药厂、啤酒厂等有机废水厌氧处理试验研究

针对几种高浓度有机废水进行厌氧处理试验,取得参数,为生产性试验提供有价值的参数。     

聚异丁烯丁二酰亚胺尾气吸收系统的改进

针对聚异丁烯丁二酰亚胺生产工艺中废气排放量大、尾气吸收得到的盐酸含油量高、难以销售等问题,在分析原因的基础上,对尾气吸收系统进行了技术改进。尾气吸收系统改进后,排放的HCl和Cl2的质量浓度分别由65,42mg／m^3降至为零;产品综合收率由89．5％增加至96．0％;产品成本降低了700元/t。     

Geotechnical and leaching properties of flowable fill incorporating waste foundry sand

Waste foundry sand (WFS) can be converted into flowable fill for geotechnical applications. In this study, WFS samples were obtained from 17 independent metal casting facilities with different casting processes, thus representing a good range of WFS properties. The laboratory studies include physical, geotechnical and leaching properties of flowable fills consisting of WFS, cement, and fly ash mixed to different water contents. The main properties measured include WFS physical properties (density, particle gradation, grain shape, and fine content), WFS flowable fill geotechnical properties (unconfined compressive strength, hydraulic conductivity, setting time, and bleeding), and the fill's leaching properties (heavy metals and organics in the bleed water and the leachate extracted from hardened WFS flowable fills). The test results indicate that in terms of the physical properties, most of the data fall within narrow ranges, although data from the copper/aluminum-based WFS samples might fall beyond the ranges. Geotechnical properties of WFS flowable fills in both fresh and hardened phases were verified conforming to the features of specified flowable fills. Material leaching analyses indicate that the toxicity of WFS flowable fills is below regulated criteria. A mix formulation range originated from this study is proposed for the design of WFS made flowable fill.     

TiO2-PTFE光催化膜的制备及性能

以聚四氟乙烯（PTFE）乳液和纳米TiO2粉末为原料,采用无水乙醇为溶剂,经辊压后与不锈钢网结合,制备了多孔固定化TiO2-PTFE光催化膜。膜性能研究结果表明,m（TiO2）：m（PTFE）=4时,光催化反应处理质量浓度为20mg／L的苯甲酸溶液,2h内TOC去除率高达81．3％。通过扫描电子显微镜观察,TiO2-PTFE光催化膜表面平整,且孔隙分布均匀。TiO2最佳负载量为15mg／cm2。在优化反应条件下同悬浮态TiO2光催化反应体系相比,TiO2-PTFE光催化膜对光源有更高的利用率,表现出更佳的催化活性。     

氯酚与富里酸的缔合作用

本文用超滤膜方法证实氯酚与富里酸之间存在缔合作用,并计算出表观缔合常数在２．７＊１０＾３－－１２１＊１０＾３ｍｌ．ｇ＾－１范围内。实验结果表明”ＰＨ、富里酸含量,氯酚取代氯原子个数都能够影响Ｋ值的大小。     

单甲脒饱和蒸气压的测定和估算

用气体的法测单甲脒在１５,２５,３５和４５℃时的饱和蒸气分别为０．２０２,０．５５４６,１．９５,６．２９Ｐａ;亨利常数计算值分别为６．３０×１０＾－４,１．６７×１０＾－３,５．６８×１０＾０－３和１．７８×１０＆－２,根据Ｃｌａｕｓｉｕｓ Ｃｌａｐｅｙｒｏｎ方程求出单甲脒在常温下气化热为８９．２ｋＪ．ｍｏｌ＾－１。     

Comparison of forest edge effects on throughfall deposition in different forest types

This study examined the influence of distance to the forest edge, forest type, and time on Cl⁻, SO₄²⁻, NO₃⁻, and NH₄⁺ throughfall deposition in forest edges. The forests were dominated by pedunculate oak, silver birch, or Corsican/Austrian pine, and were situated in two regions of Flanders (Belgium). Along transects, throughfall deposition was monitored at distances of 0-128 m from the forest edge. A repeated-measures analysis demonstrated that time, forest type, and distance to the forest edge significantly influenced throughfall deposition of the ions studied. The effect of distance to the forest edge depended significantly on forest type in the deposition of Cl⁻, SO₄²⁻, and NO₃⁻: the edge effect was significantly greater in pine stands than in deciduous birch and oak stands. This finding supports the possibility of converting pine plantations into oak or birch forests in order to mitigate the input of nitrogen and potentially acidifying deposition.     

近30年来长江口北支及口外沉积特征及输移趋势

近30 a来长江口北支在自然和人类活动影响下，沉积物特征及输移趋势发生显著变化。研究基于2015年和20世纪80年代沉积物粒度调查资料，通过粒度对比、趋势分析等方法，探讨长江口北支及口外沉积特征与输移趋势。结果表明：长江口北支及口外沉积物类型以粘土质粉砂、砂质粉砂和砂为主，近30 a来平均中值粒径减小20%左右。其中，北支口内粒径减小约30%，表明北支口内整体为淤积环境；口外0~10 m水深区域粒径增加约25%，表现为风浪和潮流作用下的侵蚀特征；10 m水深外，粒径略有减小，沉积特征基本稳定。从沉积物输移趋势上看，北支崇头至灵甸港河段，沉积物较粗，以径流作用下的沉积为主；灵甸港至三条港河段，沉积物输移趋势向下指向三条港，其中灵甸港至三和港河段边滩粗、主槽细，径潮流交汇作用明显；三条港以下河段，沉积物以海域来沙为主，颗粒细，输移趋势指向上游；北支口外，0~10 m水深区域，沉积物粗化，沉积物随水深增加变细，其中0~2 m水深区域，砂含量占比超过90%；10 m以深离岸水域，沉积物输移趋势不显著。流域来沙减少和北支围垦工程建设，致使沿岸泥沙补给不足，口外浅滩泥沙在风浪和潮流作用下，一部分随涨潮流向口内输运，一部分随落潮流向外海扩散，构成北支及口外沉积物输移趋势格局。     

香港的策略性污水排放计划及其进展

为了保障香港市民的身体健康,保护鱼类及其他海洋生物并提高维多利亚港的水质,必须对香港的150万m3/d污水采取处理措施,介绍了策略性污水排放计划的产生及一期工程的进展情况.