Study of the solubility and stability of polystyrene wastes in a dissolution recycling process

Dissolution with suitable solvents is one of the cheapest and more efficient processes for polystyrene waste management. In this work the solubility of polystyrene foams in several solvents benzene, toluene, xylene, tetrahydrofuran, chloroform, 1,3-butanediol, 2-butanol, linalool, geraniol, d-limonene, p-cymene, terpinene, phellandrene, terpineol, menthol, eucalyptol, cinnamaldheyde, nitrobenzene, N,N-dimethylformamide and water has been determined.Experimental results have shown that to develop a “green process” the constituents of essential oils, d-limonene, p-cymene, terpinene, phellandrene, are the most appropriate solvents. The action of these solvent does not produce any degradation of polymer chains. The solubility of the polymer in the mentioned solvents at different temperatures has been investigated. The solvent can be easily recycled by distillation.     

Progress on including CCS projects in the CDM: Insights on increased awareness,market potential and baseline methodologies

The inclusion of CO₂ capture and storage (CCS) in the Kyoto Protocol's Clean Development Mechanism (CDM) is still subject to controversy and discussion. A myriad of barriers prevents CCS in the CDM. Apart from political barriers, economic, social and procedural barriers play a role. This paper discusses relevant new results on the human capacity, procedural feasibility and economic potential of CCS in the CDM. The conclusions of a capacity building effort in Africa show that awareness and knowledge are low but that capacity building efforts are well received. A reality check on methodologies for hypothetical CCS projects shows that most of the issues can be resolved, and the CDM institutional arrangements can accommodate CCS. A bottom-up estimate of the potential of natural gas processing CCS in the CDM, based on a previously proprietary database from the oil and gas industry, suggests that there is an annual potential of about 174 MtCO₂ in 2020 in that sector. Most of that potential can be realized at CER prices between $20 and $30/tCO₂ but there is no sign of flooding the CDM market with cheap credits from CCS projects. Despite these results and more open information, the CCS and CDM debate, progress in the negotiations on CCS in the CDM is slow and there is no clear view on a solution.     

The concept of the Portuguese National Ecological Reserve: constraints and impossibilities in the Azores Archipelago

The biophysical features of small islands (SI) distinguish them from other territories; isolation, small size and several anthropogenic pressures reduce the resilience of ecosystems and increase their vulnerability to global changes. Many SI have a shortage of infrastructures, institutions and technical/financial resources that hinder planning and require different integrated solutions. In Portugal, the National Ecological Reserve (NER) is legally binding for spatial planning instruments. It aims to defend natural values and areas of ecological value, or sensibility, or susceptible to natural hazards. However, the criteria for the design of NER are strictly set for mainland territory, not taking into account specific features of small islands. A case study of the Azores Archipelago is used to demonstrate that spatial planning instruments should be adapted to island contexts. Such adaptation will increase the effectiveness of their implementation in relation to the protection of natural resources, stability of biophysical structures and prevention of natural hazards. Observing the main differences between mainland and the Azores Archipelago it is possible to define a methodological transposition of the NER aims and goals into an island context. This approach is an answer to the constraints in effective adaptation of spatial planning instruments for islands.     

纳米铜颗粒的种间毒性关系

纳米颗粒的种间毒性关系尚无明确结论,因此很难判断纳米颗粒对未进行毒性测试的物种的风险如何。本文作者将5种水蚤(Daphnia magna, Daphnia pulex, Daphnia galeata, Ceriodaphnia dubia, Chydorus sphaericus)暴露于4种不同粒径的纳米铜颗粒(CuNPs)和1种亚微米铜颗粒的悬浊液中,考察物种的形态特征与CuNPs急性毒性的关系。结果显示,杆状的CuNPs比球状的CuNPs毒性更低。纳米铜颗粒与溶出铜离子均对CuNPs的毒性有贡献,其中,当新生蚤的体长、体表面积和身体体积更小时,5种悬浊液中颗粒的毒性更大。5种蚤的身体体积与5种CuNPs的毒性显著相关(r_adj²>0.51, p < 0.001),78-nm CuNPs与蚤身体体积的相关性最好 (r_adj²?=?0.95, p < 0.001)。这个研究可以为纳米颗粒对有相似外形特征的物种进行毒性种间外推提供线索。
精选自Lan Song, Martina G. Vijver, Geert R. de Snoo and Willie J.G.M. Peijnenburg. Assessing toxicity of copper nanoparticles across five cladoceran species. Environmental Toxicology and Chemistry: Volume 34, Issue 8, pages 1744–1750, August 2015. DOI: 10.1002/etc.3000
详情请见http://onlinelibrary.wiley.com/doi/10.1002/etc.3000/full