a technical mixture. The TBECH isomers are thermally sensitive and can easily interconvert at temperatures of 125 degrees C. A thermal equilibrium mixture of alpha-, beta-, gamma- and delta-TBECH consists of approximately 33%, 33%, 17% and 17% of these isomers, respectively. Separation of all four TBECH diastereomers, with minimal thermal interconversion of the isomers, was achieved by careful selection of GC-capillary column length and injector temperature. Although technical TBECH does not contain the gamma- and delta-isomers, they may still be relevant environmental contaminants since manufacturing processes utilize thermal processes which may induce their formation. 相似文献
38.
MULTI INCREMENT® and discrete sampling strategies were used to estimate the average concentration and the three‐dimensional distribution of TCE in a 3,300‐m3 zone composed of two decision units (e.g., area of concern, population, exposure unit). Authors of this article and a private contractor (Stanley Consultants Inc.), respectively, implemented these two sampling strategies independently. Compared to discrete sampling, the MULTI INCREMENT sampling strategy identified more locations where percent‐level concentrations of TCE have migrated, is more economical, and provided greater data quality. © 2008 Wiley Periodicals, Inc. 相似文献
39.
David T. Rios Sudeep Chandra Alan C. Heyvaert 《Environmental monitoring and assessment》2014,186(11):7893-7907
Urban land use has been implicated as a major contributor of nonpoint source pollution in aquatic systems. Through increased nonpoint delivery of pollutants, including constituents found in stormwater, Lake Tahoe is undergoing a marked decline in its transparency, primarily due to increasing production of algae from enhanced nutrient loading and delivery of fine particles to the lake from the watershed. In response to these findings, a regional restoration effort is underway to improve basin watersheds and the water quality in Lake Tahoe. In this study, stormwater autosamplers were used to collect flow-weighted composite samples that characterized event mean concentrations for event and nonevent conditions within a small, urbanized watershed in the Tahoe basin. An event-specified constant-concentration water quality model was then applied to the event mean concentration and continuous streamflow data to estimate pollutant loads for nitrate, nitrite, ammonia, orthophosphate, and suspended sediment. These data were compared with previously reported load estimates from 10 primary monitored streams in larger watersheds of the Tahoe basin. Results from a linear regression analysis demonstrate strong and significant relationships between watershed impervious area and pollutant loadings from Lake Tahoe watersheds. These small, urbanized watersheds and intervening zones, which only comprise 10 % of the total Lake Tahoe drainage area, include a significant portion of the total Lake Tahoe impervious area. The findings of this study suggest that small, urbanized watersheds and intervening zones are disproportionately important contributors of nonpoint source pollution, including nutrients and suspended particles. 相似文献
40.
Sarath K. Guttikunda Ramani V. Kopakka Prasad Dasari Alan W. Gertler 《Environmental monitoring and assessment》2013,185(7):5585-5593
Air quality in Hyderabad, India, often exceeds the national ambient air quality standards, especially for particulate matter (PM), which, in 2010, averaged 82.2?±?24.6, 96.2?±?12.1, and 64.3?±?21.2 μg/m3 of PM10, at commercial, industrial, and residential monitoring stations, respectively, exceeding the national ambient standard of 60 μg/m3. In 2005, following an ordinance passed by the Supreme Court of India, a source apportionment study was conducted to quantify source contributions to PM pollution in Hyderabad, using the chemical mass balance (version 8.2) receptor model for 180 ambient samples collected at three stations for PM10 and PM2.5 size fractions for three seasons. The receptor modeling results indicated that the PM10 pollution is dominated by the direct vehicular exhaust and road dust (more than 60 %). PM2.5 with higher propensity to enter the human respiratory tracks, has mixed sources of vehicle exhaust, industrial coal combustion, garbage burning, and secondary PM. In order to improve the air quality in the city, these findings demonstrate the need to control emissions from all known sources and particularly focus on the low-hanging fruits like road dust and waste burning, while the technological and institutional advancements in the transport and industrial sectors are bound to enhance efficiencies. Andhra Pradesh Pollution Control Board utilized these results to prepare an air pollution control action plan for the city. 相似文献