Production of fire extinguishing mixture by solid propellant propulsion

The behavior of fire suppression by water mist spray has been studied by using the experimental setup which employs the double-based solid propellant gas generator for water mist production. The burning products of solid fuel form a supersonic flow injected through the nozzle into the diffuser chamber having input for the water component ejected from the storage. High values of temperature and pressure at stagnation point impart the substantial kinetic energy to the flow, which provides the atomization of water droplets into mist spray. Since the water evaporation occurs already in the diffuser chamber due to the high temperature of input gas flow, the droplet size is gradually decreases to the lower limit value that could ever exist. The presence of vapor phase enlarges the volume of fire extinguishing jet allowing it to operate as a flooding agent (along with the effect of heat consumption due to water evaporation) at the very beginning of fire suppression process, much before the water droplets evaporation by the flame itself. Proposed technique of the water mist production has showed noticeable fire suppression capability through the series of testing application to the gasoline and wood model fire sources.     

Free Energy Reduction by Molecular Interface Crossing: Novel Mechanism for the Transport of Material Across the Interface of Nanoscale Droplets Induced by Competing Intermolecular Forces for Application in Perfluorocarbon Blood Substitutes

 Perfluorocarbons (PFCs) are inert liquids which can dissolve – and release – approximately 50 times more oxygen than blood plasma. Oxygen carriers based on PFCs are easy to produce, free of biological components, and more rigorously sterilizable than blood. PFCs injected into the body are eliminated by expiration through the lungs. Before reaching the lungs, PFCs accumulate in storage organs such as liver and spleen. In these organs nanoscale PFC droplets reduce their free energy by unifying to microscopic drops, thus indirectly lowering the rate of their expiration. The model of free energy reduction by molecular interface crossing (FERMIC), a novel emulsion breaking mechanism derived from first principles as presented here, leads to a better understanding of the structure formation processes relevant in perfluorocarbons (PFCs) in vivo. Received: 11 November 1998 / Accepted in revised form: 18 February 1999     

Effects of arbuscular mycorrhizal fungi on Agrostis capillaris grown on amended mine tailing substrate at pot,lysimeter, and field plot scales

Applied research programs in the remediation of contaminated areas can be used also for gaining insights in the physiological and ecological mechanisms supporting the resistance of plant communities in stress conditions due to toxic elements. The research hypothesis of this study was that in the heavily contaminated but nutrient-poor substrate of mine tailing dams, the beneficial effect of inoculation with arbuscular mychorrizal fungi (AMF) is due to an improvement of phosphorus nutrition rather than to a reduction of toxic element transfer to plants. A concept model assuming a causal chain from root colonization to element uptake, oxidative stress variables, and overall plant development was used. The methodological novelty lies in coupling in a single research program experiments conducted at three scales: pot, lysimeter, and field plot, with different ages of plants at the sampling moment (six subsets of samples in all). The inoculation with AMF in expanded clay carrier had a beneficial effect on the development of plants in the amended tailing substrate heavily contaminated with toxic elements. The effect of inoculation was stronger when the quantity of expanded carrier was smaller (1 % vs. 7 % inoculum), probably because of changes in substrate features. The improvement of plant growth was due mainly to an improvement in phosphorus nutrition leading to an increase of protein concentration and decrease of oxidative stress enzyme activity (superoxide dismutase and peroxidase). In a single data subset, an effect of inoculation on the uptake of several toxic elements could be proved (decrease of As concentration in plant roots correlated with a decrease of oxidative stress independent from the effect of P concentration increase). The multi-scale approach allowed us to find differences between the patterns characterising the data subsets. These subset-specific patterns point out the existence of physiological differences between plants in different development states (as a result of sampling at different plant ages). From an applied perspective, conclusions are drawn with respect to the use of plants in the monitoring programs of contaminated areas and the use of inoculation with AMF in the remediation of tailing dams.     

Nanobioaerosols--reconsidering agricultural irrigation in a warming world

Nanobacteria are best described as 60-300 nm nanovesicles. In the body they collect calcium and phosphate to form apatite, adhere to cells, or invade them--processes regulated by a slime based on proteins (primordial proteins). A versatile functionality realized with a minimum of properties equips nanobacteria with a unique survival potential. They were identified in humans, animals, wastewater and the stratosphere. In South Africa they were detected in people infected with HIV. Models indicate that they boost the genetic diversity of the HIV-1 virus. Experiments showed that they are excreted via urine, explaining their presence in the environment. Eradication would be virtually impossible if they had an extraterrestrial origin, implying a permanent bombardment from space. Whereas the biological status of nanobacteria is still not clarified, we postulate here that the native habitat of nanobacteria are mammals, suggesting that at least modern species have their origin on Earth. The thesis results from mapping functions and properties of the slime, and could facilitate the localisation of nanobacterial reservoirs, identification of local distribution routes and tracking of global transport cycles. Agricultural irrigation with water containing excreta from humans infected with nanobacteria could be a central disseminator of the nanobioaerosols.     

Prioritization of coastal properties for conservation in New York State

Conservation of coastal lands reduces non-point source pollution loads into oceans and estuaries, retains natural areas and saves ecological communities from disappearance and change. A recent agreement for protection of Long Island Sound waters in New York and Connecticut established 30 environmental and management goals. One of them is establishment of a listing of existing undeveloped properties and their prioritization for natural resource conservation and outdoor recreation. The optimal prioritization approach poses strong constraints and methodological challenges on selection of data for analysis, assignment of a priority score to each property unit and the assessment of this assignment. To be a practical tool, the prioritization model should be reproducible and include a mechanism for evaluation of obtained prioritization scenarios. Presented study uses Geographic Information System (GIS) to assign conservation priority scores to unprotected and undeveloped parcels greater than five acres in size within New York’s Long Island Sound coastal area. The method combines spatial multi-criteria analysis and statistical methods. The results of this project include identification and prioritization of more than 700 undeveloped properties on New York coast. The most important finding of GIS analysis was the discovery of clusters of vacant parcels that together form large areas available for future conservation. These results offer new conservation tools and strategies to coastal managers and government in New York State.     

Considering Climate Change in the Estimation of Long‐Term Flood Risks of Devils Lake in North Dakota

Terminal lakes are impacted by regional changes in climate. Devils Lake (DL), North Dakota, United States (U.S.), is a case in which a prolonged shift in the precipitation pattern resulted in a 10‐m water‐level rise over the past two decades, which cost over one billion U.S. dollars in mitigation. Currently, DL is 1.5 m from an uncontrolled overspill to the nearby Sheyenne River, which could lead to unprecedented environmental, social, and economic costs. Water outlets recently implemented in the lake to slow the water‐level rise and prevent an uncontrolled overspill are subject to significant concerns over the introduction of invasive species and downstream water quality. We developed a hydrological model of the DL basin using the soil and water assessment tool and analyzed DL's overspill probability using an ensemble of statistically downscaled General Circulation Model (GCM) projections of the future climate. The results indicate a significant likelihood (7.3‐20.0%) of overspill in the next few decades in the absence of outlets; some members of the GCM integration ensemble suggest an exceedance probability of over 85.0 and 95.0% for the 2020s and 2050s, respectively. Full‐capacity outlets radically reduce the probability of DL overspill and are able to partially mitigate the problem by decreasing the average lake level by approximately 1.9 and 1.5 m in the 2020s and 2050s, respectively.     

The effect of humic substances on Cu migration in the soil profile

Humic substances (HS) are widely used for diverse purposes. The effect of HS on the metal’s status in contaminated soils is contradictory. The aim of this work was to investigate the Cu migration in soils treated with HS. A model field experiment with the addition of Cu (1.243?mg?Cu/kg) and HS Extra® (potassium humate) was performed. The Cu addition resulted in acidification (by 0.7 pH) after 3 months. The major part of the added Cu remained in the upper 7-cm-thick soil layer; 4% reached the lower soil layer, while only 0.1% were removed beyond the profile. The addition of HS mitigated soil acidification increased the content of Cu bound to solid-phase organic substances and abruptly reduced the Cu activity in the soil liquid phase. Simultaneously, the HS addition increased the water-soluble organic substances (WSOS) by four times, including those in the hydrophilic and hydrophobic fractions, resulting in a twofold increase in the content of soluble Cu. Copper complexes with hydrophilic WSOS mainly reached lysimeters, and hydrophobic organic substances were absorbed by the soil. The HS addition to a slightly acidic soil can accelerate the migration of Cu to adjacent environments.     

Chemical,biological, and ecotoxicological assessment of pesticides and persistent organic pollutants in the Bahlui River,Romania

Background, aim, and scope

Current knowledge on environmental impacts of industrial activities in Romania, particularly persistent organic pollutants (POPs), indicates that environmental standards of the European Union are not systematically met. In our study area, additional sources of POPs are agriculture and domestic wastes. Very scarce information is available upon environmental contaminations and effects. In the present study, we investigated the chemical pollution and their eventual impact on the ecosystem by measuring POPs and by using biological indicators of pollution.

Materials and methods

The survey was carried out at six main sample sites along the Bahlui River. Sediments were chemically analysed for their content in polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs)—hexachlorocyclohexanes (HCHs) isomers and the dichlorodiphenyl trichloroethane (DDT) family. River water was biologically monitored at the level of phytoplankton and benthic invertebrates’ communities. Water samples from six locations have been analyzed for algal species composition and correspondence to various water quality indices. Biological samples have been taken from the same locations so as to calculate the macroinvertebrate indices. In the most polluted areas, as revealed by previous methods, toxicity was tested by exposing the green alga Pseudokirchneriella subcapitata and the cladoceran Daphnia magna to various dilutions of water sample.

Results

Important concentrations of POPs were identified only in sediments at river mouths (sites S5 and S6). Along the year, the sum of PCB concentrations ranged between 3 and 10 ng/g dw (S5), and between 4 and 26 ng/g dw (S6). Concentration of HCHs ranged between 0.4 and 3 ng/g dw (both S5 and S6) with a higher contribution of the gamma-HCH (30–70%), followed by beta-HCH (20–50%). The beta-HCH isomer was found at lower concentrations or even not detected in outer city sites. DDTs were found at higher concentrations than HCHs and ranged between 0.18 and 4 ng/g dw (S5) and between 0.56 and 18 ng/g dw (S6). The parent compound, p,p′-DDT, could be detected only in low concentrations (up to 5 ng/g dw) and contributed with less than 30% to the sum of DDTs in sediment. The principal contributors of the ΣDDTs in sediment were p,p′-DDE, and p,p′-DDD. The o,p′-DDD and DDT isomers were minor contributors to the sum of DDT. PAHs were found at higher concentrations than DDTs and ranged between 6 and 36 ng/g dw (S5) and between 36 and 155 ng/g dw (S6). Fluoranthene was predominant (up to 40%), followed by phenantrene (up to 30%), naphthalene (up to 35%), and benzo-(g,h,i)-perylene (up to 23%). The saprobity index and the diatom index increased from springs to river mouth, indicating a decrease in the water quality, but within the limits of moderate pollution. The saprobity index varied between 1.99 at spring to 2.70 at mouth. The diatom index varied from 3.48 to 3.14. The species’ richness in phytoplankton has a less clear pattern along the river, but in general, it appears to be negatively influenced by pollution. At the level of biological consumer species, the analyses of the macroinvertebrates confirm the situation and the tendency shown with algae. In addition, the Shannon–Wiener index, the Pielou evenness index, and the McNaughton dominance index indicate a peculiar pattern: invertebrate communities appear to a have a more stable structure along the river, with visible shifts at springs and at river mouths. Water toxicity testing indicates low toxicity of river waters around the city of Iasi, with two notable exceptions: the point pollution at the domestic wastewater treatment discharge and at the old open-air deposit of domestic solid wastes. Another important result was that tested algae appeared to be more readily affected than tested cladoceran: EC₅₀ (percent effluent) was 16 in algae and 28 in cladocerans. The slope of toxic effect was also much steeper in cladocerans (6) than in algae (1.8), which means that the toxic effect is more sudden on the tested invertebrates than on the tested algae.

Discussion

Pollutant concentrations reported herein are lower or similar than those reported for the sediments by earlier studies (RIZA 2000; Dragan et al., Int J Environ Anal Chem 86:833–842, 2006). Ratios of individual PAH compounds indicate important pyrolytic inputs and suggest that PAHs in the area are derived from the combustion of fossil fuels. Biologically, the waters appear to be beta-mesosaprobic towards alpha-mesosaprobic according to the saprobic index classification and undergo moderate pollution according to the diatom index classification. Water quality decreases from springs to river mouths. Algal species richness index has a less clear pattern along the river. Water toxicity is low, but certain sources of point pollution require increased attention.

Conclusions

The water quality is better than expected, probably because of the drop in pollution intensity following the collapse of local agricultural and industrial activity following the fall of communism in 1989. Nevertheless, further studies will be needed to confirm and refine our results. While this study draws no strident alarm, it appeals for high attention, particularly because the economic activity in the area is expected to increase.

Recommendations and perspectives

Future close monitoring will be necessary for insuring compliance with the Water Framework Directive, and for refining standards and understanding of the local situation, but with relevance for the wider international community. On the basis of the situation described in the present study, we recommend that future studies dedicate specific efforts to point pollution and effluent toxicity, particularly around the city of Iasi. For a better understanding of pollution and its effects, we recommend pursuing the type of multidisciplinary investigations proposed by the present study: chemical, ecotoxicological, and ecological. We also recommend that new methods should be developed and/or refined, like the empirical determination of partitioning coefficients in water and soils, process-based toxicity methods in ecotoxicological assessments, searching for interactions between pollution, producers, and consumers in aquatic ecosystems. We also recommend preference for cheaper survey methods, as these will be more applicable locally.

     

Bioprospecting at former mining sites across Europe: microbial and functional diversity in soils

The planetary importance of microbial function requires urgently that our knowledge and our exploitation ability is extended, therefore every occasion of bioprospecting is welcome. In this work, bioprospecting is presented from the perspective of the UMBRELLA project, whose main goal was to develop an integral approach for remediation of soil influenced by mining activity, by using microorganisms in association with plants. Accordingly, this work relies on the cultivable fraction of microbial biodiversity, native to six mining sites across Europe, different for geographical, climatic and geochemical characteristics but similar for suffering from chronic stress. The comparative analysis of the soil functional diversity, resulting from the metabolic profiling at community level (BIOLOG ECOPlates) and confirmed by the multivariate analysis, separates the six soils in two clusters, identifying soils characterised by low functional diversity and low metabolic activity. The microbial biodiversity falls into four major bacterial phyla: Actinobacteria, Proteobacteria, Firmicutes and Bacteroidetes, including a total of 47 genera and 99 species. In each soil, despite harsh conditions, metabolic capacity of nitrogen fixation and plant growth promotion were quite widespread, and most of the strains showed multiple resistances to heavy metals. At species-level, Shannon’s index (alpha diversity) and Sørensen's Similarity (beta diversity) indicates the sites are indeed diverse. Multivariate analysis of soil chemical factors and biodiversity identifies for each soil well-discriminating chemical factors and species, supporting the assumption that cultured biodiversity from the six mining sites presents, at phylum level, a convergence correlated to soil factors rather than to geographical factors while, at species level, reflects a remarkable local characterisation.