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291.
Effects of Electron-Beam Irradiation and Ultraviolet Light (365 nm) on Polylactic Acid Plastic Films
Strips of Ca-I [polylactic acid (PLA) monolayer plastic films from Cargill Dow Polymers LLC, Minnetonka, MN] cut in the machine and nonmachine directions were irradiated with an electron beam using a CIRCLE III Linear Accelerator (MeV Industries S.A., Jouy-en-Josas, Cedex, France). The effects of 33-kGy irradiation on the physical properties of the Ca-I strips were studied. In addition, the effects of ultraviolet (UV) light (365-nm) illumination on the degradation of three PLA plastic films, Ch-I (PLA monolayer plastic films from Chronopol, Golden, CO), GII (PLA trilayer plastic films from Cargill Dow Polymers LLC), MN), and Ca-I (PLA monolayer plastic films from Cargill Dow Polymers LLC) were analyzed by a modified ASTM D5208-91 method. Results showed that irradiation had decreased the weight-average molecular weight (M
w), stress at break, percentage of elongation, and strain energy of Ca-I by 35.5, 26.7, 32.3, and 44.8%, respectively (P < 0.01). The shelf life of the irradiated Ca-I strips at 5°C and <20 ± 5% RH was about 6 months. The degradation rate of Ch-I, GII, and Ca-I with no UV light treatment at 55°C and 10% RH was 2512, 5618, and 3785 M
w/week, respectively. Under the UV light illumination (365 nm), the degradation rate of Ch-I, GII, and Ca-I, was 2982, 8722, and 7467 M
w/week, respectively. Hence, the degradation rate of GII and Ca-I was increased 55 and 97% by UV light (P < 0.008), respectively. This trend was not observed in Ch-I because its starting M
w (78,000 g/mol) was close to the tensile strength lost range (50,000 to 75,000 g/mol) of PLA films. To our knowledge, this is the first study to demonstrate that UV light does further enhance the degradation of PLA films. 相似文献
292.
293.
Anita M. Thompson Kyunghyun Kim Anthony J. Vandermuss 《Journal of the American Water Resources Association》2008,44(5):1325-1336
Abstract: Urban impervious surfaces absorb and store thermal energy, particularly during warm summer months. During a rainfall/runoff event, thermal energy is transferred from the impervious surface to the runoff, causing it to become warmer. As this higher temperature runoff enters receiving waters, it can be harmful to coldwater habitat. In an urban watershed, impervious asphalt surfaces (roads, parking lots, and driveways) and pervious residential lawns comprise a significant portion of the watershed area. A paired asphalt‐turfgrass sod plot was constructed to compare the thermal runoff characteristics between asphalt and turfgrass sod surfaces, to identify meteorological variables that influence these thermal characteristics, and to evaluate evaporative heat loss for runoff from asphalt surfaces. Rainfall simulations were conducted during the summers of 2004 and 2005 under a range of climatic conditions. Asphalt surface temperatures immediately prior to rainfall simulations averaged 43.6°C and decreased an average of 12.3°C over 60 min as rain cooled the surface. In contrast, presimulation sod surface temperatures averaged only 23.3°C and increased an average of 1.3°C throughout the rainfall events. Heat transferred from the asphalt to the runoff resulted in initial asphalt runoff temperatures averaging 35.0°C that decreased by an average of 4.1°C at the end of the event. Sod runoff temperatures averaged only 25.5°C and remained fairly constant throughout the simulations. Multivariable regression equations were developed to predict (1) average asphalt surface temperature (R2 = 0.90) and average asphalt runoff temperature (R2 = 0.92) as a function of solar radiation, rain temperature, and wind speed, and (2) average sod surface temperature (R2 = 0.85) and average sod runoff temperature (R2 = 0.94) as a function of solar radiation, rain temperature, rain intensity, and wind speed. Based on a heat balance analysis, existing evaporation equations developed from studies on lakes were not adequate to predict evaporation from runoff on a heated impervious surface. The combined heat from the asphalt and sod plots was an average of 38% less than the total heat had the total area consisted solely of asphalt. 相似文献
294.
Anthony Ricciardi 《Conservation biology》2005,19(5):1672-1673
295.
Wenxiu Zhang Anthony K. Lau Zhiping S. Wen 《Journal of environmental science and health. Part. B》2013,48(5):496-505
Better understanding of the effects of key operational parameters or environmental factors on odor emission is of critical importance for minimizing the generation of composting odors. A series of laboratory experiments was conducted to examine the effects of various operating conditions on odor emissions. The results revealed that airflow rates that were too high or too low could result in higher total odor emissions. An optimal flowrate for odor control would be approximately 0.6 L/min.kg dry matter with intermittent aeration and a duty cycle of 33%. Temperature setpoint at 60°C appeared to be a turning point for odor emission. Below this point, odor emissions increased with increasing temperature setpoint; conversely, odor emissions decreased with increasing temperature setpoint above this point. With regard to the composting material properties, odor emissions were greatly affected by the initial moisture content of feedstock. Both peak odor concentration and emission rate generally increased with higher initial moisture content. Odor emission was significant only at moisture levels higher than 65%. An initial moisture level below 45% is not recommended due to concern with the resulting lower degree of biodegradation. Biodegradable volatile solids content (BVS) of feedstock had pronounced effect on odor emissions. Peak odor concentration and emission rate increased dramatically as BVS increased from 45% to 65%, thus, total odor emission increased exponentially with BVS. 相似文献
296.
Anthony C Fisher John V Krutilla 《Journal of Environmental Economics and Management》1974,1(2):96-108
In this paper we consider the special nature and implications, for economic theory and policy, of resource uses that involve adverse effects on the physical environment that are difficult or impossible to reverse. Distinctions are drawn between reversible and irreversible activities, between replaceable and irreplaceable resources. The existence of an “irreversibility premium” is demonstrated under certain plausible conditions, including uncertainty and shifting time perspective. 相似文献
297.
Factors Influencing the Effectiveness of Wildlife Underpasses in Banff National Park, Alberta, Canada 总被引:12,自引:1,他引:11
Abstract: Wildlife crossing structures are intended to increase permeability and habitat connectivity across roads. Few studies, however, have assessed the effectiveness of these mitigation measures in a multispecies or community level context. We used a null model to test whether wildlife crossing structures serve large mammal species equally or whether such structures limit habitat connectivity across roads in species-specific ways. We also modeled species responses to 14 variables related to underpass structure, landscape features, and human activity. Species performance ratios (observed crossing frequency to expected crossing frequency) were evaluated for four large carnivore and three ungulate species in 11 underpass structures in Banff National Park, Alberta, Canada. Observed crossing frequencies were collected in 35 months of underpass monitoring. Expected frequencies were developed from three independent models: radio telemetry, pellet counts, and habitat-suitability indices. The null model showed that species responded to underpasses differently. In the presence of human activity carnivores were less likely to use underpasses than were ungulates. Apart from human activity, carnivore performance ratios were better correlated to landscape variables, and ungulate performance ratios were better correlated to structural variables. We suggest that future underpasses designed around topography, habitat quality, and location will be minimally successful if human activity is not managed. 相似文献
298.
Anthony Donnellan 《The Environmentalist》2007,27(1):13-23
The National Water Commission (NWC) and the $2 billion Australian Government Water Fund (the fund) has drawn attention to
the need for innovative and adaptive practices for water use. The NWC and the fund, whilst a critical and catalytic step in
the recognition of the current water situation in Australia, has thus far neglected to consider the systemic failures of the
water, irrigation and related industries that led to this point. The underlying issue of the efficient allocation of water
resources can be resolved by the harmonisation of competing demands (economic, social and environmental) and the establishment
of governance structures to reduce institutional impediments. The linking of the fund to National Competition Council (NCC)
payments is an important consideration in this process. This paper will argue that governance reform and institutional (re)alignment
to remedy the impediments to the efficient allocation of water resources needs to be embedded in and linked to national competition
policy principles. This paper will consider the NWC in this context with the aim of informing future policy to consider the
systemic failures of the water industry and to forge institutional change for the more effective allocation of water. 相似文献
299.
Len Wright Paul Chinowsky Kenneth Strzepek Russell Jones Richard Streeter Joel B. Smith Jean-Marc Mayotte Anthony Powell Lesley Jantarasami William Perkins 《Mitigation and Adaptation Strategies for Global Change》2012,17(8):939-955
We assessed the potential impacts of increased river flooding from climate change on bridges in the continental United States. Daily precipitation statistics from four climate models and three greenhouse gas (GHG) emissions scenarios (A2, A1B, and B1) were used to capture a range of potential changes in climate. Using changes in maximum daily precipitation, we estimated changes to the peak flow rates for the 100-year return period for 2,097 watersheds. These estimates were then combined with information from the National Bridge Inventory database to estimate changes to bridge scour vulnerability. The results indicate that there may be significant potential risks to bridges in the United States from increased precipitation intensities. Approximately 129,000 bridges were found to be currently deficient. Tens of thousands to more than 100,000 bridges could be vulnerable to increased river flows. Results by region vary considerably. In general, more bridges in eastern areas are vulnerable than those in western areas. The highest GHG emissions scenarios result in the largest number of bridges being at risk. The costs of adapting vulnerable bridges to avoid increased damage associated with climate change vary from approximately $140 to $250 billion through the 21st century. If these costs were spread out evenly over the century, the annual costs would be several billion dollars. The costs of protecting the bridges against climate change risks could be reduced by approximately 30% if existing deficient bridges are improved with riprap. 相似文献
300.
AbdelHamid Sherihan G. Refaat Aya A. Benjamin Anthony M. Elmawardy Laila A. Elgendy Lougine A. Manolly Mark M. Elmaksoud Nada Abd Sherif Nourhan Hamdy Nadia M. 《Environmental science and pollution research international》2021,28(39):54209-54221
Environmental Science and Pollution Research - COVID-19 pandemic waves hitting worldwide result in drastic postinfection complications with interindividual variations, which raised the question for... 相似文献