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101.
102.
Tina Kosjek Noelia Negreira Ester Heath Miren López de Alda Damià Barceló 《Environmental science and pollution research international》2016,23(15):14706-14717
Etoposide susceptibility to microbiological breakdown was studied in a batch biotransformation system, in the presence or absence of artificial wastewater containing nutrients, salts and activated sludge at two concentration levels. The primary focus of the present study was to study etoposide transformation products by ultra-high performance liquid chromatography coupled to high-resolution hybrid quadrupole-Orbitrap tandem mass spectrometry (MS/MS). Data-dependent experiments combining full-scan MS data with product ion spectra were acquired to identify the molecular ions of etoposide transformation products, to propose the molecular formulae and to elucidate their chemical structures. Due to the complexity of the matrix, visual inspection of the chromatograms showed no clear differences between the controls and the treated samples. Therefore, the software package MZmine was used to facilitate the identification of the transformation products and speed up the data analysis. In total, we propose five transformation products; among them, four are described as etoposide transformation products for the first time. Even though the chemical structures of these new compounds cannot be confirmed due to the lack of standards, their molecular formulae can be used to target them in monitoring studies. 相似文献
103.
Joshua Eli Cinner Morgan Stuart Pratchett Nicholas Anthony James Graham Vanessa Messmer Mariana Menezes Prata Bezerra Fuentes Tracy Ainsworth Natalie Ban Line Kolind Bay Jessica Blythe Delphine Dissard Simon Dunn Louisa Evans Michael Fabinyi Pedro Fidelman Joana Figueiredo Ashley John Frisch Christopher John Fulton Christina Chemtai Hicks Vimoksalehi Lukoschek Jennie Mallela Aurelie Moya Lucie Penin Jodie Lynn Rummer Stefan Walker David Hall Williamson 《Regional Environmental Change》2016,16(4):1133-1146
Corals and coral-associated species are highly vulnerable to the emerging effects of global climate change. The widespread degradation of coral reefs, which will be accelerated by climate change, jeopardizes the goods and services that tropical nations derive from reef ecosystems. However, climate change impacts to reef social–ecological systems can also be bi-directional. For example, some climate impacts, such as storms and sea level rise, can directly impact societies, with repercussions for how they interact with the environment. This study identifies the multiple impact pathways within coral reef social–ecological systems arising from four key climatic drivers: increased sea surface temperature, severe tropical storms, sea level rise and ocean acidification. We develop a novel framework for investigating climate change impacts in social–ecological systems, which helps to highlight the diverse impacts that must be considered in order to develop a more complete understanding of the impacts of climate change, as well as developing appropriate management actions to mitigate climate change impacts on coral reef and people. 相似文献
104.
Ferreira Felipe Silva Brito Samuel Vieira de Oliveira Almeida Waltécio Alves Rômulo Romeu Nóbrega 《Regional Environmental Change》2016,16(2):543-551
Regional Environmental Change - The use and trade of animals in traditional medicine involves many different species, some of which are threatened with extinction. Thus, evaluating biological and... 相似文献
105.
Thomas H. Hutchinson Amanda Beesley Patricia E. Frickers James W. Readman Jenny P. Shaw Jürg Oliver Straub 《Environment international》2009,35(6):931-936
In case of an avian-influenza-derived human flu pandemic, an inordinately high use of medicines over several weeks is predicted, in particular for the recommended influenza antiviral oseltamivir (Tamiflu). While the risk of oseltamivir to sewage works and freshwater bodies has already been assessed, the fact that a large percentage of the human population worldwide lives relatively close to the sea raises concern for its environmental compatibility in coastal marine waters. The potential risk of high oseltamivir use to the marine compartment is assessed in this publication, based on the 2003 European Community Technical Guidance Document (TGD) for risk assessment. Subchronic embryo–larval ecotoxicity tests with three marine invertebrates (Pomatoceros triqueter, Annelida; Mytilus edulis, Mollusca; Paracentrotus lividus, Echinodermata) and chronic growth inhibition tests with two different groups of marine microalgae (Isochrysis galbana, Haptophyta; Skeletonema costatum, Heterokontophyta) were performed with the active substance oseltamivir carboxylic acid to derive a dependable marine predicted no-effect concentration (PNEC). This was compared to a predicted environmental concentration (PEC) for oseltamivir in coastal waters, based on the worst-case freshwater PEC. The PEC/PNEC risk characterisation ratio for the marine compartment is well below 1, which in the terminology of the TGD signifies no immediate concern. Further, while oseltamivir may be persistent (P), it is not bioaccumulative (B) nor highly ecotoxic (T) and therefore not a PBT substance. In conclusion, even a high pandemic use of oseltamivir would not lead to a significant risk for the marine compartment, in confirmation of the risk assessment for sewage works and freshwaters. 相似文献
106.
Jean-Franois Viel Elisabeth Cardis Monika Moissonnier Ren de Seze Martine Hours 《Environment international》2009,35(8):1150-1154
Information on the exposure of individual persons to radiofrequency (RF) fields is scarce, although such data are crucial in order to develop a suitable exposure assessment method, and frame the hypothesis and design of future epidemiological studies. The main goal of this survey is to assess individual RF exposure on a population basis, while clarifying the relative contribution of different sources to the total exposure. A total of 377 randomly selected people were analyzed. Each participant was supplied with a personal exposure meter for 24-hour measurements (weekday), and kept a time–location–activity diary. Electric field strengths were recorded in 12 different RF bands every 13 s. Summary statistics were calculated with the robust regression on order statistics method. Most of the time, recorded field strengths were not detectable with the exposure meter. Total field, cordless phones, WiFi-microwave, and FM transmitters stood apart with a proportion above the detection threshold of 46.6%, 17.2%, 14.1%, and 11.0%, respectively. The total field mean value was 0.201 V/m, higher in urban areas, during daytime, among adults, and when moving. When focusing on specific channels, the highest mean exposure resulted from FM sources (0.044 V/m), followed by WiFi-microwaves (0.038 V/m), cordless phones (0.037 V/m), and mobile phones (UMTS: 0.036 V/m, UMTS: 0.037 V/m). Various factors, however, contributed to a high variability in RF exposure assessment. These population-based estimates should therefore be confirmed by further surveys to better characterize the exposure situation in different microenvironments. 相似文献
107.
Marisia P. Esposito Mauricio L. Ferreira Silvia M.R. Sant'Anna Marisa Domingos Silvia R. Souza 《Atmospheric environment (Oxford, England : 1994)》2009,43(3):619-623
Previous studies have reported that the extent of leaf injury in Nicotiana tabacum “Bel-W3” exposed to environmental conditions in the city of São Paulo is influenced by weather conditions. This influence may occur by means of antioxidant responses. Thus, this study aimed to evaluate whether daily antioxidant responses to environmental variations interfere on the progression of leaf injury on plants of this cultivar during their exposure in a state park of São Paulo and to determine a linear combination of variables, among antioxidants and environmental factors, which mostly explain this visible response. Plants were exposed at the mentioned site for 14 days in four different experiments. During each experiment, three plants were daily sampled to determine the accumulated percentage of leaf area affected by necrosis and antioxidant responses (concentrations of total ascorbic acid (AA) and activity of superoxide dismutase (SOD) and peroxidases (POD)). Ozone concentrations and weather conditions were also daily measured. Pearson correlations and multivariate analyses assessed the relationship between biological and environmental variables. Leaf injury appeared between the 3rd and 6th days of exposure and increased over the exposure periods. The daily concentrations of AA tended to decrease with time of exposure in all experiments, but the activity of SOD and POD oscillated during plant exposure. Positive correlations were observed between AA or SOD and O3 concentrations, as well as negative correlations between AA and air temperature. The increasing percentage of leaf necrosis across the whole period was explained by decreasing levels of AA 2 days before injury estimation and by higher O3 concentrations 5 days before (R2 = 0.36; p < 0.001). The use of N. tabacum Bel-W3 as a bioindicator can be restricted by leaf antioxidant responses to both atmospheric contamination and weather conditions. 相似文献
108.
Gabriel Ibarra-Berastegi Jon Sáenz Agustín Ezcurra Unai Ganzedo Javier Díaz de Argandoña Iñigo Errasti Alejandro Fernandez-Ferrero Josué Polanco-Martínez 《Atmospheric environment (Oxford, England : 1994)》2009,43(25):3829-3836
In Bilbao (Spain), an air quality network measures sulphur dioxide levels at 4 locations. The objective of this paper is to develop a practical methodology to identify redundant sensors and evaluate a network's capability to correctly follow and represent SO2 fields in Bilbao, in the frame of a continuous network optimization process.The methodology is developed and tested at this particular location, but it is general enough to be useable at other places as well, since it is not tied neither to the particular geographical characteristics of the place nor to the phenomenology of the air quality over the area.To assess the spatial variability of SO2 measured at 4 locations in the area, three different techniques have been used: Self-Organizing Maps (SOMs), cluster analysis (CA) and Principal Component Analysis (PCA). The results show that the three techniques yield the same results, but the information obtained via PCA can be helpful not only for that purpose but also to throw light on the major mechanisms involved. This might be used in future network optimization stages. The main advantage of cluster analysis and SOMs is that they provide readily interpretable results. All the calculations have been carried out using the freely available software R. 相似文献
109.
There is growing concern that recreational shoreline angling activity may negatively impact littoral and riparian habitats
independent of any direct or indirect influences of fish harvest or fishing mortality through mechanisms such as disturbance
(e.g., trampling, erosion) and pollution (e.g., littering). We sampled a suite of aquatic and terrestrial variables (i.e.,
water quality, aquatic and terrestrial macrophytes, soil compaction, anthropogenic refuse) at 14 high shoreline angling-activity
sites (identified by way of interviews with conservation officers and angling clubs) within an urban area (Ottawa, Canada).
For each high angling-activity site, a nearby corresponding low angling-activity site was sampled for comparison. We found
that the percentage of barren area and soil compaction were greater in areas of high angling activity compared with areas
that experienced relatively low angling activity. In addition, terrestrial and aquatic macrophyte density, height, and diversity
were lower at high angling-activity sites. Angling- and non-angling-related litter was present in large quantities at each
of the high angling-activity sites, and comparatively little litter was found at low angling-activity sites. Collectively,
these findings indicate that shoreline angling does alter the riparian environment, contributing to pollution and environmental
degradation in areas of high angling intensity. With growing interest in providing urban angling opportunities and in response
to increasing interest in developing protected areas and parks, a better understanding of the ecologic impacts of shoreline
angling is necessary to address multiuser conflicts, to develop angler outreach and educational materials, and to optimize
management of angling effort to maintain ecologic integrity of riparian and aquatic ecosystems. 相似文献
110.
Itziar de Aranzabal María F. Schmitz Francisco D. Pineda 《Environmental management》2009,44(5):938-951
Tourism and landscape are interdependent concepts. Nature- and culture-based tourism are now quite well developed activities
and can constitute an excellent way of exploiting the natural resources of certain areas, and should therefore be considered
as key objectives in landscape planning and management in a growing number of countries. All of this calls for careful evaluation
of the effects of tourism on the territory. This article focuses on an integrated spatial method for landscape analysis aimed
at quantifying the relationship between preferences of visitors and landscape features. The spatial expression of the model
relating types of leisure and recreational preferences to the potential capacity of the landscape to meet them involves a
set of maps showing degrees of potential visitor satisfaction. The method constitutes a useful tool for the design of tourism
planning and management strategies, with landscape conservation as a reference. 相似文献