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581.
Alan Lock Dirk Wallschläger Nelson Belzile Graeme Spiers Celine Gueguen 《环境科学学报(英文版)》2018,30(4):338-347
Sediments from an arsenic(As) contaminated groundwater vent site were used to investigate As( Ⅲ) binding, transformation and redistribution in native and iron oxide amended lake sediments using aging spiked batch reactions and a sequential extraction procedure that maintains As(V) and As( Ⅲ) speciation. In the native sediments, fractionation analysis revealed that 10% of the spiked As( Ⅲ) remained intact after a 32-day aging experiment and was predominantly adsorbed to the strongly sorbed(NH_4H_2PO_4 extractable) and amorphous Fe oxide bound(H_3PO_4 extractable) fractions. Kinetic modelling of the experimental results allowed identifying the dominant reaction path for depletion of dissolved As( Ⅲ) to As( Ⅲ)absorbed on to the solid phase, followed by oxidation in the solid phase. Arsenite was initially adsorbed primarily to the easily exchangeable fraction((NH_4)_2SO_4 extractable), then rapidly transformed into As(V) and redistributed to the strongly sorbed and amorphous Fe oxide bound fractions. Oxidation of As( Ⅲ) in recalcitrant fractions was less efficient. The iron oxide amendments illustrated the controls that iron oxides can have on As( Ⅲ) binding and transformation rates. In goethite amended samples As( Ⅲ) oxidation was faster and primarily occurred in the strongly sorbed and amorphous Fe oxide bound fractions. In these samples,19.3 μg Mn was redistributed(compared to the native sediment) from the easily exchangeable and crystalline Fe oxide bound fractions to the strongly sorbed and amorphous Fe oxide bound fractions, indicating that goethite may act as a catalyst for Mn(Ⅱ) oxidation, thereby producing sorbed Mn( Ⅲ/Ⅳ ), which then appears to be involved in rapidly oxidizing As( Ⅲ). 相似文献
582.
Alessandra DiGiacomo David W.-L. Wu Peter Lenkic Bud Fraser Jiaying Zhao Alan Kingstone 《Journal of Environmental Planning and Management》2018,61(2):309-331
Increasing volumes of solid waste, implicated in environmental pollution and health problems, are central to the current environmental crisis. In two randomized field experiments, we demonstrate that convenience dramatically boosts recycling and composting rates in multi-family dwellings and university residences. When compost bins were placed on each floor in a multi-family residence, instead of on the ground floor, composting rates increased by 70%, diverting 27 kilograms of compost from the landfill per unit per year. When recycling stations were placed just meters from suites in student residences, instead of in the basement, recycling increased by 147% (container), and 137% (paper), and composting increased by 139%, diverting 23, 22, and 14 kilograms of containers, paper, and compost, respectively, from the landfill per person per year. Simply making recycling and composting convenient can significantly increase waste diversion, and as such this single intervention has important implications for waste management and environmental policy. 相似文献
583.
Wetlands are critical natural resources in developing countries where they perform a range of environmental functions and provide numerous socio-economic benefits to local communities and a wider population. In recent years, however, many wetlands throughout eastern Africa have come under extreme pressure as government policies, socio-economic change and population pressure have stimulated a need for more agriculturally productive land. Although wetland drainage and cultivation can make a key contribution to food and livelihood security in the short term, in the long term there are concerns over the sustainability of this utilization and the maintenance of wetland benefits. This article draws upon recent research carried out in western Ethiopia, which addressed the sustainability of wetland agriculture in an area of increasing food insecurity and population pressure. It discusses the impacts of drainage and cultivation on wetland hydrology and draws attention to local wetland management strategies, particularly those characterized by multiple use of wetlands, where agriculture exists alongside other wetland uses. The article suggests that where multiple wetland uses exist, a range of benefits can be sustained with little evidence of environmental degradation. Ways of promoting and empowering such sustainable wetland management systems are discussed in the context of the wider need for water security throughout the region. 相似文献
584.
Creighton R. Omer E. James Nelson Alan K. Zundel 《Journal of the American Water Resources Association》2003,39(2):467-475
ABSTRACT: Current data collection technologies such as light detection and ranging (LIDAR) produce dense digital terrain data that result in more accurate digital terrain models (DTMs) for engineering applications. However, such data are redundant and often cumbersome for hydrologic and hydraulic modeling purposes. Data filtering provides a means of eliminating redundant points and facilitates model preparation. This paper demonstrates the impact of varied data resolution on a case study completed for a 2.3 mi2 area with mild slopes (about 001 ft/ft) along Leith Creek near Laurinburg, North Carolina. For the original data set and seven filtered data sets, filtering induced changes in elevation, area, and hydraulic radius were determined for 10 water depths at 23 cross sections. Water surface elevations resulting from HEC‐RAS (Hydrologic Engineering Center‐River Analysis System) models for each data set were then compared. A hydraulic model sensitivity analysis was also conducted to compare filtering error to error introduced by variation in flow rates and roughness values. Finally, automated floodplain delineation was performed for each filter level based on the computed hydraulic model results and the filtered LIDAR elevations. Data filtering results indicate that significant time savings are achieved throughout the modeling process and that filtering to four degrees can be performed without compromising cross‐sectional geometry, hydraulic model results, or floodplain delineation results. 相似文献
585.
586.
Converting Toxic Equivalents (TEQ) of dioxins and dioxin-like compounds in fish from one Toxic Equivalency Factor (TEF) scheme to another 总被引:1,自引:0,他引:1
Toxic Equivalency Factors (TEFs) are an essential part of the Toxic Equivalent (TEQ) concept and have evolved for dioxins/dioxin-like compounds over the last two and half decades. Therefore, it is difficult to compare past and current TEQs that are reported using different TEFs without explicitly mentioning underlying congener concentrations. Using what likely is the largest known dioxin/furan (PCDD/F) and dioxin-like polychlorinated biphenyl (dl-PCB or DLP) fish database, here we present regression models that can facilitate conversion of a fish TEQ from an old to a newer TEF scheme. The results show that the mammalian PCDD/F-TEQ based on the latest TEF(WHO-05) is about 7.5% lower than that based on TEF(WHO-98). The mammalian DLP-TEQ(WHO-05) is on average 25-26% lower than almost identical DLP-TEQ(WHO-94) and DLP-TEQ(WHO-98). Total-TEQ(WHO-05) is on average 22% lower than Total-TEQ(WHO-98). According to the current toxicological standards for dioxins/furans, all previous major TEF schemes except TEF(Germany-85) and TEF(USEPA-87) were conservative (i.e., higher) in estimating TEQs. The major (> 75%) contribution to PCDD/F-TEQ(WHO-05) is from 2,3,7,8-TCDD (33%), 1,2,3,7,8-PCDD (26%), 2,3,7,8-TCDF (10%), and 2,3,4,7,8-PCDF (9%). The DLP-TEQ(WHO-05) is dominated by PCB-126 which on average contributes about 88%. The DLP-TEQ generally contribute > 70% of Total-TEQ. When reporting TEQs, we recommend that the underlying congener specific concentrations are presented, TEF scheme used is clearly stated, names of compounds included are explicitly expressed, and TEQs are identified accordingly (e.g., DLP-TEQ, PCDD/F-TEQ, Total-TEQ). 相似文献
587.
Caterpillars have many natural enemies and, therefore, have evolved a diversity of antipredator strategies. Most research
focuses on those strategies (crypsis, countershading, and warning coloration) targeting visually guided predators. In contrast,
defensive sounds, although documented for more than a century, have been poorly studied. We report on a novel form of sound
production—chirping—in caterpillars of the common European Great Peacock moth (Saturnia pyri). Chirps are broadband, with dominant peaks ranging between the sonic (3.7 kHz) and ultrasonic (55.1 kHz) and are generated
by a rapid succession of mandibular “tooth strikes.” Chirp trains are induced by simulated predator attacks and precede or
accompany the secretion of a defensive chemical from integumental bristles, supporting our hypothesis that these sounds function
in acoustic aposematism. We propose that these caterpillars generate multimodal warning signals (visual, chemical, and acoustic)
to target the dominant sensory modalities of different predators, including birds, bats, and invertebrates.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
588.
Climate change in Australia has become a political risk (for political parties) and a physical, transitional, and regulatory risk for businesses. Not‐for‐profits (NFPs) and for‐purpose (FPs) organisations, for example, Climate Alliance Limited, have acted in the absence of national climate risk policy, to support businesses to become better informed to manage their exposure to this risk, and helping them to set their own commitments and pathways to low and net zero carbon businesses. The objective of this article is to demonstrate, through the case study method, how one Australian NFP/FP has influenced the business sector and regulation. Climate Alliance Limited has done this through its interventions of (1) sharing case studies (best practices) on successful transitions to a low carbon business model and linking climate risk to business risk; (2) bringing thought leaders (advocacy) from the Bank of England and UK Prudential Regulator into the Australian finance and business sector; and (3) by offering a program (reward and recognition), showcasing how business leaders have and are adapting to climate risks and capturing business value. 相似文献
589.
Revealing life‐history traits by contrasting genetic estimations with predictions of effective population size
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Gili Greenbaum Sharon Renan Alan R. Templeton Amos Bouskila David Saltz Daniel I. Rubenstein Shirli Bar‐David 《Conservation biology》2018,32(4):817-827
Effective population size, a central concept in conservation biology, is now routinely estimated from genetic surveys and can also be theoretically predicted from demographic, life‐history, and mating‐system data. By evaluating the consistency of theoretical predictions with empirically estimated effective size, insights can be gained regarding life‐history characteristics and the relative impact of different life‐history traits on genetic drift. These insights can be used to design and inform management strategies aimed at increasing effective population size. We demonstrated this approach by addressing the conservation of a reintroduced population of Asiatic wild ass (Equus hemionus). We estimated the variance effective size (Nev) from genetic data () and formulated predictions for the impacts on Nev of demography, polygyny, female variance in lifetime reproductive success (RS), and heritability of female RS. By contrasting the genetic estimation with theoretical predictions, we found that polygyny was the strongest factor affecting genetic drift because only when accounting for polygyny were predictions consistent with the genetically measured Nev. The comparison of effective‐size estimation and predictions indicated that 10.6% of the males mated per generation when heritability of female RS was unaccounted for (polygyny responsible for 81% decrease in Nev) and 19.5% mated when female RS was accounted for (polygyny responsible for 67% decrease in Nev). Heritability of female RS also affected Nev; (heritability responsible for 41% decrease in Nev). The low effective size is of concern, and we suggest that management actions focus on factors identified as strongly affecting , namely, increasing the availability of artificial water sources to increase number of dominant males contributing to the gene pool. This approach, evaluating life‐history hypotheses in light of their impact on effective population size, and contrasting predictions with genetic measurements, is a general, applicable strategy that can be used to inform conservation practice. 相似文献
590.
Climate policy analysis has come to rely heavily on large‐scale numerical simulation models of increasing complexity, posing a challenge to policy‐makers and other non‐specialists who must interpret and apply the models. This paper provides a “user's guide” to economic models used in climate analysis. We review basic features, underlying design issues, and basic research questions bearing on the models' foundations. We also provide an overview of five such global or world models currently in use. 相似文献