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111.
Andreas Musolff Sebastian Leschik Monika Mder Gerhard Strauch Frido Reinstorf Mario Schirmer 《Environmental pollution (Barking, Essex : 1987)》2009,157(11):3069-3077
Based on a monitoring program over the course of a year, we characterize the temporal and spatial distribution of selected micropollutants in an urban watershed within the city of Leipzig, Germany. Micropollutants revealed a ubiquitous presence in untreated and treated wastewater, surface water and groundwater. The loads of 4-nonylphenol in the effluents of the municipal wastewater treatment plant followed a seasonal trend, whereas the loads of all other micropollutants were highly variable and not correlated to seasons. In the surface water, load seasonality of caffeine, galaxolide and tonalide resulted from a rapid removal with increased water temperature. The loads of 4-nonylphenol and of caffeine in the colder months increased when rainfall occurred. In the groundwater, complex spatial and temporal patterns were apparent and were related to varying input, retardation and removal processes. As a consequence, an assessment of micropollutants in urban waters should consider different micropollutants' temporal and spatial variability. 相似文献
112.
Zheng Li Erin N. Porter Andreas Sjödin Larry L. Needham Sangil Lee Armistead G. Russell James A. Mulholland 《Atmospheric environment (Oxford, England : 1994)》2009,43(27):4187-4193
Twenty-eight polycyclic aromatic hydrocarbons (PAH) and methylated PAHs (Me-PAH) were measured in daily PM2.5 samples collected at an urban site, a suburban site, and a rural site in and near Atlanta during 2004 (5 samples/month/site). The suburban site, located near a major highway, had higher PM2.5-bound PAH concentrations than did the urban site, and the rural site had the lowest PAH levels. Monthly variations are described for concentrations of total PAHs (∑PAHs) and individual PAHs. PAH concentrations were much higher in cold months than in warm months, with average monthly ∑PAH concentrations at the urban and suburban-highway monitoring sites ranging from 2.12 to 6.85 ng m?3 during January–February and November–December 2004, compared to 0.38–0.98 ng m?3 during May–September 2004. ∑PAH concentrations were found to be well correlated with PM2.5 and organic carbon (OC) within seasons, and the fractions of PAHs in PM2.5 and OC were higher in winter than in summer. Methyl phenanthrenes were present at higher levels than their un-substituted homologue (phenanthrene), suggesting a petrogenic (unburned petroleum products) input. Retene, a proposed tracer for biomass burning, peaked in March, the month with the highest acreage and frequency of prescribed burning and unplanned fires, and in December, during the high residential wood-burning season, indicating that retene might be a good marker for burning of all biomass materials. In contrast, potassium peaked only in December, indicating that it might be a more specific tracer for wood-burning. 相似文献
113.
An indispensable asset at risk: merits and needs of chemicals-related environmental sciences 总被引:1,自引:1,他引:0
114.
Mechanistic effect models for ecological risk assessment of chemicals (MEMoRisk)—a new SETAC-Europe Advisory Group 总被引:1,自引:1,他引:0
115.
Heinz Rüdel Winfried Schröder Karl Theo von der Trenck Gerhard Andreas Wiesmüller 《Environmental science and pollution research international》2009,16(5):486-498
Background Due to the requirements of the EU Water Framework Directive and other legal regulations (e.g., national laws like the German
Federal Soil Protection Act), but also due to the implementation of the new EU chemicals management system REACH, environmental
monitoring will gain increasing importance for the surveillance of environmental quality as well as for the assessment of
chemicals. Against this background, the Work Group on ‘Environmental Monitoring’ of the Division of ‘Environmental Chemistry
and Ecotoxicology’ within the German Chemical Society has compiled a position paper on substance-related environmental monitoring.
Scope Core elements of this position paper are the definitions of important terms like monitoring, exposure monitoring, effect monitoring,
and integrated monitoring. Moreover, temporal and spatial aspects (monitoring of spatial distributions, trend monitoring,
and retrospective monitoring) and their applications are discussed. The main focus of this position paper is the coverage
of aspects which have to be observed for the preparation and implementation of a monitoring program. Essential is the clear
specification of the targets of the monitoring which determine the development of the monitoring concept and its realization,
e.g., if environmental media (compartments) or organisms are most appropriate as samples for the aim of the study. Of course,
also the properties of the target substances are important (e.g., lipophilicity/bioaccumulation as pre-requisite for an exposure
monitoring with organisms). Finally, the monitoring phases of sample planning, sampling, storage and transport of samples,
selection of analytical methods, quality assurance measures as well as reporting are discussed.
Perspectives An important issue for the future is to link the quantification of chemicals in environmental compartments (exposure and pollution
monitoring) more closely to the study of biological effects (effect monitoring) than has been the case up to now. Furthermore,
by inclusion of a spatial differentiation, a comprehensive evaluation of the state of an ecosystem can be obtained and the
relevance of the results improved. Practical examples of monitoring studies which illustrate various aspects covered in this
position paper will be presented in a series of publications by members of the Work Group in the following issues of this
journal.
相似文献
Gerhard Andreas WiesmüllerEmail: |
116.
117.
Claudia Pahl-Wostl Christoph Schlumpf Martin Büssenschütt Andreas Schönborn Jan Burse 《Integrated Assessment》2000,1(4):267-280
Within the CLEAR project a new approach to integrated assessment modelling has been developed for the participatory integrated
assessment of regional climate change involving citizens' focus groups. The climate change decision problem was structured
by focusing separately on climate impacts and mitigation options. The attempt was made to link the different scales of the
problem from the individual to the global level. The abstract topic of climate change was related to options on the level
of a citizen's individual lifestyle. The option of a low energy society was emphasised in order to embed the climate change
decision problem in a wider range of societal concerns. Special emphasis was given to the characterisation and communication
of uncertainties. The chosen approach allows different kinds of uncertainties in one framework to be addressed. The paper
concludes with a summary of the experience made, and recommendations for the use of models in participatory integrated assessments.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
118.
Past changes and possible future variations in the nature of extreme precipitation and flood events in Central Europe and
the Alpine region are examined from a physical standpoint. An overview is given of the following key contributory physical
processes: (1) the variability of the large-scale atmospheric flow and the associated changes of the North-Atlantic storm
track; (2) the feedback process between climate warming and the water cycle, and in particular the potential for more frequent
heavy precipitation events; and (3) the catchment-scale hydrological processes associated with variations in major river flooding
events and that are related to land-use changes, river training measures, and shifts in the proportion of rain to snowfall.
In this context an account is provided of the possible future forecasting and warning methodologies based upon high-resolution
weather prediction and runoff models. Also consideration is given to the detectability of past (future) changes in observed
(modeled) extreme events. It is shown that their rarity and natural fluctuation largely impedes a detection of systematic
variations. These effects restrict trend analysis of such events to return periods of below a few months. An illustration
using daily precipitation from the Swiss Alps does yield evidence for pronounced trends of intense precipitation events (return
period 30 days), while trends of stronger event classes are not detectable (but nevertheless can not be excluded). The small
detection probability for extreme events limits possible mitigation of future damage costs through an abatement of climate
change alone, and points to the desirability of developing improved early forecasting/warning systems as an additional no-regret
strategy.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
119.
Skyllberg U Drott A Lambertsson L Björn E Karlsson T Johnson T Heinemo SA Holmström H 《Ambio》2007,36(6):437-442
Sediments contaminated by various sources of mercury (Hg) were studied at 8 sites in Sweden covering wide ranges of climate, salinity, and sediment types. At all sites, biota (plankton, sediment living organisms, and fish) showed enhanced concentrations of Hg relative to corresponding organisms at nearby reference sites. The key process determining the risk at these sites is the net transformation of inorganic Hg to the highly toxic and bioavailable methylmercury (MeHg). Accordingly, Hg concentrations in Perca fluviatilis were more strongly correlated to MeHg (p < 0.05) than to inorganic Hg concentrations in the sediments. At all sites, except one, concentrations of inorganic Hg (2-55 microg g(-1)) in sediments were significantly, positively correlated to the concentration of MeHg (4-90 ng g(-1)). The MeHg/Hg ratio (which is assumed to reflect the net production of MeHg normalized to the Hg concentration) varied widely among sites. The highest MeHg/Hg ratios were encountered in loose-fiber sediments situated in southern freshwaters, and the lowest ratios were found in brackish-water sediments and firm, minerogenic sediments at the northernmost freshwater site. This pattern may be explained by an increased MeHg production by methylating bacteria with increasing temperature, availability of energy-rich organic matter (which is correlated with primary production), and availability of neutral Hg sulfides in the sediment pore waters. These factors therefore need to be considered when the risk associated with Hg-contaminated sediments is assessed. 相似文献
120.
This work has examined cobalt(II) binding by a variety of solid humic acids (HAs) isolated from peat, plant and soil sources at temperatures down to 60K. The results confirm that X-ray absorption near-edge spectroscopy (XANES) measurements cannot distinguish between aquo and carboxylato ligands in the inner coordination sphere of Co(II). However, between 1 and 2 inner-sphere carboxylato ligands can be detected in all the peat, plant and soil-derived HA samples by extended X-ray absorption fine structure (EXAFS) measurements, indicating inner-sphere coordination of HA-bound Co(II). The precision of C(carboxylate) detection is limited by the extent and quality of the data and the contribution from inner-sphere O to the Fourier transformed peaks used to detect carbon. Putative chelate ring formation is consistent with a relatively negative entropy change in step A, the stronger Co(II) binding step by HA functional groups, and could relate to 'non-exchangeable' metal binding by HSs. 相似文献