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31.
Alberto Notario Iván Bravo José Antonio Adame Yolanda Díaz-de-Mera Alfonso Aranda Ana Rodríguez Diana Rodríguez 《Environmental science and pollution research international》2013,20(9):6059-6069
The purpose of this work is to investigate the behaviour and variability of oxidant levels (OX?=?NO2?+?O3), for the first time, in a rural coastal area in the southwest of the Iberian Peninsula, affected by several air masses types. Detailed database (built-up over the years 2008 to 2011, and containing around 500,000 data) from the Atmospheric Sounding Station “El Arenosillo” was used. The observed daily cycles of NO x and OX were influenced by air masses coming from industrial and urban area. It can be seen that the concentration of OX is made up of a NO x -independent ‘regional’ contribution (i.e. the O3 background), and a linearly NO x -dependent ‘local’ contribution from primary emissions, such as traffic. The local emission is very low in this area. Also, the regional contribution is similar to unpolluted sites and presents seasonal variation, being higher in May. However, our measurements showed that the proportion of OX in the form of NO2 increases with the increase in NO x concentration during the day. The higher proportion of NO2 observed at night must be due to the conversion of NO to NO2 by the NO?+?O3 reaction. With regards to the source of the local NO x -dependent contribution, it may be attributed to industrial emission, or the termolecular reaction 2NO?+?O2?=?2NO2, at high-NO x levels and stagnant air during several days. Finally, we estimated the photolysis rate of NO2, J NO2, an important key atmospheric reaction coupled with ozone. We also present surface plots of annual variation of the daily mean NO x and OX levels, which indicate that oxidants come from transport processes instead of local emissions associated as local photochemistry. 相似文献
32.
This study modeled the impact on freshwater ecosystems of pharmaceuticals detected in biosolids following application on agricultural soils. The detected sulfonamides and hydrochlorothiazide displayed comparatively moderate retention in solid matrices and, therefore, higher transfer fractions from biosolids to the freshwater compartment. However, the residence times of these pharmaceuticals in freshwater were estimated to be short due to abiotic degradation processes. The non-steroidal anti-inflammatory mefenamic acid had the highest environmental impact on aquatic ecosystems and warrants further investigation. The estimation of the solid-water partitioning coefficient was generally the most influential parameter of the probabilistic comparative impact assessment. These results and the modeling approach used in this study serve to prioritize pharmaceuticals in the research effort to assess the risks and the environmental impacts on aquatic biota of these emerging pollutants. 相似文献
33.
Carlos Alberto A. de Almeida Carla G.B. Brenner Luciane Minetto Carlos A. Mallmann Ayrton F. Martins 《Chemosphere》2013
In this study, an analytical methodology was developed for the determination of psycho-active drugs in the treated effluent of the University Hospital at the Federal University of Santa Maria, RS – Brazil. Samples were collected from point A (Emergency) and point B (General effluent). The adopted methodology included a pre-concentration procedure involving the use of solid phase extraction and determination by liquid chromatography coupled to mass spectrometry. The limit of detection for bromazepam and lorazepam was 4.9 ± 1.0 ng L−1 and, for carbamazepine, clonazepam and diazepam was 6.1 ± 1.5 ng L−1. The limit of quantification was 30.0 ± 1.1 ng L−1, for bromazepam, clonazepam and lorazepam; for carbamazepine was 50.0 ± 1.8 ng L−1 and was 40.0 ± 1.0 ng L−1 for diazepam. The mean concentrations in the Emergency and General effluent treated currents were as follows: for bromazepam, 195 ± 6 ng L−1 and 137 ± 7 ng L−1; for carbamazepine, 590 ± 6 ng L−1 and 461 ± 10 ng L−1; for diazepam, 645 ± 1 ng L−1 and 571 ± 10 ng L−1; for lorazepam, 96 ± 7 ng L−1 and 42 ± 4 ng L−1; and for clonazepam, 134 ± 10 ng L−1 and 57 ± 10 ng L−1. A preliminary risk assessment was conducted: carbamazepine and diazepam require considerable attention owing to their environmental toxicity. The occurrence of these psychoactive-drugs and the environmental risks that they pose demonstrated the need for a more efficient treatment system. As far we are aware, there have been no comparable studies to this on the hazards of hospital effluents in Brazil, and very few that have carried out a risk assessment of psycho-active drugs in hospital effluent in general. 相似文献
34.
Ramos-Gómez J Coz A Viguri JR Luque A Martín-Díaz ML DelValls TÁ 《Environmental pollution (Barking, Essex : 1987)》2011,159(7):1914-1922
Biomarkers comprising activities of biotransformation enzymes (ethoxyresorufin-O-deethylase -EROD-, dibenzylfluorescein dealkylase -DBF-, glutathione S-transferase -GST), antioxidant enzymes (glutathione reductase -GR- and glutathione peroxidase -GPX), lipid peroxidation -LPO- and DNA strand breaks were analyzed in the clam Ruditapes philippinarum caged at Cádiz Bay, Santander Bay and Las Palmas de Gran Canaria (LPGC) Port (Spain). Sediments were characterized. Digestive gland was the most sensitive tissue to sediment contamination. In Cádiz Bay, changes in LPO regarding day 0 were related with metals. In LPGC Port, DBF, EROD, and GST activity responses suggested the presence of undetermined contaminants which might have led to DNA damage. In Santander Bay, PAHs were related with EROD activity, organic and metal contamination was found to be associated with GR and GST activities and DNA damage presented significant (p < 0.05) induction. R. philippinarum was sensitive to sediment contamination at biochemical level. Biomarkers allowed chemical exposure and sediment quality assessment. 相似文献
35.
Angioni A Dedola F Garau A Sarais G Cabras P Caboni P 《Journal of environmental science and health. Part. B》2011,46(6):544-549
Chlorpyrifos (O,O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate) was applied with three different formulations on oranges, peaches, tomatoes, wine and table grapes, and its behaviour was evaluated after field treatment. The formulations applied were emulsifiable concentrates (EC), microencapsulates (ME), and wettable granules (WG). The residues were similar in all crops studied in the EC and WG experiments, except peaches with WG treatment, the residue amount was lower than EC values. Tomatoes which were grown in greenhouse showed similar residues in all treatments just after treatment. Wine and table grapes showed different decline curves in the EC experiments ascribable to the different growing technology. Instrumental limit of determination (LOD) and limit of quantification (LOQ) for all matrices were 0.01, and 0.03 mg kg?1, respectively. Repeated treatments showed that Chlorpyrifos can accumulate leading to residue levels at the preharvest interval (PHI) over the maximum residue level (MRL), especially on oranges and peaches. Among the formulates used ME showed the higher risk of residues over the MRL at harvest. 相似文献
36.
Ruiz I Morales A Oliva J Barba A 《Journal of environmental science and health. Part. B》2011,46(6):530-534
An analytical procedure has been developed for the determination of natural pyrethrins (pyrethrin I, pyrethrin II, jasmolin I, jasmolin II, cinerin I and cinerin II) in lemon and apricot. The QuEChERS method, which stands for quick, easy, cheap, effective, rugged and safe was used for extraction. Analysis of the extract was performed by liquid-chromatography-electrospray ionisation-tandem mass spectrometry. The ions prominent in the ESI spectra were [M+H]+ for the six compounds. A Zorbax SB-C18 column was used with a programmed gradient mobile phase consisting of (A) water containing 0.1% formic acid and 5 mM ammonium formate and (B) ACN. The method was linear within the investigated concentration range, displaying a calibration curve correlation factor of 0.99. The coefficients of variation obtained (RSD) were below 20% and the recoveries were in the 70-110% range. 相似文献
37.
Morales A Ruiz I Oliva J Barba A 《Journal of environmental science and health. Part. B》2011,46(6):525-529
A method for the detection and quantification of 16 pesticides: flufenoxuron, fenoxycarb, dimethomorph, acetamiprid, imidacloprid, lufenuron, thiacloprid, thiabendazole, thiophanate-methyl, spinosad, fenbutatin oxide, methoxyfenozide, oxamyl, clothianidin, thiamethoxam and carbendazim has been developed based on high-performance liquid chromatography-mass spectrometry. Pesticide residues were extracted from the samples according to the QuEChERS method which stands for quick, essay, cheap, effective, rugged and safe. Homogenised analytical portions (10 g ± 0.1) of samples of peppers were spiked at two levels (10 and 100 μg kg?1) with a small volume of an appropriate standard mixture solution containing each pesticide. Analyses were performed using electrospray ionization (ESI) and a MSD trap system. Chromatography separation was achieved using a ZORBAX SB-C18 3.5 μm particle size analytical column, 2.1 × 50 mm from Agilent, with gradient elution at a flow-rate of 0.4 mL/min with mobile phases: waters-0.1 % HCOOH-5 mM HCOONH? and MeOH-5 mM HCOONH?. The method has been validated based on the SANCO European Guidelines. Under the optimized conditions the recoveries (n = 7) were in the range 70-110 % with satisfactory precision (CV ≤ 20 %). A linear dynamic range was obtained over a range of concentrations from 10 to 100 μg kg?1 for each of the analytes, with correlation coefficients >0.997. 相似文献
38.
Luca Salvati Alberto Mancini Sofia Bajocco Roberta Gemmiti Margherita Carlucci 《Regional Environmental Change》2011,11(4):767-777
In recent years, the surface area affected by land degradation (LD) has significantly increased in southern European regions
where the socioeconomic development has been proposed as a basic factor underlying the degree of vulnerability to LD. This
paper investigates the correlation between several socioeconomic indicators and the level of vulnerability to LD in Italy,
expressed as changes (1990–2000) in a composite index of land vulnerability (ΔLVI). The analysis was carried out over 784
local districts. The impact of per capita value added, agricultural intensity, industrial and tourism concentration, and urban
growth was separately tested on ΔLVI. Results indicate that a lower district value added, crop intensification, irrigation,
and the level of land vulnerability to degradation are strongly associated with the increasing level of land vulnerability
over time, highlighting the role of the socioeconomic development as a main process underlying LD. In this framework, spatially
equitable sustainable development may represent the effective strategy to mitigate the detrimental effects of economic growth
and regional disparities on Mediterranean LD. 相似文献
39.
The activity of 210Po and 210Pb was determined in mussels of the same size (3.5-4.0 cm shell length) sampled monthly over a 17-month period at the Atlantic coast of Portugal. Average radionuclide concentration values in mussels were 759 ± 277 Bq kg−1 for 210Po (range 460-1470 Bq kg−1 dry weight), and 45 ± 19 Bq kg−1 for 210Pb (range 23-96 Bq kg−1 dry weight). Environmental parameters and mussel biometric parameters were monitored during the same period. Although there was no seasonal variation of radionuclide concentrations in sea water during the study period, the concentration of radionuclide activity in mussels varied seasonally displaying peaks of high concentrations in winter and low concentrations in summer. Analysis of radionuclide data in relation to the physiological Condition Index of mussels revealed that 210Po and 210Pb activities in the mussel (average activity per individual) remained nearly constant during the investigation period, while mussel body weight fluctuated due to fat storage/expenditure in the soft tissues. Similar variation of radionuclide concentrations was observed in mussels transplanted from the sea coast into the Tejo Estuary. However, under estuarine environmental conditions and with higher food availability throughout the year, transplanted mussel Condition Index was higher than in coastal mussels and average radionuclide concentrations were 210 ± 75 Bq kg−1 (dry weight) for 210Po and 10 ± 4 Bq kg−1 (dry weight) for 210Pb, therefore lower than in coastal mussels with similar shell length. It is concluded that the apparent seasonal fluctuation and inter-site difference of radionuclide concentrations were mostly caused by mussel body weight fluctuation and not by radionuclide body burden fluctuation. This interpretation can be extended to the apparent seasonal fluctuation in concentrations of lipophilic and lipophobic contaminants in mussels, and provides an explanation for occasional high concentrations of 210Po and man-made contaminants measured in mussels far from pollution sources. 相似文献
40.
Sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of the Biobio River in south central Chile 总被引:2,自引:0,他引:2
Ricardo Barra Roberto Quiroz Katia Saez Alberto Araneda Roberto Urrutia Peter Popp 《Environmental Chemistry Letters》2009,7(2):133-139
Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in the environment; there are concerns about them due to their toxic
properties. Human activities could significantly contribute to the total PAH burden in river sediments. In this work, we document
the analysis of PAHs in sediments taken in the middle stretch of the Biobio River in south central Chile. This river is a
principal system, draining more than 24,000 km2 and subjected to a diverse variety of human-made stressors (pulp mill and urban effluents, agricultural drainage systems,
etc). During 2003, several sediment samples were taken in more than 45 sampling sites located in the river’s middle stretch.
Due to the granulometric characteristics (mainly sandy sediments), only 17 samples were analyzed, taking into consideration
the presence of a fine section within the sediment sample. Using HPLC with fluorescence detection, 15 EPA priority PAHs and
perylene were analyzed. The composition of PAHs in the sediment samples is rather similar between sites and levels averaged
104 ± 78 ng g−1 d.w. The highest levels were detected downstream from an industrial discharge. A good correlation was observed between PAH
levels and organic carbon content in the tested sediments; however, concentrations above 134 ng g−1 d.w. did not indicate correlation. The samples PAH ratios (Flu/Pyr and Chr/B(a)A) reveal a strong pyrolytic PAH pattern in
the sediments tested, supporting evidence indicating that PAHs come mainly from pyrolytic sources. This result contrasts with
previous records that have shown a natural influence in the upper basin and a petrogenic pattern near the mouth. 相似文献