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701.
Anna Parus Małgorzata Gaj Bożena Karbowska Joanna Zembrzuska 《Chemistry and Ecology》2020,36(7):705-725
ABSTRACT Pharmaceutical compounds are considered emerging environmental pollutants that have a potential harmful impact on environment and human health. In this study, the spiky green horse-chestnut shell was used for the biosorption and removal of acetaminophen from aqueous solution. It was analysed how the parameters, like contact time, pH, mass of biosorbent and temperature, influence the effectiveness of acetaminophen removal from aqueous solutions. The equilibrium was quickly achieved after 10?min (~60%). The amount of acetaminophen adsorption slightly increased with the increase of the mass of biosorbent, and for example for an aqueous solution containing 10?mg/L of acetaminophen adsorption was increased from 62% to 81%. The promising results obtained at pH ranged between 2 and 9, which shows that the adsorption of acetaminophen did not depend on the pH and it may be a consequence of the predominant microporous sorbent and its surface charge. The result is better correlated to a pseudo-second-order kinetic model of type 2 (r 2?=?0.9992) than pseudo-first-order. A sorption mechanism of acetaminophen on biosorbent was also proposed. The sorption of acetaminophen over biosorbent is mainly preceded by hydrophilic interactions between hydroxyl and carbonyl groups in pharmaceutical molecules and hydroxyl and carboxyl groups on the surface of biosorbent. 相似文献
702.
Chiara Lombardi Silvia Cocito Anna Occhipinti-Ambrogi Keith Hiscock 《Marine Biology》2006,149(5):1103-1109
Zooid size variation and growth banding in the bryozoan Pentapora fascialis, collected from the South of Great Britain to the South of Italy, were investigated in order to test their relationship with the variation of seawater temperature. Zooid length appeared to be more sensitive than zooid area and width to temperature variation. The longest zooids were budded in localities that typically experience low seasonal variation in temperature (3.2–7.5°C) and low mean annual temperature (about 11°C). Zooid length demonstrated the strongest relationship with the range of seasonal variation in temperature rather than the mean annual temperature. Growth bands produced during colder months were less high than those produced during warmer months. Measurements of these alternating bands were used to calculate growth rate of the laminae, ranging from 20.7 at Plymouth to 29.3 mm year−1 at Tino Island. Significant differences in zooid length were found between the two bands, with longer zooids within the band developed in colder months and shorter zooids in bands produced in the warmer period. We conclude that zooid size can be used as an environmental proxy of the seasonal temperature regimes experienced by the species. 相似文献
703.
Maciej Manecki Anna Bogucka Tomasz Bajda Olaf Borkiewicz 《Environmental Chemistry Letters》2006,3(4):178-181
Bioavailability of Pb in contaminated soils can be highly decreased by conversion of labile Pb species into pyromorphite Pb5(PO4)3Cl, induced by amendment with a phosphate source. However, PO4
3− can be specifically adsorbed on goethite α-Fe(OH)3 present in soils. We demonstrate that despite the stability of phosphate ions adsorbed on goethite surface, the reaction between goethite-adsorbed phosphates and aqueous lead in the presence of Cl− results in crystallization of pyromorphite. Two morphological forms of pyromorphite formed on goethite were observed: 1) incrustations, indicating direct reaction of Pb and Cl ions with PO4
3− adsorbed on goethite surface, and 2) aggregates of pyromorphite crystals indicating that the reaction with PO4
3− ions took place in the volume of the solution. This suggests that precipitation of pyromorphite is faster than desorption of phosphates and that aqueous Pb may serve as a sink for phosphate ions by shifting the equilibrium and inducing PO4
3− desorption. 相似文献
704.
Anna Tiraa 《生态毒理学报》2002,24(3):42-47
塔基图穆保护区 1996年创建于库克群岛的拉罗汤加岛 , 其目标是为了当前和未来生产者的利 益而对生物多样性实施保护 . 只有当地人民对其土地和资源拥有所有权 . 生态旅游将成为该 保护区的主要经济活动 . 在土地所有者同意和支持下 , 一个有指导的 " 大自然漫步 " 已经组 织起来 . 相似文献
705.
Pilot study of sources of lead exposure in Moscow,Russia 总被引:11,自引:0,他引:11
Anna O. Orlova Desmond I. Bannon Mark R. Farfel Valerie M. Thomas Lev V. Aleschukin Valery V. Kudashov James P. Shines Georgy I. Kruchkov 《Environmental geochemistry and health》1995,17(4):200-210
This preliminary investigation of sources of lead exposure in Moscow, Russia, by Russian and US collaborators measured lead in paint, interior dust, and drinking water in seven day-care centres, and in petrol, soil and canned food. Some paint samples exceeded US regulatory standards for lead in paint on surfaces (0.5%). Dust lead loadings were < 1.7 g cm–2 and below the guidance levels of the US EPA. Drinking water lead concentrations were at or below the US drinking water standard of 15 g L–1. Lead concentrations in petrol from Moscow vehicles and petrol stations were consistent with a regulation banning the sale of leaded petrol within the Moscow City limits. Except for baby food, lead levels were higher in the Russian canned foods (range 6 to 1240 g kg–1, dry weight) compared to corresponding US canned foods, with ratios of Russian to US levels of up to 120:1 for evaporated milk. Lead concentrations in soil generally ranged from 500 to 2000 g g–1, levels that would trigger hazard reduction measures according to US EPA guidance. These findings, together with the use of lead in petrol outside Moscow, indicate multiple sources of lead exposure in Russia. Priorities for future research are discussed including the establishment of interlaboratory quality control programmes. 相似文献
706.
Biodegradation of 4-nonylphenol in seawater and sediment 总被引:15,自引:0,他引:15
Ekelund R Granmo A Magnusson K Berggren M Bergman A 《Environmental pollution (Barking, Essex : 1987)》1993,79(1):59-61
Biodegradation of 14C-labelled nonylphenol at the concentration 11 microg litre (-1) in seawater has been estimated by collection and quantification of the formed labelled carbon dioxide. Initially degradation was very slow but when the microorganisms had become adapted, after four weeks at 11 degrees C, the degradation rate increased rapidly and after 58 days about 50% of 14C from NP was found in the CO2 fraction. In the presence of sediment the initial degradation rate was high and did not increase after longer incubation. Lack of oxygen reduced the degradation rate by half in the presence of sediment. 相似文献
707.
Objective: Powered mobility devices (PMDs) are commonly used as aids for older people and people with disabilities, subgroups of vulnarable road users (VRUs) who are rarely noted in traffic safety contexts. However, the problem of accidents involving PMD drivers has been reported in many countries where these vehicles have become increasingly popular.The aim of this study is to extract and analyze national PMD-related accident and injury data reported to the Swedish Traffic Accident Data Acquisition (STRADA) database. The results will provide valuable insight into the risks and obstacles that PMD drivers are exposed to in the traffic environment and may contribute to improving the mobility of this group in the long term.Methods: The current study is based on data from 743 accidents and 998 persons. An analysis was performed on a subset of data (N?=?301) in order to investigate the development of accidents over a period of 10 years. Thereafter, each accident in the whole data set was registered as either single (N?=?427) or collision (N?=?315).Results: The results show that there was a 3-fold increase in the number of PMD-related accidents reported to STRADA during the period 2007–2016.With regard to single accidents, collisions, as well as fatalities, the injury statistics were dominated by males. Single accidents were more common than collisions (N?=?427 and N?=?316, respectively) and the level of injury sustained in each type of accident is on par. The vast majority of single accidents resulted in the PMD driver impacting the ground (87%), due to either PMD turnover (71%) or the driver falling out of the PMD (16%). The reason for many of the single accidents was a difference in ground level (34%, typically a curb).Cars, trucks, or buses were involved in 67% of collision events; these occured predominantly at junctions or intersections (70%).Abbreviated Injury Scale (AIS) 3+ injuries were dominated by hip and head injuries in both single accidents and collision events.Conclusions: The present study shows that further research on PMD accidents is required, with regard to both single accidents and collision events. To ensure that appropriate decisions are made, future work should follow up on injury trends and further improve the quality of PDM-related accident data. Improved vehicle stability and design, increased usage of safety equipment, proper training programs, effective maintenance services, and development of a supporting infrastructure would contribute to increased safety for PMD drivers. 相似文献
708.
Jana Mrázová Martina Gažarová Jana Kopčeková Anna Kolesárová Ondřej Bučko Branislav Bobček 《Journal of environmental science and health. Part. B》2020,55(1):69-74
AbstractThe aim of the research was to evaluate the effect of consumption of selenium-enriched pork on selected health indicators of probands. The intake of feed mixture with increased organic selenium at the dose of 0.3?mg.kg?1 probably increases selenium concentration in MSM (musculus semimembranosus). In the pork enriched with organic selenium, the concentration was higher by 1.045?±?0.10?mg.kg?1 compared with the control group 0.701?±?0.05?mg.kg?1 at significance P?<?0.001. Sixteen participants in the experiment were represented by 8 men at the average age of 41.5?±?11.9?years and 8 women at the average age of 41.4?±?7.9?years. All the probands consumed meat enriched with selenium three times a week during one month. By consumption of the enriched pork, there was an increase of the selenium concentration in blood serum of probands traced with selenium increase from 73.19?±?15.68?μg.L?1 to 73.73?±?15.13?μg.L?1 (P?>?0.05). From the results we can see that consumption of enriched pork with selenium was significantly manifested in lowering of total cholesterol levels, which was associated with LDL cholesterol lowering (P?<?0.05). Differences among the HDL cholesterol and triglycerides samples were not significant. 相似文献
709.
Lindberg SE Southworth GR Bogle MA Biasing TJ Owens J Roy K Zhang H Kuiken T Price J Reinhart D Sfeir H 《Journal of the Air & Waste Management Association (1995)》2005,55(7):859-869
Mercury-bearing material enters municipal landfills from a wide array of sources, including fluorescent lights, batteries, electrical switches, thermometers, and general waste; however, the fate of mercury (Hg) in landfills has not been widely studied. Using automated flux chambers and downwind atmospheric sampling, we quantified the primary pathways of Hg vapor releases to the atmosphere at six municipal landfill operations in Florida. These pathways included landfill gas (LFG) releases from active vent systems, passive emissions from landfill surface covers, and emissions from daily activities at each working face (WF). We spiked the WF at two sites with known Hg sources; these were readily detected downwind, and were used to test our emission modeling approaches. Gaseous elemental mercury (Hg(O)) was released to the atmosphere at readily detectable rates from all sources measured; rates ranged from approximately 1-10 ng m(-2) hr(-1) over aged landfill cover, from approximately 8-20 mg/hr from LFG flares (LFG included Hg(O) at microg/m3 concentrations), and from approximately 200-400 mg/hr at the WF. These fluxes exceed our earlier published estimates. Attempts to identify specific Hg sources in excavated and sorted waste indicated few readily identifiable sources; because of effective mixing and diffusion of Hg(O), the entire waste mass acts as a source. We estimate that atmospheric Hg releases from municipal landfill operations in the state of Florida are on the order of 10-50 kg/yr, substantially larger than our original estimates, but still a small fraction of current overall anthropogenic losses. 相似文献
710.
Southworth GR Lindberg SE Bogle MA Zhang H Kuiken T Price J Reinhart D Sfeir H 《Journal of the Air & Waste Management Association (1995)》2005,55(7):870-877
Waste distribution and compaction at the working face of municipal waste landfills releases mercury vapor (Hg(o)) to the atmosphere, as does the flaring of landfill gas. Waste storage and processing before its addition to the landfill also has the potential to release Hg(o) to the air if it is initially present or formed by chemical reduction of Hg(II) to Hg(o) within collected waste. We measured the release of Hg vapor to the atmosphere during dumpster and transfer station activities and waste storage before landfilling at a municipal landfill operation in central Florida. We also quantified the potential contribution of specific Hg-bearing wastes, including mercury (Hg) thermometers and fluorescent bulbs, and searched for primary Hg sources in sorted wastes at three different landfills. Surprisingly large fluxes were estimated for Hg losses at transfer facilities (approximately 100 mg/hr) and from dumpsters in the field (approximately 30 mg/hr for 1000 dumpsters), suggesting that Hg emissions occurring before landfilling may constitute a significant fraction of the total emission from the disposal/landfill cycle and a need for more measurements on these sources. Reducing conditions of landfill burial were obviously not needed to generate strong Hg(o) signals, indicating that much of the Hg was already present in a metallic (Hg(o)) form. Attempts to identify specific Hg sources in excavated and sorted waste indicated few readily identifiable sources; because of effective mixing and diffusion of Hg(o), the entire waste mass acts as a source. Broken fluorescent bulbs and thermometers in dumpsters emitted Hg(o) at 10 to >100 microg/hr and continued to act as near constant sources for several days. 相似文献