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51.
Jose Oliva Paula Payá Miguel Ángel Cámara Alberto Barba 《Journal of environmental science and health. Part. B》2013,48(7):775-781
The effects of six clarification agents [egg albumin, blood albumin, bentonite + gelatine, charcoal, polyvinylpolypyrrolidine (PVPP) and silica gel] on the removal of residues of three fungicides (famoxadone, fluquinconazole and trifloxystrobin) applied directly to a racked red wine, elaborated from Monastrell variety grapes from the D.O. Region of Jumilla (Murcia, Spain) were studied. The clarified wines were filtered with 0.45 μ m nylon filters to determine the influence of this winemaking process in the disappearance of fungicide residues. Analytical determination of fluquinconazole and trifloxystrobin was performed by gas chromatography with electron captor detector (ECD), while that of famoxadone using an HPLC equipped with a diode array detector (DAD). Generally, trifloxystrobin is the fungicide that is the lowest persistent one in wines, except in the egg albumin study whereas, the most persistent one is fluquinconazole. The elimination depends on the nature of the active ingredient, though the water stability in the presence of light within it has more influence than the solubility and polarity of the product itself. The most effective clarifying agents were the charcoal and PVPP. The silica gel and bentonite plus gelatine were not enough to reduce considerably the residual contents in the wine clarified with them. In general terms, filtration is not an effective step in the elimination of wine residues. The greatest removal after filtration is obtained in wines clarified with egg albumine and bentonite plus gelatine, and the lowest in those clarified with PVPP. 相似文献
52.
Orrù R Cincotti A Concas A Cao G 《Environmental science and pollution research international》2003,10(6):385-389
The possibility of exploiting self-propagating reactions for environmental protection is discussed in this paper. In particular, results obtained at the laboratory scale and related to the fixation and consolidation of high level radioactive wastes, the recycling of silicon sludge and aluminum dross produced by semiconductor industries and aluminum foundries, the treating and recycling of a highly toxic solid waste from electrolytic zinc plants, and the degradation of chlorinated aromatics, are examined with particular emphasis on the latter case. Specifically, the self-propagating destruction of hexachlorobenzene and 2-(2-4-dichlorophenoxy)-propanoic acid with calcium hydride as reductive substrate is demonstrated. In fact, the heat liberated by the reactions involved is large enough to guarantee the self-sustaining character of the process within a wide range of reactants compositions. Moreover, no residual chlorinated organic compounds were found in the final solid product. Some reactor engineering aspects, as well as other significant future scientific and technological issues, are also addressed in view of large-scale applicability of processes based on self-propagating reactions. To date, the batch reactor technology seems to be more easily applicable, although the use of continuous reactors is not excluded in the next future. 相似文献
53.
Luca Salvati Alberto Mancini Sofia Bajocco Roberta Gemmiti Margherita Carlucci 《Regional Environmental Change》2011,11(4):767-777
In recent years, the surface area affected by land degradation (LD) has significantly increased in southern European regions
where the socioeconomic development has been proposed as a basic factor underlying the degree of vulnerability to LD. This
paper investigates the correlation between several socioeconomic indicators and the level of vulnerability to LD in Italy,
expressed as changes (1990–2000) in a composite index of land vulnerability (ΔLVI). The analysis was carried out over 784
local districts. The impact of per capita value added, agricultural intensity, industrial and tourism concentration, and urban
growth was separately tested on ΔLVI. Results indicate that a lower district value added, crop intensification, irrigation,
and the level of land vulnerability to degradation are strongly associated with the increasing level of land vulnerability
over time, highlighting the role of the socioeconomic development as a main process underlying LD. In this framework, spatially
equitable sustainable development may represent the effective strategy to mitigate the detrimental effects of economic growth
and regional disparities on Mediterranean LD. 相似文献
54.
Alberto Megías Antonio Maldonado Andrés Catena Leandro L. Di Stasi Jesús Serrano Antonio Cándido 《Safety Science》2011,49(10):1388-1393
In road safety literature the effects of emotional content and salience of advertising billboards have been scarcely investigated. The main aim of this work was to uncover how affect-laden roadside advertisements can affect attention – eye-movements – and subsequent risky decisions – braking – on the Honda Riding Trainer motorcycle simulator. Results indicated that the number of fixations and total fixation time elicited by the negative and positive emotional advertisements were larger than the neutral ones. At the same time, negative pictures got later gaze disengagement than positive and neutral ones. This attentional capture results in less eye fixation times on the road relevant region, where the important driving events happen. Finally, the negative emotional valence advertisements sped up braking on subsequent risky situations. Overall results demonstrated how advertisements with emotional content modulate attention allocation and driving decisions in risky situations and might be helpful for designing roadside advertisements regulations and risk prevention programs. 相似文献
55.
Marino Tiziana Galiano Francesco Simone Silvia Figoli Alberto 《Environmental science and pollution research international》2019,26(15):14774-14785
Environmental Science and Pollution Research - The possibility of replacing traditional toxic solvents normally employed during the preparation of polymeric membranes with greener alternatives... 相似文献
56.
Carlos Alberto A. de Almeida Carla G.B. Brenner Luciane Minetto Carlos A. Mallmann Ayrton F. Martins 《Chemosphere》2013
In this study, an analytical methodology was developed for the determination of psycho-active drugs in the treated effluent of the University Hospital at the Federal University of Santa Maria, RS – Brazil. Samples were collected from point A (Emergency) and point B (General effluent). The adopted methodology included a pre-concentration procedure involving the use of solid phase extraction and determination by liquid chromatography coupled to mass spectrometry. The limit of detection for bromazepam and lorazepam was 4.9 ± 1.0 ng L−1 and, for carbamazepine, clonazepam and diazepam was 6.1 ± 1.5 ng L−1. The limit of quantification was 30.0 ± 1.1 ng L−1, for bromazepam, clonazepam and lorazepam; for carbamazepine was 50.0 ± 1.8 ng L−1 and was 40.0 ± 1.0 ng L−1 for diazepam. The mean concentrations in the Emergency and General effluent treated currents were as follows: for bromazepam, 195 ± 6 ng L−1 and 137 ± 7 ng L−1; for carbamazepine, 590 ± 6 ng L−1 and 461 ± 10 ng L−1; for diazepam, 645 ± 1 ng L−1 and 571 ± 10 ng L−1; for lorazepam, 96 ± 7 ng L−1 and 42 ± 4 ng L−1; and for clonazepam, 134 ± 10 ng L−1 and 57 ± 10 ng L−1. A preliminary risk assessment was conducted: carbamazepine and diazepam require considerable attention owing to their environmental toxicity. The occurrence of these psychoactive-drugs and the environmental risks that they pose demonstrated the need for a more efficient treatment system. As far we are aware, there have been no comparable studies to this on the hazards of hospital effluents in Brazil, and very few that have carried out a risk assessment of psycho-active drugs in hospital effluent in general. 相似文献
57.
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59.
Carlos Toledo-Hernández Alberto M. Sabat Anabella Zuluaga-Montero 《Marine Biology》2007,152(3):527-535
Gorgonia ventalina’s density, size structure and lesion prevalence was measured at six sites in Puerto Rico that exhibited variation in horizontal
water transparency, sedimentation rates, suspended particle matter, scleractinian and macroalgal cover. G. ventalina density varied significantly among sites (between 0.84 and 0.007 colonies/m2), and was positively correlated with water transparency. Size structure did not vary much among sites, and reflects high
mortality among the smaller size classes and high survivorship in large colonies. Prevalence of active fungi-induced lesions
(type I) did not vary significantly among sites and was density-independent. However, prevalence of old lesions of unknown
origin (type II) did vary among reefs and was negatively correlated with water transparency. Prevalence of types I or II lesions
was independent of colony size. Our results suggest that (1) turbidity and sedimentation are important abiotic factors controlling
the abundance of sea fans, (2) variation in settlement success and early survivorship of recruits has more impact on the sea
fan populations than variation in the survivorship of large colonies and (3) prevalence of aspergillosis (type I) at the studied
sites is similar to that reported for other Caribbean reefs and supports the epizootic nature of the disease and (4) lesions
with exposed skeleton are more likely to be colonized by fouling organisms at impacted reefs. The combined effects of anthropogenic
impacts and aspergillosis may cause local extinctions of sea fans, as is becoming evident in many reefs in Puerto Rico. 相似文献
60.
We investigated the physiological plasticity and environmental tolerance of two phylogenetically closely related, ecologically
similar and co-occurring species of supralittoral amphipods differing drastically in the size of their geographical ranges.
A series of physiological traits were characterised for the Corsican-endemic Talorchestia ugolinii Bella-Santini and Ruffo and the widespread Talitrus saltator Montagu. The effect of body mass, temperature and salinity on heart rate (used as proxy for metabolic activity and stress),
the effect of temperature on oxygen consumption and the tolerance to salinity exposure were investigated in both species,
together with the characterisation of haemolymph osmoregulation in T. ugolinii. Our results showed that there is a clear difference in the resting metabolic rates and physiological capacity, as well as
environmental tolerance, between T. saltator and T. ugolinii, with T. saltator overall showing a broader physiological niche. Although T. ugolinii showed a relatively good ability to regulate its haemolymph osmotic concentration (similar to that previously described for
T. saltator), it demonstrated a lower tolerance to exposure to hypo-osmotic stress. In addition, a consistent picture emerged between
the ability to control the cardiac function and the capacity to actively respond to osmotic stress. The physiological findings
are discussed in relation to the known ecology and geographical distribution of T. ugolinii. 相似文献