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181.
Chloe Indermuhle Maria J. Martín de Vidales Cristina Sáez José Robles Pablo Cañizares Juan F. García-Reyes Antonio Molina-Díaz Christos Comninellis Manuel A. Rodrigo 《Chemosphere》2013
The use of Conductive-Diamond Electrochemical Oxidation (CDEO) and Sonoelectrochemical Oxidation (CDSEO) has been evaluated for the removal of caffeine of wastewater. Effects of initial concentration, current density and supporting electrolyte on the process efficiency are assessed. Results show that caffeine is very efficiently removed with CDEO and that depletion of caffeine has two stages depending on its concentration. At low concentrations, opposite to what it is expected in a mass-transfer controlled process, the efficiency increases with current density very significantly, suggesting a very important role of mediated oxidation processes on the removal of caffeine. In addition, the removal of caffeine is faster than TOC, indicating the formation of reaction intermediates. The number and relative abundance of them depend on the operating conditions and supporting electrolyte used. In chloride media, removal of caffeine is faster and more efficiently, although the occurrence of more intermediates takes place. CDSEO does not increase the efficiency of caffeine removal, but it affects to the formation of intermediates. A detailed characterization of intermediates by liquid chromatography time-of-flight mass spectrometry seems to indicate that the degradation of caffeine by CDEO follows an oxidation pathway similar to mechanism proposed by other advanced oxidation processes. 相似文献
182.
A lignite humic acid (HA) was fractionated by preparative high performance size-exclusion chromatography (HPSEC) in seven different size-fractions. The size-fractions were characterized by cross polarization (CP) magic angle spinning (MAS) (13)C NMR spectroscopy and a further analytical HPSEC elution under UV and fluorescence detection. The alkyl hydrophobic components mainly distributed in the largest molecular-size-fraction, whereas the amount of oxidized carbons increased with decreasing size of fractions. Cross polarization time (T(CH)) and proton spin-lattice relaxation time in the rotating frame (T(1rho)(H)) were measured from variable contact time (VCT) experiments. The bulk HA was characterized by the shortest T(CH) values and the longest T(1rho)(H) values which suggested, respectively, one. an aggregation of components in a large conformation that favored a fast H-C cross polarization, and, two. consequent steric hindrances that prevented fast local molecular motions and decreased proton relaxation rates. Conversely, the separated size-fractions showed longer T(CH) values and shorter T(1rho)(H) values than the bulk HA, thereby indicating that they were constituted by a larger number of mobile molecular conformations. The UV and fluorescence absorptions were both low in the large size-fractions that mainly contained alkyl carbons, whereas they increased in the olephinic- and aromatic-rich fractions with intermediate molecular-size, and decreased again in the smaller fractions which were predominantly composed by oxidized carbons. These results support the supramolecular structure of humic substances and indicate that the observed variation in conformational distribution in humic association may be used to explain environmental processes with additional precision. 相似文献
183.
Barros Ivaldete Tijolin Ceccon Juliana Parolin Glinski Andressa Liebel Samuel Grötzner Sonia Regina Randi Marco Antonio Ferreira Benedito Evanilde Ortolani-Machado Claudia Feijó Filipak Neto Francisco de Oliveira Ribeiro Ciro Alberto 《Environmental science and pollution research international》2017,24(19):16228-16240
Environmental Science and Pollution Research - In the current study, water quality of five river sites in Parana River basin (Brazil), utilized for public water supply, was assessed through a set... 相似文献
184.
Gredilla Ainara Fdez-Ortiz de Vallejuelo Silvia Gomez-Nubla Leticia Carrero Jose Antonio de Leão Felipe B. Madariaga Juan Manuel Silva Luis F. O. 《Environmental science and pollution research international》2017,24(31):24333-24345
Environmental Science and Pollution Research - In city playgrounds, there is a potential risk of harming children’s health by contamination coming from anthropogenic activities. With the aim... 相似文献
185.
Surface marine sediments from Ría de Arousa estuary were analyzed for humic and fulvic acids by UV-visible spectrometry and have been characterized using elemental analysis (carbon, hydrogen and nitrogen elemental composition) and spectrometric data (A2/A4 ratio, absorbancies at 270 and 407 nm and E4/E6 ratio, absorbancies at 465 and 665 nm). These variables have been used as discriminating factors to distinguish of marine and terrestrial origin of humic and fulvic acids in Ría de Arousa surface marine sediments. Principal component analysis, PCA, and cluster analysis, CA, have been used as unsupervised pattern recognition procedures. The half-range central value transformation was used as data pre-treatment to homogenize data. After a Varimax rotation, PCA applied to humic acid data has reveled that spectrometric A2/A4 and E4/E6 ratios are the main dominating features in the first principal component (48.6% of total variance), the humic acid content is the feature with the highest weight in the second principal component (22.9% of the total variability) and the carbon elemental composition domain in the third principal component (13.3% of total variance). Results from PCA have revealed that surface sediments collected at inner-left part of the estuary and at the mouth of the river Ulla belong to the same group. Similarly, PCA has shown that surface sediments from the right mouth of the estuary form a compact group. Taking in account the water circulation in Ría de Arousa estuary, these findings mean that the organic matter in surface sediments from the inner-left part of the estuary derived mainly from terrestrial organic matter while the organic matter in surface sediments from the right mouth of the estuary is mainly derived from marine sources. Finally, it must be noticed that any classification of surface sediments was assessed when applying of PCA and CA from fulvic acids data. 相似文献
186.
The Evolution of the Environmental Quality Concept: From the US EPA Red Book to the European Water Framework Directive 总被引:1,自引:0,他引:1
Vighi M Finizio A Villa S 《Environmental science and pollution research international》2006,13(1):9-14
- DOI: http://dx.doi.org/10.1065/espr2006.01.003
Background Water Quality Criteria were firstly defined in the 1970s by the EPA in the USA and the EIFAC in Europe, recognizing the need
for protecting water quality in order to allow the use of water resources by man. In the 1990s, the European Commission emphasized
the importance of safeguarding structure and function of biologic communities. These approaches were chemically-based. The
European Water Framework Directive (WFD) substantially changes the concept of Water Quality, by assuming that a water body
needs to be protected as an environmental good and not as a resource to be exploited. In this frame, the biological-ecological
quality assumes a prevailing role.
Main Features The Water Quality concept introduced by the WFD is a challenge for environmental sciences. Reference conditions should be
defined for different typologies of water bodies and for different European ecoregions. Suitable indicators should be developed
in order to quantify ecological status and to define what a 'good' ecological status is. Procedures should be developed for
correlating the deviation from a good ecological to the effects of multiple stressors on function and structure of the ecosystem.
The protection of biodiversity becomes a key objective. In this frame, the traditional procedures for ecotoxicological risk
assessment, mainly based on laboratory testing, should be overcome by more site-specific approaches, taking into account the
characteristics and the homeostatic capabilities of natural communities. In the paper an overview of the present knowledge
and of the new trends in ecotoxicology to get these objectives will be given. A procedure is suggested based on the concept
of Species Sensitivity Distribution (SSD).
Recommendations and Perspective . The need for more site-specific and ecologically-oriented approaches in ecotoxicology is strongly recommended. The development
of new tools for implementing the concept of 'Stress Ecology' has been recently proposed by van Straalen (2003). In the same
time, more 'cological realism'is needed in practically applicable procedures for regulatory purposes. 相似文献
187.
Notario A Díaz-de-Mera Y Aranda A Adame JA Parra A Romero E Parra J Muñoz F 《Environmental science and pollution research international》2012,19(1):186-200
Purpose
The purpose of this work is to contribute to the understanding of the photochemical air pollution analysing the levels and temporal variations of surface ozone in two rural areas situated in central-southern Spain. 相似文献188.
Testolin Renan C. Feuzer-Matos Ana Júlia Cotelle Sylvie Adani Fabrizio Janke Leandro Poyer-Radetski Gabriel Pereira Antonio C. Ariente-Neto Rafael Somensi Cleder A. Radetski Claudemir M. 《Environmental science and pollution research international》2021,28(36):49642-49650
Environmental Science and Pollution Research - Recalcitrant dyes found in textile wastewater represent a threat for sustainable textile production due to their resistance to conventional... 相似文献
189.
Giuseppe Latini M. Loredana Marcovecchio Antonio Del Vecchio Francesco Gallo Enrico Bertino Francesco Chiarelli 《Environment international》2009,35(6):987-993
Genetic and environmental factors influence insulin sensitivity (IS) during one's lifetime. Actually, uterine environment may affect IS at birth and later in life. In particular, various exogenous toxic substances, coupled to a genetic predisposition, may remarkably influence the regulation of the hypothalamus–hypophysis–adrenal gland axis, and the production or the activity of insulin, cerebral incretins, pro-inflammatory cytokines, and placental hormones. Owing to this reaction against environmental injuries, fetal growth and endocrine system development may be impaired, leading to low or large birth weight, or prematurity. Reduced growth in early life has been related to insulin resistance, which can be silent for years and evident in predisposed adults. The incidence of type 2 diabetes mellitus and obesity associated with sedentary lifestyle patterns and inadequate dieting behaviors in children and adolescents has rapidly increased during the last decade.Recent evidences suggest that the Pro12Ala polymorphism of the peroxisome proliferator-activated receptor-? (PPAR-?) gene and the angiotensin converting enzyme (ACE) I/D gene polymorphism combined with environmental factors, such as phthalates interfering with the post receptorial action of insulin, alter insulin-sensible tissues. Therefore, IS, deriving from a complex interaction between genotype and environment, may change during life and depends on previous metabolic control, which is a sort of metabolic memory. The goal for the future is preventing the complications associated with impaired IS through the control of exogenous factors and the use of drugs selectively effective on its pathogenesis. 相似文献
190.
François Vialard Giuseppe Simoni Denise Molina Gomes Azzedine Abourra Simona De Toffol Fabrice Bru Maria Carmen Martinez Romero Lucio Nitsch Philippe Bouhanna Livia Marcato Thomas Popowski Beatrice Grimi Jose Antonio Martínez-Conejero B. Benzacken Rita Genesio Francesca R. Grati 《黑龙江环境通报》2012,32(4):329-335