Novel Biodegradable Cast Film from Cherry Tree Gum,Development, Modification and Characterization

The feasibility of sweet cherry gum as a bio-based film-forming material and effect of hydrogen peroxide as a chemical modifier investigated. The influence of film compositions (gum, glycerol) and hydrogen peroxide on the physical properties of films, including solubility in water, permeability to water vapor (WVP), mechanical properties, and transparency, thermal and microstructural properties evaluated. The results showed that WVP and thickness increased by gum and glycerol concentration, but significantly decreased by hydrogen peroxide. As expected, elongation-at-break and solubility, increased at higher concentration of glycerol but the tensile strength decreased at the same condition. The film transparency was influenced by the dry weight content and was improved by higher concentrations of hydrogen peroxide. The partial degradation of polymer chain by hydrogen peroxide was observed by FTIR analysis.     

Orange Juice Processing Waste as a Biopolymer Base for Biodegradable Film Formation Reinforced with Cellulose Nanofiber and Activated with Nettle Essential Oil

Journal of Polymers and the Environment - Concerns about environmental problems have led to the development of biodegradable packaging. Food wastes as a byproduct could be a good source for...     

Adsorption of Crystal Violet Dye from Aqueous Solution by Poly(Acrylamide-<Emphasis Type="Italic">co</Emphasis>-Maleic Acid)/Montmorillonite Nanocomposite

Poly(acrylamide-co-maleic acid)/montmorillonite nanocomposites, were synthesized via in situ polymerization with different maleic acid and MMT content. The capability of the hydrogel for adsorption of crystal violet (CV) was investigated in aqueous solutions at different pH values and temperatures. The pseudo-second-order kinetics model could fit successfully the adsorption kinetic data. The effects of maleic acid to acrylamide molar ratio (MA_R), weight percent of MMT (MMT%), the pH of medium and the solution temperature (T) on the CV adsorption capacity (q _e ) of adsorbents were studied by Taguchi experimental design approach. The results indicated that increasing the MMT% leads to a greater q _e . The q _e value of adsorbents increased also with increasing both MA_R and pH, while reduced when the temperature of medium increased. The relatively optimum conditions to achieve a maximum CV adsorption capacity for P(AAm/MA)/MMT adsorbents were found as: 0.06 for MA_R and 5 % of MMT%, medium pH = 7 and T = 20 °C.     

Investigation of the Thermosensitive Nanosphere Polymer in Removing Organophosphorus Pesticides from Water and Its Isotherm Study (Case Study: Diazinon)

In this research, a novel thermosensitive nanosphere polymer (TNP) was synthesized by copolymerization of N-isopropylacrylamide with 3-allyloxy-1,2-propanediol for the removal of diazinon from water. The characterization of the synthesized adsorbent has been performed by Fourier transform infrared spectrometer, scanning electron microscopy and elemental analysis. Batch adsorption method was performed to investigate the influences of various parameters like pH, temperature and contact time on the adsorption of diazinon. The equilibrium adsorption data of diazinon by TNP was studied by Langmuir, Freundlich, Temkin and Redlich–Peterson model. According to equilibrium adsorption results, the Langmuir, Freundlich and Temkin constants were evaluated to be 0.912 (L/mg), 7.916 (mg/g) (L/mg)^1/n and 2.494 respectively at pH 7 and room temperature. Based on Redlich–Peterson model analysis, the equilibrium data for the adsorption of diazinon was conformed well to the Langmuir isotherm model. This method was successfully applied for removal of diazinon from environmental samples. Moreover, in reusing of TNP, the sorption capacity was maintained without any significant change after 10 cycles of sorption–desorption process.     

Evaluation of environmental impacts of large scale physical development in central Galilee: Role of experts and policy makers

This article reports on the content and process used to evaluate environmental impacts caused by the development of 50 new settlements in the central Galilee region in northern Israel between 1978 and 1988. Some 60 different environmental and developmental factors and their interrelationships were identified. Selected physical changes that were defined as impacts were later evaluated. The evaluation method was based on intensive use of interviews with resource scientists and decision makers as experts. The data from interviews were used as the basis for factors identification, impact screening, and their rating. Experts used three types of criteria in the latter process: intensity of impact, the potential for its mitigation and compatibility with existing natural resource conservation, and environmental quality protection policy. Researchers concluded that reliance on experts with broad local experience eliminated the need for a more structured and detailed assessment method. The case study shows that experts provided creditable and reliable findings. They substituted the need for long periods of observation and largescale and costly data gathering, analysis, and evaluation.     

Minimum quantity lubrication in grinding: effects of abrasive and coolant–lubricant types

This research has been conducted to study the influence of the abrasive and coolant–lubricant types on the minimum quantity lubrication (MQL) grinding performance. One type of CBN and three types of conventional wheels (corundum) have been tested. The tests have been performed in presence of fluid, air jet and eleven types of coolant–lubricants, as well as, in dry condition. The results indicate that the finest surface quality and lower grinding forces could be obtained while grinding with CBN wheel. In case of conventional wheels, the coarser and high porosity wheels induce much proper grinding results. Furthermore, grinding when utilizing MQL with oil results in higher grinding performance.