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111.
112.
Diane Ciaparra Eric Aries Marie-Jo Booth David R. Anderson Susana Marta Almeida Stuart Harrad 《Atmospheric environment (Oxford, England : 1994)》2009,43(12):2070-2079
Investigations have been undertaken at two integrated steelworks in the UK to characterise airborne organic micro-pollutants and to assess the contribution of iron ore sintering and coke making operations on the air quality. Concentrations of volatile organic compounds (VOCs), namely benzene, toluene and p-xylene, were measured continuously within the boundary of a coking plant using for the first time differential optical absorption spectrometry (DOAS) between 2004 and 2006. Concentrations were obtained along two monitoring paths surrounding the coke plant and the average benzene concentration measured along both paths over the campaign was 28 μg m?3. Highest benzene concentrations were associated with winds downwind of the coke oven batteries. Concentrations of polycyclic aromatic hydrocarbons (PAHs) in ambient air were measured during 27 consecutive days in 2005 at three different locations on an integrated steelworks. PAH profiles were determined for each sampling point and compared to coke oven and sinter plant emission profiles showing an impact from the steelworks. The mean benzo [a] pyrene concentration determined in the immediate vicinity of the coke ovens downwind from the battery was 19 ng m?3, whereas for the two other sites average benzo [a] pyrene concentrations were much lower (around 1 ng m?3). Data were analysed using principal components analysis (PCA) and results showed that coke making and iron ore sintering were responsible for most of the variation in the PAH concentrations in the vicinity of the investigated plant. 相似文献
113.
114.
Freitas MC Farinha MM Ventura MG Almeida SM Reis MA Pacheco AM 《Environmental monitoring and assessment》2005,109(1-3):81-95
This paper describes concentration amounts of arsenic (As), particulate mercury (Hg), nickel (Ni) and lead (Pb) in PM10 and PM2.5, collected since 1993 by the Technological and Nuclear Institute (ITN) at different locations in mainland Portugal, featuring
urban, industrial and rural environments, and a control as well. Most results were obtained in the vicinity of coal- and oil-fired
power plants. Airborne mass concentrations were determined by gravimetry. As and Hg concentrations were obtained through instrumental
neutron activation analysis (INAA), and Ni and Pb concentrations through proton-induced X-ray emission (PIXE). Comparison
with the EU (European Union) and the US EPA (United States Environmental Protection Agency) directives for Ambient Air has
been carried out, even though the sampling protocols herein – set within the framework of ITN's R&D projects and/or monitoring
contracts – were not consistent with the former regulations. Taking this into account, 1) the EU daily limit for PM10 was exceeded a few times in all sites except the control, even if the number of times was still inferior to the allowed one;
2) the EU annual mean for PM10 was exceeded at one site; 3) the EPA daily limit for PM2.5 was exceeded one time at three sites; 4) the EPA annual mean for PM2.5 was exceeded at most sites; 5) the inner-Lisboa site approached or exceeded the legislated PMs; 6) Pb levels stayed far below
the EU limit value; and 7) concentrations of As, Ni and Hg were also far less than the reference values adopted by EU. In
every location, Ni appeared more concentrated in PM2.5 than in coarser particles, and its levels were not that different from site to site, excluding the control. The highest As
and Hg concentrations were found in the neighbourhood of the coal-fired, utility power plants. The results may be viewed as
a “worst-case scenario” of atmospheric pollution, since they have been obtained in busy urban-industrial areas and/or near
major power-generation and waste-incineration facilities. 相似文献
115.
Almeida MD Lacerda LD Bastos WR Herrmann JC 《Environmental pollution (Barking, Essex : 1987)》2005,137(2):179-186
This work reports on the effect of land use change on Hg distribution in Amazon soils. It provides a comparison among Hg concentrations and distribution along soil profiles under different land use categories; primary tropical forest, slashed forest prior to burning, a 1-year silviculture plot planted after 4 years of forest removal and a 5-year-old pasture plot. Mercury concentrations were highest in deeper (60-80 cm) layers in all four plots. Forest soils showed the highest Hg concentrations, ranging from 128 ngg(-1) at the soil surface to 150 ngg(-1) at 60-80 cm of depth. Lower concentrations were found in pasture soils, ranging from 69 ngg(-1) at the topsoil to 135 ngg(-1) at 60-80 cm of depth. Slashed and silviculture soils showed intermediate concentrations. Differences among plots of different soil-use categories decreased with soil depth, being non-significant below 60 cm of depth. Mercury burdens were only statistically significantly different between pasture and forest soils at the topsoil, due to the large variability of concentrations. Consequently, estimated Hg losses were only significant between these two land use categories, and only for the surface layers. Estimated Hg loss due to forest conversion to pasture ranged from 8.5 mgm(-2) to 18.5 mgm(-2), for the first 20 cm of the soil profile. Mercury loss was comparable to loss rates estimated for other Amazon sites and seems to be directly related to Hg concentrations present in soils. 相似文献
116.
Almeida JA Novelli EL Dal Pai Silva M Júnior RA 《Environmental pollution (Barking, Essex : 1987)》2001,114(2):169-175
The contamination of water by metal compounds is a worldwide environmental problem. This study was undertaken to evaluate the impact of short-term cadmium exposure on metabolic patterns of the freshwater fish Oreochromis niloticus. The fish were exposed to 320, 640, 1,280 and 2,560 microg/l sublethal concentrations of Cd++ (CdCl2) in water for 7 days. The specific activities of the enzymes phosphofructo kinase (PFK-E.C.2.7.1.11.), lactate dehydrogenase (LDH-E.C.1.1.1.27.) and creatine kinase (CKE.C.2.7.3.2.) were decreased in white muscle after cadmium treatments, indicating decreases in the capacity of glycolysis in this tissue. Cadmium exposure induced increased glucose concentration in white muscle of fish. On the other hand, cadmium exposure at sublethal concentrations increased phosphofructo kinase and LDH in red muscle of fish. Cadmium significantly decreased total protein concentrations in liver and white muscle regardless of tissue glycogen levels. The data suggest that cadmium acts as a stressor, leading to metabolic alterations similar to those observed in starvation. 相似文献
117.
118.
Tatiane Becker Pedro Aurélio Costa Lima Pequeno Gislene Almeida Carvalho-Zilse 《Die Naturwissenschaften》2018,105(9-10):55
Temperature is a major driver of biological phenomena, from metabolism to ecological interactions and rates of evolutionary diversification. However, species vary greatly in their thermal tolerance, as well as the temperature under which they perform best. This study aimed to investigate the effect of experimental manipulation of environmental temperatures on the individual mortality and phenotypic composition of colonies of Melipona interrupta. To fulfill these objectives, 30 colonies in equivalent developmental conditions were artificially subjected to different temperatures. Temperatures were monitored by thermo-hygrometers, and immature mortality and sex and caste ratios were observed in brood combs during 14 months. A strong effect of external temperature on immatures was detected on deviations from 28 to 30 °C (the natural average temperature inside the colony), causing an increase in mortality. Likewise, a significant effect of temperature on sex ratio was detected, with male:female ratio decreasing at temperatures below and above 28–30 °C. Lastly, there was no clear evidence for an effect of temperature on caste ratio, although queens appeared to become relatively more frequent at warmer temperatures. The results of this study allow us to conclude that anthropogenic changes, whose effect can be extrapolated to the similar natural changes, that modify the environmental temperatures to which M. interrupta colonies are exposed are likely to compromise their survival, mainly through individual mortality. 相似文献
119.
Matheus Ribeiro da Silva Assis Carmen Baur Vieira Julia Monassa Fioretti Mônica Simões Rocha Pedro Ivo Neves de Almeida Marize Pereira Miagostovich Tulio Machado Fumian 《Food and environmental virology》2016,8(4):305-309
Gemycircularvirus (GemyCV) is a group of viruses which has been recently proposed as a new viral genus detected in fecal and environmental samples around the world. GemyCVs have been detected in human blood, brain tissue, cerebrospinal fluid, and stool sample. In the present study, we demonstrate for the first time, through molecular detection and characterization, the presence of GemyCVs in environmental samples from Brazil. Our results show a percentage of positivity ranging from 69 (25/36) to 97 % (35/36) in river water samples collected in Manaus, Amazon region, and wastewater from a wastewater treatment plant located in Rio de Janeiro, respectively, revealing GemyCVs as an important environmental contaminant. 相似文献
120.
Godoy JM de Oliveira MS de Almeida CE de Carvalho ZL da Silva ER Fernandes Fda C Pitanga FL Danelon OM 《Journal of environmental radioactivity》2008,99(4):631-640
Twenty ropes with 400 Perna perna mussels seeds (3 cm shell size) were set-up on floating structures at Cabo Frio Island, Arraial do Cabo, approximately 100 km northeast of Rio de Janeiro city. A rope was taken out on a monthly basis, and the shell sizes of 100 seeds were measured. The haemolymph of 10 male and 10 female individuals was taken, and the same individuals were separated for 210Po/210Pb determination. After one year of monthly sampling, no clear correlation was observed between the 210Po concentration, mussel's age and weight. A mean 210Po concentration of 155 Bq kg(-1) wet weight basis, was obtained, which is comparable with data reported in the literature. The radiation dose did not have any observable effect on the micronuclei frequency and DNA breaks in the mussels. This was probably due to the low dose rate, 0.02 mGy d(-1), in comparison with the suggested potential dose limit of 10 mGy d(-1). 相似文献