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111.
Tatiana Calvete Eder C. Lima Natali F. Cardoso Júlio C.P. Vaghetti Silvio L.P. Dias Flavio A. Pavan 《Journal of environmental management》2010,91(8):1695-1706
Activated (AC-PW) and non-activated (C-PW) carbonaceous materials were prepared from the Brazilian-pine fruit shell (Araucaria angustifolia) and tested as adsorbents for the removal of reactive orange 16 dye (RO-16) from aqueous effluents. The effects of shaking time, adsorbent dosage and pH on the adsorption capacity were studied. RO-16 uptake was favorable at pH values ranging from 2.0 to 3.0 and from 2.0 to 7.0 for C-PW and AC-PW, respectively. The contact time required to obtain the equilibrium using C-PW and AC-PW as adsorbents was 5 and 4 h at 298 K, respectively. The fractionary-order kinetic model provided the best fit to experimental data compared with other models. Equilibrium data were better fit to the Sips isotherm model using C-PW and AC-PW as adsorbents. The enthalpy and entropy of adsorption of RO-16 were obtained from adsorption experiments ranging from 298 to 323 K. 相似文献
112.
Simas Angélica Mores Rúbia Steffens Juliana Dallago Rogério Marcos Kunz Airton Michelon William Fongaro Gislaine Viancelli Aline 《Environmental Chemistry Letters》2019,17(1):495-499
Environmental Chemistry Letters - Swine production generates large volumes of wastewater, rich in organic matter, nutrients and pathogens. Electrodisinfection is used to remove organic matter and... 相似文献
113.
Diogenes Meneses José Guimarães F. Júnior Paulo Cesar Costa de Oliveira 《Environmental monitoring and assessment》2018,190(10):617
This work proposes the quantification of Cr (VI) ions in natural waters in trace level, using activated alumina (Al2O3) as preconcentration support, controlled in-line dissolution of the solidified chromophore diphenylcarbazide after heat treatment and spectrophotometric detection. The manifold ensures high sensitivity of analytical response, good repeatability, and stability. In this work, optimization of experimental conditions of a flow injection system was chosen as the parameters for greater sensitivity and better selectivity. The selected optimized conditions were 0.30 mol L?1 for H2SO4 concentration, system flow rate as 0.40 mL min?1, sample injection volume of 192.50 μL, 2 min for preconcentration time, and 0.10 mol L?1 for eluent concentration. The analytical curves obtained for real sample analysis show linear range from 0.192 to 0.961 μM, linear correlation coefficient R?=?0.9997 and LOD?=?0.024 μM. The preconcentration factor of about four times was obtained through the passage of 800 μL of a standard solution containing 0.961 μM of Cr (VI) through mini-column of preconcentration followed by elution at 192.5 μL of NH4OH 0.1 mol L?1 solution. The solid chromogenic reagent presented high durability (weeks in daily use with mass of 0.0993 g) and good reproducibility in analytical signal. The reactivation of the mini-column of alumina should be executed after ten injections of eluent, using 800 μL of HCl 0.02 mol L?1 solution in flow through the same. Each cycle of injection and elution of the sample takes about 5 min on the proposed terms. Despite the length of each cycle still be high, low concentrations can be detected using a technique of relatively low cost. This is due in part, the association dissolution of the chromogenic reagent directly in the line and the preconcentration step. Another important factor is the economy of reagent chromogenic, low generation of reject contributing to better quality of the environment, and the high potential for applications to work in field. 相似文献
114.
Július Árvay Ján Tomáš Martin Hauptvogl Miriama Kopernická Anton Kováčik Daniel Bajčan 《Journal of environmental science and health. Part. B》2013,48(11):815-827
The aim of this study was to evaluate the contamination of six edible wild species of mushrooms (Boletus pulverulentus, Cantharellus cibarius, Lactarius quietus, Macrolepiota procera, Russula xerampelina and Suillus grevillei) by heavy metals (Hg, Cd, Pb, Zn, Cu, Ni, Cr, Co, Mn and Fe). Mushroom samples were collected from sites contaminated by emissions from mining and processing of polymetallic ores in operation during the period 1969–1993 in Rudňany, southeast Slovakia. The four study sites spanned up to a 5-km distance from the emission source. The collected mushroom samples were analyzed using Flame Atomic Absorption Spectrophotometry and/or Flame Atomic Absorption Spectrophotometry with graphite furnace. Mercury, Cd and, in some samples, also Pb present the highest risks in terms of contamination of the food chain following subsequent consumption. The content of two metals in the dry matter (dm) of the mushrooms exceeded the limits set by the European Union (EU; Cd: 0.5 mg/kg dm, Pb: 1.0 mg/kg dm). The highest mean contents of the eight metals recorded for S. grevillei were 52.2, 2.15, 107, 104, 2.27, 2.49, 81.6 and 434 mg/kg dm for Hg, Pb, Zn, Cu, Ni, Cr, Mn and Fe, respectively. The highest content of Cd was recorded in M. procera (3.05 mg/kg dm) and that of Co in L. quietus (0.90 mg/kg dm). The calculated weekly intake for Hg, Pb and Cd shows that regular consumption of mushrooms from the studied area poses risks to human health. 相似文献
115.
116.
The present study describes the emergence pattern of loggerhead sea turtle hatchlings (Caretta caretta) from a nesting beach in Kyparissia Bay (Greece). We try to establish the role played by hatchling biometry, nest relocation
and distance from nest to the sea on this emergence pattern. We surveyed a total of 32 nests, and found long emergence periods
(mean = 6.7 nights). The majority of emergences occurred at night, mainly between 0030 and 0100 hours, and in small groups.
Most of the hatchlings emerged from the nests the first night. We found no clear trend when we studied the effect of hatchling
biometry between successive emergence days. We also found that relocation of the nests did not significantly affect the emergence
pattern. However, we noted that in the relocated nests, hatchlings emerged in smaller groups. Emergence periods were inversely
related to distance from the sea. In short, factors such as climate conditions, relocation and nest distance to the sea appear
to have some effect on the emergence pattern. Therefore, they should be taken into account in both biological studies and
management plans for sea turtle nesting beaches. Our results suggest leaving an extended period between the first emergence
of hatchlings and the excavation of nests by researchers in future studies in the area. 相似文献
117.
Jonathan M. P. Torres Kalina Bermúdez Marmolejo-Rodríguez Ana Judith López Eugenia López 《Environmental science and pollution research international》2022,29(41):61547-61549
Environmental Science and Pollution Research - 相似文献
118.
Diniz Vinicius Rath Gabriela Rath Susanne Araújo Larissa Sene Cunha Davi Gasparini Fernandes 《Environmental science and pollution research international》2022,29(28):42185-42200
Environmental Science and Pollution Research - Activated carbon (AC) can be used for the removal of emerging contaminants (e.g., drugs) in water and wastewater treatment plants. In the present... 相似文献
119.
Bolliger Janine Schmatz Dirk Pazúr Robert Ostapowicz Katarzyna Psomas Achilleas 《Regional Environmental Change》2017,17(8):2265-2277
Regional Environmental Change - Understanding drivers of forest-cover change is essential for a broad range of ecosystem properties. In this work, we assessed changes in forest cover using... 相似文献
120.