武汉城市圈土地利用碳排放效应分析及因素分解研究

土地低碳利用对减少土地利用碳排放,发展低碳经济,建设“两型社会”具有重要作用。以武汉城市圈为研究对象,估算了武汉城市圈1996～2010年土地利用碳排放量,分析了城市圈1996～2010年土地利用碳排放效应,利用LMDI模型对影响城市圈土地利用碳排放的因素进行了分解。研究表明：（1）1996～2010年武汉城市圈土地利用碳排放量由1996年的95282万t上升到2010年的4 55035万t,年均增长1182%,且上升幅度越来越大;（2）武汉城市圈居民点及工矿用地碳排放强度最大,耕地最小,不同土地利用方式碳排放强度及变化幅度存在一定差异;（3）城市圈各城市土地利用碳排放存在时空差异,时间上表现为碳排放增长速度和幅度的差异,空间上表现为各城市单元碳排放量的差异;（4）土地利用变化、经济发展水平提高、人口规模增加对城市圈土地利用碳排放存在正效应,能源效率提高和能源结构优化存在负效应     

Photolytic degradation of decabromodiphenyl ethane (DBDPE)

The photolytic degradation of decabromodiphenyl ethane (DBDPE), an alternative flame retardant to decabromodiphenyl ether, was investigated in a variety of matrixes (n-hexane, tetrahydrofuran, methanol/water, humic acid/water, and silica gel) by irradiation under ultraviolet light and in n-hexane under natural light. Photolytic degradation of DBDPE occurs in all the matrixes investigated within the irradiation period (<320 min). The degradation experiments showed varied reaction rates, dependent on the matrixes, with increasing half-lives (t_1/2) in the order of tetrahydrofuran (t_1/2 = 6.0 min) > n-hexane (t_1/2 = 16.6 min) > humic acid/water (30 < t_1/2 < 60) > silica gel (t_1/2 = 75.9 min) > methanol/water (t_1/2 > 240 min). The reaction in tetrahydrofuran, n-hexane, and silica gel matrixes can be described by the pseudo first order kinetics. Nevertheless, the matrixes have little effect on the degradation product distributions of DBDPE. A numbers of debrominated intermediates were identified. The degradation involves the initial formation of nona-BDPEs and the subsequent decomposition of these congeners to lower brominated congeners (octa- and hepta-BDPEs) within the irradiation time. To our knowledge, the present work is the first attempt to investigate the photolytic degradation kinetics and the identification of intermediates, as well as the degradation mechanism, during the degradation of DBDPE. Further research is needed to understand the photolytic degradation pattern of DBDPE in the natural environment.     

Efficient bio-deodorization of aniline vapor in a biotrickling filter: metabolic mineralization and bacterial community analysis

A biotrickling filter inoculated with commercial mixed microorganisms B350 was employed to treat N-containing odorous vapor - aniline. Results indicated no aniline could be detected when empty bed residence time (EBRT) was larger than 110s at inlet concentration of 0.30 g m(-3). The variation of inlet concentration did not change removal efficiencies when concentration is less than 0.21 g m(-3) at fixed EBRT 110s. Biodegradation mechanism of aniline was tentatively proposed based on identified intermediates and predicted biodegradation pathway as well as final mineralized products. Aniline was firstly biodegraded to catechol, and then to levulinic acid and subsequently to succinic acid. Finally, about 62% aniline carbon was completely mineralized to CO(2), while about 91% aniline nitrogen was converted into ammonia and nitrate. Bacterial community in biotrickling filter was found that at least seven bands microbes were identified for high efficiencies of bioreactor at stable state. In all, biotrickling filter seeded with B350 would be a better choice for the purification odorous gas containing high concentration aniline.     

多能场协同紫外光催化降解甲基橙的实验研究

以甲基橙为模拟废水,负载型纳米TiO2为光催化剂,在自制的多能场组合反应器中,初步研究了电场和超声场协同紫外光催化降解水中甲基橙的特点和规律。结果表明,在偏置电场电压为20 v,超声场声频为21.33 kHz、声强为0.375 W/cm2,紫外光波长为366 nm,功耗为O.25 W/mL,TiO2催化降解负荷为1.25 mL/cm2的条件下,对浓度为4 mg/L的甲基橙溶液分别处理30 min和90 min,脱色率分别可达91.67％和95.36％;比单一紫外光催化降解脱色率分别提高86.59％和86.79％。     

Carrousel氧化沟系统出水COD预报的神经网络模型

以河南漯河市污水净化中心的氧化沟系统为考察对象,针对该系统进水水质复杂,控制滞后的难点,引入人工神经网络的理论和方法,对其进行模拟分析,建立了基于BP网络的氧化沟系统出水COD预报模型。模型性能检验和灵敏度检验表明,建成的模型准确度高,适应性强,可直接用于该系统出水COD预报。这为氧化沟工艺在线控制提供了一条简便的途径。     

贵州省水资源承载力的空间地域差异

水资源承载力是一个国家或地区可持续发展过程中各种自然资源承载力的重要组成部分,对一个国家或地区综合的发展和发展规模有至关重要的影响。由于水资源承载力是涉及到人口、社会经济发展以及资源环境在内的复杂巨系统,通过利用综合多种因素的状态空间法,从综合、宏观的角度来描述研究区域现实的承载状况,并对其进行定量化表示和分析。以贵州省为例,根据其具体情况,选取了9个指标构成评价指标体系,并对各指标运用反映客观赋权的熵值法进行权重的确定,然后通过状态空间法求算出贵州省现实的水资源承载状态值及其理想状态值。计算结果表明,贵州省目前的水资源承载状况总体上处于超载状态,但不同的地区又有所差异,表现出一定的空间地域性。根据贵州省水资源承载的现状值与理想值的比较,把整个贵州省水资源承载力划分为3种类型区：严重超载区、满载区及可载区。计算结果符合贵州省水资源实际情况,对贵州省水资源的可持续利用具有一定的现实指导意义。     

川西南柳杉早材、晩材年表与温度和降雨的关系

年轮宽度和气候要素的相关或响应分析已大量应用在气候 树木生长的相互作用研究中。以川西南区瓦屋山自然保护区速生树种柳杉（Cryptomeria fortunei）的71个样芯,探讨了温度和降雨与柳杉早材、晩材年表的关系,结果表明早材径向生长对温度变化比较敏感,早材年轮指数序列与当年4月的平均温度、4月平均最高温度、上年9、10月平均最高温度间呈显著正相关关系,与当年7月平均温度以及上年11月最低温度间均存在显著负相关关系;晚材年轮序列与当年10月的平均最高温度呈显著正相关关系。柳杉早材年轮的生长过程中气温“滞后效应”表现明显,特别是在上个生长季的9～10月,最高温度的变化对柳杉当年生长季节形成较宽的年轮有重要的作用。不同的季节温度、降水量变化影响早材、晚材年轮的形成与生长     

插层改性累托石对水性环氧涂料性能的影响

根据累托石可进行阳离子交换的矿物学特征,先将天然累托石钠基化,再用氟碳表面活性剂和复合季铵盐对其进行插层改性,使有机铵阳离子进入累托石层间,并使层间距由2.41nm撑开至4.75nm,将插层改性后的累托石用作水性环氧涂料的防沉剂和流变助剂.结果表明:当插层改性累托石用量为颜填料质量的2%时,可以显著改善涂料的流平性、抗流挂性和颜填料的分散性.     

Size-segregated trace elements in continental suburban aerosols: seasonal variation and estimation of local,regional, and remote emission sources

We have measured trace element contents in suburban aerosols from six size fractions in the range of PM_0.27–16 from a background station in Belgrade (Serbia). The distribution and concentration of elements were determined within each of the investigated Dp fractions with emphasis on the fine and coarse modes. Fine/coarse mode ratios of element can provide information regarding their anthropogenic or natural origin. Analysis of seasonal variations of element contents in fine and coarse mode show that Cd, Co, K, and V have higher concentrations in the fine mode during heating season, while Fe contents are lower. In the coarse mode, Cu and V have higher concentrations during the heating season, while Al, Fe, Mg, Mn, and Sb contents are lower. We also apply a distribution probability model (normal, log-normal, and three-parameter Weibull) as new approach to estimate the distances of emission sources that can contribute to pollutant contents in particulate matter of the investigated location.     

Use of headspace SPME-GC-MS for the analysis of the volatiles produced by indoor molds grown on different substrates

An automated headspace solid phase microextraction method followed by GC-MS analysis was used to evaluate and compare the in vitro production of microbial volatile organic compounds (MVOCs) on malt extract agar, plasterboard and wallpaper. Five fungal strains were isolated from the walls of water-damaged houses and identified. In addition, four other common molds were studied. In general, MVOC production was the highest on malt extract agar. On this synthetic medium, molds typically produced 2-methylpropanol, 2-methylbutanol and 3-methylbutanol. On wallpaper, mainly 2-ethylhexanol, methyl 2-ethylhexanoate and compounds of the C8-complex such as 1-octene-3-ol, 3-octanone, 3-octanol and 1,3-octadiene were detected. The detection of 2-ethylhexanol and methyl 2-ethylhexanoate indicates an enhanced degradation of the substrate by most fungi. For growth on plasterboard, no typical metabolites were detected. Despite these metabolite differences on malt extract agar, wallpaper and plasterboard, some molds also produced specific compounds independently of the used substrate, such as trichodiene from Fusarium sporotrichioides and aristolochene from Penicillium roqueforti. Therefore, these metabolites can be used as markers for the identification and maybe also mycotoxin production of these molds. All five investigated Penicillium spp. in this study were able to produce two specific diterpenes, which were not produced by the other species studied. These two compounds, which remain unidentified until now, therefore seem specific for Penicillium spp. and are potentially interesting for the monitoring of this fungal genus. Further experiments will be performed with other Penicillium spp. to study the possibility that these two compounds are specific for this group of molds.