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91.
92.
Ludwig Weißflog Wolfgang Rolle Klaus-Dieter Wenzel Ralph Kühne Gerrit Schüürmann 《Environmental Sciences Europe》1994,6(3):135-138
The deposition of heavy metals bound to air dust and their ecological effects depend, to a large degree, on particle size, which influences the transport processes in the environment. To estimate the size range of the particles mainly taken up by the pine needles, concentration gradients along a sector leeward of Leipzig were modelled according toGauss plume calculations. The results show that the aerodynamic size is between 1 and 10 μm. Particles of this size range can be taken up by lungs and, thus, have a particular toxicological relevance. 相似文献
93.
Tobias Frische Jan Ahlers Andreas Gies Carola Kussatz Christoph Schulte Hans -Christian Stolzenberg 《Environmental Sciences Europe》2007,19(1):49-61
This contribution highlights the role and importance of ecotoxicology in regulatory decisions of chemicals legislation focussing on the responsibilities of the German Federal Environmental Agency (UBA). Therefore, organisational structures and processes relevant for making decisions concerning the risks of chemicals to men and the environment are described. As any regulatory decision starts with scientific findings, a brief overview of UBA’s activities with regard to own research and to initiate research in the area of ecotoxicology is provided. In addition, the vast importance of standardisation and international harmonisation of guidelines for testing and assessment of chemicals is illustrated, including the time- and ressource consuming character of these harmonisation processes. Subsequently, the involvement of regulatory decision making in intense and controversial scientific and political debates is emphasised. The transparency of these discussions and the independence of science is critically addressed in this context. In a final chapter the job requirements and options for qualification in Germany are described, ending up with a brief summary of the positive experiences with UBA’s contribution to the new advanced training course in ecotoxiciology realised by GDCh/SETAC GLB. A summary of the discussions on these different topics emphasises the specific challenge in regulatory ecotoxicology: To generate knowledge relevant for decision making, while acting in an area of conflict between scientific demands and economical as well as political interests. 相似文献
94.
Goal and Scope
The constant increase of traffic and the rising energy and material consumption both in industry and trade as well as in private households mean a constant challenge to environmental protection and to the air pollution control. With the commencement of the Federal ambient pollution control act in April 1974, the legal basis for the monitoring of air pollution was created. In future, the limit values laid down in the Council Directive 1999/30/EG, 2000/69/EG and 96/62/EG, will be valid. In town and regional planning there is a great demand for a simple index to evaluate the air quality. From the available data of PM10, NO2, O3, CO, SO2, trends of the air quality will be derived.Methods
The indices LQI and TLQ suggested by Mayer et al. (2002) were calculated for selected stations of the air pollution monitoring network (ZIMEN) in Rhineland-Palatine. All analysis are based on hourly recorded value, Mean values and frequency distributions are used for the interpretation. Furthermore, the characteristics and trends of the indices under different weather conditions were examined and discussed.Results
The examination figures out that the air pollutions indices at all stations show similar patterns in the period between January 2001 and December 2002. Neither the LQI, nor the TLQ shows an annual variation. Existing variations are mainly controlled by the general weather situation and the air temperature. High values of the indices appear at extremely high or low mean daily air temperature. The absolute value of the air pollution index is determined by local pollution factors.Outlook and Recommendations
Both indices are well suitable to evaluate the air quality and to assess the effects of state-aided measures for air pollutant control. Therefore, the indices TLQ and LQI should be published as an additional information in the world wide web. 相似文献95.
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99.
Cadmium poses a major environmental and human health threat because of its constant release through anthropogenic activities. A need, therefore, exists for cost-effective remediation procedures. Phytoremediation, the use of plants to extract contaminants from soils and groundwater, has revealed great potential. However, it is limited by the fact that plants need time, nutrient supply and, moreover, have a limited metal uptake capacity. Synthetic chelators have shown positive effects in enhancing heavy metal extraction through phytoremediation, but they have also revealed a vast number of negative side-effects. The objective of this research was to investigate the use of humic acids as an alternative to synthetic chelators. Humic acids were applied to a cadmium-contaminated soil at various dosages, and the uptake of cadmium into Nicotiana tabacum SR-1 was determined in relation to the amounts of total and bioavailable cadmium in the soil. It was found that the theoretical bioavailability of cadmium, as determined by diethylenetriaminepentaacetic acid (DTPA) extraction, did not change, but its plant uptake was enhanced significantly, in some cases up to 65%. Humic acids added at a rate of 2 g kg(-1) soil increased the cadmium concentration in the shoots from 30.9 to 39.9 mg kg(-1). A possible reason for this enhancement is the decrease in pH, resulting in higher cadmium availability. Another possibility taken into account is that plants may take up cadmium complexes with humic acid fragments, which result from microbiological degradation or, self-dissociation. 相似文献
100.
Saito K Sjödin A Sandau CD Davis MD Nakazawa H Matsuki Y Patterson DG 《Chemosphere》2004,57(5):373-381
A new analytical method has been developed for the quantification of 59 different persistent organohalogen compounds, such as polybrominated diphenyl ethers (PBDEs), polychlorinated naphthalenes (PCNs), polychlorinated biphenyls (PCBs), PCB metabolites, organochlorine pesticides (OCPs) in biological organ tissues. The optimum extraction and cleanup procedures were examined using accelerated solvent extraction (ASE), automated gel permeation chromatography (GPC) on Biobeads S-X3 and automated solid phase extraction (SPE) on silica-gel. The target compounds were divided into two fractions, non-polar compounds and more polar compounds, which in the latter fraction was subsequently methylated using diazomethane. Detection can be achieved by GC/MS in negative chemical ionization (NCI) mode. The average recoveries of the compounds spiked in swine liver, heart, kidney, and cattle adipose tissues were considered satisfactory, and it was confirmed that the method could be used in routine analysis. 相似文献