Fullerenes toxicity and electronic properties

Nanotechnology globally represents a new direction within scientific development, where the atomic and electronic properties of molecules are used in a unique fashion to produce and construct new and exotic materials and products. Fullerenes (Bucky balls, C₆₀) constitute a particular group within the field of nanotechnology. Fullerenes find applications in medicine, industrial chemistry and electronics. However, there are several unanswered questions about fullerenes and their toxicological properties. Most toxicological studies on fullerenes evolve around the in vitro and in vivo aspects of pristine C₆₀ along with chemically modified C₆₀ molecules. We reviewed toxicology reports on C₆₀. We bring a critical and challenging evaluation of the electronic and quantum properties of C₆₀ molecules in context with the implications on cellular factors and metabolites. The evaluation shows that the reactivity and quantum chemical properties of C₆₀ can have unexpected effects in the cell, by principally absorbing metabolites, such as OH^? and H⁺ ions and alter its reactivity. We thus challenge the present view of C₆₀ solely based on empirical studies, based on the electronic properties of C₆₀ that vary considerably with their size and reaction path. A further example of this is the absorption of divalent zinc ions, which shows an increase in reactivity of the C₆₀ that presents an important pattern of chemical state, reactivity and toxicological potential. The results evaluate the toxicological potential of C₆₀ from a different angle than conventional, by applying a blend of critical review of the findings on C₆₀ toxicity, their chemical and electronic properties.     

Bioaccumulation of organochlorine pollutants in the fish community in Lake Årungen,Norway

Organochlorine pollutants in the major fish species (pike Esox lucius, perch Perca fluviatilis, and roach Rutilus rutilus) of Lake Årungen, Norway, were investigated after an extensive removal of large pike in 2004. The organochlorine pollutants detected in fish liver samples in 2005 were dichlorodiphenyltrichloroethane (DDTs), polychlorinated biphenyls (PCBs), hexachlorobenzene (HCB), and heptachlor epoxide (HCE). DDTs were the dominant among all analyzed OCs. ΣPCB and HCB, detected in fish from two clearly distinct trophic levels (prey and predators), give an indication of biomagnification. All OC concentrations in female pike were significantly lower compared to males, which might be due to the removal of high concentrations of pollutants in roe during spawning.     

Greenhouse gas emissions from home composting of organic household waste

The emission of greenhouse gases (GHGs) is a potential environmental disadvantage of home composting. Because of a lack of reliable GHG emission data, a comprehensive experimental home composting system was set up. The system consisted of six composting units, and a static flux chamber method was used to measure and quantify the GHG emissions for one year composting of organic household waste (OHW). The average OHW input in the six composting units was 2.6–3.5 kg week^?1 and the temperature inside the composting units was in all cases only a few degrees (2–10 °C) higher than the ambient temperature. The emissions of methane (CH₄) and nitrous oxide (N₂O) were quantified as 0.4–4.2 kg CH₄ Mg^?1 input wet waste (ww) and 0.30–0.55 kg N₂O Mg^?1 ww, depending on the mixing frequency. This corresponds to emission factors (EFs) (including only CH₄ and N₂O emissions) of 100–239 kg CO₂-eq. Mg^?1 ww. Composting units exposed to weekly mixing had the highest EFs, whereas the units with no mixing during the entire year had the lowest emissions. In addition to the higher emission from the frequently mixed units, there was also an instant release of CH₄ during mixing which was estimated to 8–12% of the total CH₄ emissions. Experiments with higher loads of OHW (up to 20 kg every fortnight) entailed a higher emission and significantly increased overall EFs (in kg substance per Mg^?1 ww). However, the temperature development did not change significantly. The GHG emissions (in kg CO₂-eq. Mg^?1 ww) from home composting of OHW were found to be in the same order of magnitude as for centralised composting plants.     

Eelgrass fairy rings: sulfide as inhibiting agent

Distinct ‘fairy rings’ consisting of narrow fringes of eelgrass (Zostera marina L.) expand radially over a bottom of chalk plates outside the calcium carbonate cliffs of the island of Møn, Denmark. We conducted a survey to evaluate possible explanations for the formation of the rings and, more specifically, for the apparent die-off of eelgrass shoots on the inner side of the rings. The fairy rings were up to 15 m in diameter consisting of 0.3- to 1-m-wide zones of sea grass shoots at densities of up to 1,200 shoots m^?2 and rooted in an up to 10-cm-thick sediment layer. On the outer side, shoots expanded over the bare chalk plates. On the inner side, shoots were smaller, had lower absolute and specific leaf growth, shoot density was lower and the sediment eroded leaving the bare chalk with scattered boulders behind. Sediment organic matter and nutrients and tissue nutrient contents were not different among positions. Sediment pools of acid volatile sulfides and chromium-reducible sulfur increased from outer to the middle positions of the rings, and so did total sulfur content of eelgrass tissues, while tissue δ³⁴S isotope ratios, regardless of position in the fringes, were low reflecting substantial invasion of sulfide from the sediment. Neither the clonal growth pattern of eelgrass, sediment burial of shoots, hydrodynamic forcing nor nutrient limitation could explain the ring-shaped pattern. We conclude that the most likely explanation must be found in invasion of eelgrass shoots by toxic sulfide accumulating in the sediment due to low iron availability in the carbonate-rich environment.     

Public perceptions of planning objectives for regional level management of wild reindeer in Norway

We examined community perceptions of preferred objectives for wild reindeer management in Southern Norway as the former population-based model is being replaced with an area-based, multi-level regional management model spanning large mountain regions. Communally oriented objectives are favoured over economic benefits to landowners. Environmental attitudes discriminate on many of the issues and can be useful factors in sorting out levels of support for proposed management actions and compromises in land use decisions. The regional reindeer plans create a new political context for land use management across large mountain areas which will require better cooperation among municipalities.     

Farm management indicators and farm typologies as a basis for assessments in a changing policy environment

This paper focuses on the assessment of farm management indicators and argues that typologies are a necessary tool for comprehensive environmental assessments. In the paper Andersen et al., [(2004a). Farming and the Environment in the European Community--using agricultural statistics to provide farm management indicators. Paper presented at OECD Expert meeting, March 2004, New Zealand. < http:webdomino1.oecd.org/comnet/agr/farmind.nsf/viewHtml/index/$FILE/Anderson_et_al.PDF> (1st of February 2006).] presented at the OECD expert meeting on farm management indicators in New Zealand in March 2004, a set of farm management indicators was presented in the framework of a typology of grazing livestock farming systems in the EU-15 (includes all Member States of the European Union before 2004). The present paper presents new results on farm management indicators within the framework of an extended typology for all farming sectors. It presents an environmentally oriented extension to the EU typology of farms currently used for assessing the situation of farming within the European Union. The extended typology is tested in relation to emerging policy issues such as environmental sustainability and rural viability by analysing some of the farm management indicators suggested in Andersen et al., [(2004a). Farming and the Environment in the European Community--using agricultural statistics to provide farm management indicators. Paper presented at OECD Expert meeting, March 2004, New Zealand. (1st of February 2006).]. Finally, recommendations in relation to the next generation EU farm typology are given.     

The prevention of occupational injuries in two industrial plants using an incident reporting scheme

INTRODUCTION: The aim of this study was to examine whether the introduction of an incident reporting scheme with feedback in two industrial plants had an effect on the number of major incidents. METHOD: An intervention design with measurements before the implementation of the incident reporting scheme and two years later was used to examine the relationship between incident rates, safety climate, the willingness to report incidents and perceived management commitment to safety. RESULTS: The results showed that a successful implementation of an incident reporting scheme was followed by a decline in the incidence of major incidents at a Danish metal plant. A key factor in implementing the scheme was top management commitment, which was lacking at another plant, where the implementation of a similar scheme failed. CONCLUSION: Although the study shows some encouraging results concerning the use of incident reporting schemes to prevent occupational accidents, the possibility to draw causal conclusions is limited in the present study, and further studies are needed before the effectiveness of such schemes can be evaluated with certainty.     

Correlation of cadmium distribution coefficients to soil characteristics

Cadmium (Cd) distribution between the soil solid phase and the soil solution is a key issue in assessing the environmental effect of Cd in the terrestrial environmental. Previous studies have shown that many individual minerals and other components found in soils can bind Cd, but most studies on whole soil samples have shown that pH is the main parameter controlling the distribution. To identify further the components that are important for Cd binding in soil we measured Cd distribution coefficients (Kd) at two fixed pH values and at low Cd loadings for 49 soils sampled in Denmark. The Kd values for Cd ranged from 5 to 3000 L kg(-1). The soils were described pedologically and characterized in detail (22 parameters) including determination of contents of the various minerals in the clay fraction. Correlating parameters were grouped and step-wise regression analysis revealed that the organic carbon content was a significant variable at both pH values. Cation exchange capacity (CEC) and gibbsite were important at the low pH (5.3) while iron oxides also were important at the high pH (6.7). None of the other clay minerals present in the soils (illite, smectite, kaolinite, hydroxy interlayered clay minerals [HIM], chlorite, quartz, microcline, plagioclase) were significant in explaining the Cd distribution coefficient.     

Life around the North Water ecosystem: Natural and social drivers of change over a millennium

The formation of the North Water in Smith Sound about 4500 years ago, as evidenced by the establishment of bird colonies and human presence, also initiated a long-term anthropogenic agent as part of this High Arctic ecosystem. Different epochs have influenced the human occupation in the area: immigration pulses from Canada and Alaska, trade with meteorite iron throughout the Arctic, introduction of new technologies by whalers and explorers, exploitation of resources by foreigners, political sequestration, export of fox and seal skins and later narwhal products, and recently fishing. Physical drivers in terms of weather and climate affecting the northern hemisphere also impact accessibility and productivity of the ecosystem, with cascading effects on social drivers, again acting back on the natural ecologies. Despite its apparent isolation, the ecosystem had and still has wide ranging spatial ramifications that extend beyond the High Arctic, and include human activity. The challenge is to determine what is internal and what is external to an ecosystem.     

Treatment of Arctic wastewater by chemical coagulation,UV and peracetic acid disinfection

Conventional wastewater treatment is challenging in the Arctic region due to the cold climate and scattered population. Thus, no wastewater treatment plant exists in Greenland, and raw wastewater is discharged directly to nearby waterbodies without treatment. We investigated the efficiency of physicochemical wastewater treatment, in Kangerlussuaq, Greenland. Raw wastewater from Kangerlussuaq was treated by chemical coagulation and UV disinfection. By applying 7.5 mg Al/L polyaluminium chloride (PAX XL100), 73% of turbidity and 28% phosphate was removed from raw wastewater. E. coli and Enterococcus were removed by 4 and 2.5 log, respectively, when UV irradiation of 0.70 kWh/m³ was applied to coagulated wastewater. Furthermore, coagulated raw wastewater in Denmark, which has a chemical quality similar to Greenlandic wastewater, was disinfected by peracetic acid or UV irradiation. Removal of heterotrophic bacteria by applying 6 and 12 mg/L peracetic acid was 2.8 and 3.1 log, respectively. Similarly, removal of heterotrophic bacteria by applying 0.21 and 2.10 kWh/m³ for UV irradiation was 2.1 and greater than 4 log, respectively. Physicochemical treatment of raw wastewater followed by UV irradiation and/or peracetic acid disinfection showed the potential for treatment of arctic wastewater.