一种新的处理甲基汞废水的树脂:石油亚砜萃淋树脂

本文对从高硫原油很容易制取的一种新的廉价萃取剂——石油亚砜(PSO)所合成的树脂,即PSO萃淋树脂处理低浓度甲基汞废水的可能性进行了研究。研究结果表明:在中性范围内(pH5—8)树脂对甲基汞的吸附能力很强,吸附率≥99％(废水浓度为10—20ppb);随着流速的增加,吸附率下降幅度很小;树脂易再生, 十倍树脂体积的再生剂(4mol HCl),洗脱率可达97.9％,再生五个周期后,净化率未见明显变化;Mg~(2+)、Fe~(2+)(Fe~(3+)、Ag+、cu~(2+)、Hg~(2+)、PA(黄腐酸)及Cl~-的干扰实验表咀除Hg~(2+)、Ag+外,其他离子基本没有影响。     

Study on low-temperature plasma γ-Al2O3 catalytic viscosity reduction of polyacrylamide solution

The wide use of polyacrylamide (PAM) in enhanced oil recovery generates a large amount of polymer-bearing wastewater featuring high viscosity and difficult viscosity reduction, making the treatment of wastewater increasingly difficult. In this paper, the experimental study on reducing the viscosity of wastewater containing polyacrylamide by using the plasma generated by dielectric barrier discharge (DBD) and the synergistic effect of catalyst γ-Al₂O₃ is carried out. The law of plasma reducing the viscosity of wastewater containing polyacrylamide is studied under the different conditions of amounts of γ-Al₂O₃ catalyst, discharge voltages, and initial concentrations of polyacrylamide-containing wastewater. The mechanism of viscosity reduction of polyacrylamide is studied through environmental scanning electron microscope (ESEM), Fourier transform infrared (FTIR) spectrometer, and X-ray photoelectron spectroscopy (XPS). The results show that the catalytic viscosity reduction is the best when the discharge voltage is 18 kV and the discharge time is 15 min. With the increase in the input of the γ-Al₂O₃ catalyst, the viscosity of the PAM solution decreases gradually. When the amount of γ-Al₂O₃ is 375 mg, the shear rate changes from 0.5 1/sec to 28 1/sec, and the viscosity of the solution containing polyacrylamide changes from 434.5 mPa·s to 40.2 mPa·s. The viscosity reduction rate of the PAM solution is 90.7%. After the catalytic viscosity reduction, the functional groups of polyacrylamide do not change much. The elemental composition of the catalyst has not changed, which is still Al, C, and O.

     

Artificial aging induced changes in biochar,s properties and Cd2+ adsorption behaviors

Environmental Science and Pollution Research - Fresh biochar has been widely applied to the remediation of heavy metals in soil by its property of adsorption, but the changes in its physicochemical...     

微生物磁效应及其强化废/污水生物处理的研究进展

介绍了微生物磁效应的现象、原理及其在强化废/污水生物处理过程应用的研究进展,包括磁场对微生物运动、微生物生长、微生物酶活力以及对活性污泥法或生物接触氧化法处理废/污水过程的影响。提出生物亲和亲水磁性填料以及磁粉的合理运用,可能是实现微生物磁效应在废/污水生物处理中应用的有效途径。     

大九湖泥炭磁化率及腐殖化度记录的18.7 Ka BP气候变化

神农架大九湖泥炭沼泽是中纬度亚热带地区的高山泥炭沼泽,其连续沉积的泥炭剖面蕴含了丰富的气候变化信息,对揭示我国中纬度地区不同时间尺度的气候环境变化有着重要意义。使用碱提取溶液吸光度法对大九湖泥炭吸光度进行测定,以E4/E6比值表征腐殖化度,同时测定了泥炭的磁化率,通过AMS14C测年技术建立了神农架大九湖泥炭地的年代序列,结合区域的其他气候代用指标,分析大九湖泥炭磁化率与腐殖化度E4/E6的古气候意义：大九湖泥炭频率磁化率值高指示气候冷干,降水量小;磁化率值偏低指示气候暖湿,降水量大。E4/E6值高,腐殖化度低,指示气候冷干;值低,腐殖化度高,指示气候暖湿。探讨大九湖地区末次冰消期以来的气候变化,重建该区18.7 Ka BP 的气候演化过程：末次冰期结束期（18.7~11.7 Ka BP）气候比较冷干,期间存在气候冷暖干湿交替波动;全新世（11.7~0 Ka BP）以来,气温开始回升,气候比较暖湿,期间也存在突发性降温事件,其中,全新世早期（11.7~9.3 Ka BP）气候冷暖干湿交替波动,总体冷湿;全新世中期（9.3~3.5 Ka BP）气候暖湿;全新世晚期（3.5~0 Ka BP）气候温干。 关键词： 泥炭;磁化率;E4/E6;大九湖;气候变化     

安庆西江长江江豚饵料鱼资源评估

安庆西江是长江江豚（Neophocaena asiaeorientalis asiaeorientalis）迁地保护的重要基地,为评估西江长江江豚饵料资源的供给能力,于2016年8月和2017年1月采用水声学探测与电捕取样相结合的方法,评估了西江水域鱼类群落结构和长江江豚可持续利用的鱼类资源。共采集到鱼类5目8科34种,夏季鱼类密度为1.4～5 662.3 ind./1 000 m3,均值为 253.3 ind./1 000 m3;冬季鱼类密度为0.8～2 338.1 ind./1 000 m3,均值为127.5 ind./1 000 m3。基于平均生物量和P/B-系数估算了西江鱼类生产力,并根据Y=0.5P对江豚可持续利用的饵料鱼产量进行了估算,西江可持续供长江江豚摄食的鱼类资源量约为 3 050～40 800 kg/a。为防止凶猛性鱼类种群过度发展与长江江豚争夺饵料资源,建议加强对西江鱼类群落的持续监测,并在必要时进行人工合理调控。 关键词： 西江;水声学;长江江豚;现存量;最大持续产量     

加强环境保护宣传教育提高公众环境意识

社会与科技的快速发展虽然为人们创造了更加良好的生存环境,但同时,也对实际的环境保护宣传教育提出了更多要求。在此情况之下,相关人员必须要对公众的环境意识进行全面的了解,结合当下的发展趋势和环境保护现状,有针对性的对环境保护宣传教育进行创新与改革。另外,还必须要考虑公众的生活习惯和工作习惯的变化,构建全新的环境保护宣传教育平台,科学利用现代化科技和多样化方式来引导公众进行环境保护知识学习。这样不仅能够全面提升公众的环境意识,同时也能够有效地实现环境友好型和资源节约型社会的全面构建。     

Sea salt bittern-driven forward osmosis for nutrient recovery from black water: A dual waste-to-resource innovation via the osmotic membrane process

• A dual “waste-to-resource” application of FO was proposed. • Performance of sea salt bittern as an economic FO draw solution was evaluated. • High quality struvite recovery from black water using FO was demonstrated. • Feed pH is a key factor to control the form of recovered phosphorous. A dual “waste-to-resource” innovation in nutrient enrichment and recovery from domestic black water using a sea salt bittern (SSB)-driven forward osmosis (FO) process is proposed and demonstrated. The performance of SSB as a “waste-to-resource” draw solution for FO was first evaluated. A synthetic SSB-driven FO provided a water flux of 25.67±3.36 L/m²⋅h, which was 1.5‒1.7 times compared with synthetic seawater, 1 M NaCl, and 1 M MgCl₂. Slightly compromised performance regarding reverse solute selectivity was observed. In compensation, the enhanced reverse diffusion of Mg²⁺ suggested superior potential in terms of recovering nutrients in the form of struvite precipitation. The nutrient enrichment was performed using both the pre-filtered influent and effluent of a domestic septic tank. Over 80% of phosphate-P recovery was achieved from both low- and high-strength black water at a feed volume reduction up to 80%‒90%. With an elevated feed pH (~9), approximately 60%‒85% enriched phosphate-P was able to be recovered in the form of precipitated stuvite. Whereas the enrichment performance of total Kjeldahl nitrogen (TKN) largely differed depending on the strength of black water. Improved concentration factor (i.e., 3-folds) and retention (>60%) of TKN was obtained in the high-nutrient-strength black water at a feed volume reduction of 80%, in comparison with a weak TKN enrichment observed in low-strength black water. The results suggested a good potential for nutrient recovery based on this dual “waste-to-resource” FO system with proper management of membrane cleaning.     

Invasion costs,impacts, and human agency: response to Sagoff 2020

Article impact statement: In an era of profound biodiversity crisis, invasion costs, invader impacts, and human agency should not be dismissed.     

山东省经济结构的失衡水平:测度和比较

山东省是中国经济发展最快的省区之一,但随着经济增长的不断推进所积累的矛盾和失衡水平也逐渐提高,经济发展的可持续性日趋降低。为考察山东省经济发展的现状,明确山东省经济结构中存在的问题,该文拟根据文献[1]的方法,构建省域经济结构失衡程度指标体系。考虑到省域经济的特殊性,确定了包括产业结构、投资消费结构、金融结构、省内经济结构和国际收支结构5大类共17个指标作为基本指标体系,对近10年以来山东省经济结构失衡程度进行了测试,并且利用相同的指标体系对广东、江苏、浙江等东部代表性省区以及全国的整体结构失衡水平进行了测度和比较分析,明确了山东省经济结构失衡的绝对水平和相对水平。结果表明:山东省经济结构失衡现象较为突出,经济发展的可持续性日趋降低。本文建议山东省加快第三产业发展,理顺投资与消费的关系,提高国民经济中消费所占比重,平衡省内各市际间经济发展水平才能真正缓解经济结构失衡状况,增强可持续发展的动力。