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751.
Warren C Duzgoren-Aydin NS Weston J Willett KL 《Environmental monitoring and assessment》2012,184(2):1107-1119
Hurricanes are relatively frequent ecological disturbances that may cause potentially long-term impacts to the coastal environment.
Hurricane Katrina hit the Mississippi Gulf Coast in August 2005, and caused a storm surge with the potential to change the
trace element content of coastal surface sediments. In this study, surface estuarine and marine sediments were collected monthly
following the storm from ten sites along the Mississippi Gulf Coast (Mobile Bay, Grand Bay Bayous Heron and Cumbest, Pascagoula,
Ocean Springs, Biloxi Gulf, Back Biloxi Bay, Gulfport Gulf, Gulfport Courthouse Rd, and Gulfport Marina). Concentrations of
V, Cr, Mn, Fe, Co, Ni, Zn, As, Cd, and Pb were measured by inductively coupled plasma–mass spectrometry to evaluate their
temporal and spatial variations in the year following Hurricane Katrina. Sediments were characterized by pH, particle size
distribution and total carbon and nitrogen content. Trace element contents of the sediments were determined in both <2 mm
and <63 μm grain size fractions. Results revealed no significant temporal and spatial variability in trace element concentrations,
in either size fraction. Potential ecological risk of the sediments was assessed by using NOAA SQuiRTs’ guideline values;
most concentrations remained below probable adverse effects guidelines to marine organisms suggesting that trace elements
redistributed by Hurricane Katrina would not cause an adverse impact on resident organisms. Instead, the concentrations of
trace elements were site-dependent, with specific contaminants relating to the use of the area prior to Hurricane Katrina. 相似文献
752.
Karakaya and Sultansuyu Dam Lakes, located in the eastern part of Turkey, are important water sources, both for irrigation
and fishery. The main goal of the study was to investigate water qualities of dam lakes using a set of biomarkers in the fish
Cyprinus carpio. For this aim, field sample and laboratory-acclimated fish were compared to identify changes in selected biomarkers. The
activities of ethoxyresorufin-O-deethylase, glutathione S-transferase, glutathione reductase, and carboxylesterase were determined in liver samples. Also, plasma and liver lactate
dehydrogenase, aspartate aminotransferase, and alanine aminotransferase activities were assayed. Brain acetylcholinesterase
and carboxylesterase activities were also determined. The hepatosomatic index and condition factors were calculated. Plasma
vitellogenin assays were evaluated for the presence of xenoestrogen. Physicochemical values of water samples showed the existence
of eutrophication risk, and also, some chemicals in both lakes were determined to be over tolerable limits. The comparisons
of samples from both dam lake and laboratory-acclimated fish showed that the lakes may be at risk of pollution by some xenobiotics,
namely xenoestrogens and acetylcholinesterase-inhibiting agents. 相似文献
753.
Hugo Ramiro Poma Verónica Beatriz Rajal María Dolores Blanco Fernández Patricia Angélica Barril Miguel Oscar Giordano Gisela Masachessi Laura Cecilia Martínez María Beatriz Isa María Cecilia Freire Gabriela López Riviello Daniel Cisterna Silvia Viviana Nates Viviana Andrea Mbayed 《Environmental monitoring and assessment》2013,185(3):2565-2576
Enteric viruses monitoring in surface waters requires the concentration of viruses before detection assays. The aim of this study was to evaluate different methods in terms of recovery efficiencies of bacteriophage PP7 of Pseudomonas aeruginosa, measured by real-time PCR, using it as a viral control process in water analysis. Different nucleic acid extraction methods (silica–guanidinium thiocyanate, a commercial kit (Qiagen Viral RNA Kit) and phenol–chloroform with alcohol precipitation) exhibited very low recovery efficiencies (0.08–4.18 %), being the most efficient the commercial kit used for subsequent experiments. To evaluate the efficiency of three concentration methods, PBS (as model for clean water) and water samples from rivers were seeded to reach high (HC, 106 pfu ml?1) and low concentrations (LC, 104 pfu ml?1) of PP7. Tangential ultrafiltration proved to be more efficient (50.36?±?12.91, 17.21?±?9.22 and 12.58?±?2.35 % for HC in PBS and two river samples, respectively) than adsorption–elution with negatively charged membranes (1.00?±?1.34, 2.79?±?2.62 and 0.05?±?0.08 % for HC in PBS and two river samples, respectively) and polyethylene glycol precipitation (15.95?±?7.43, 4.01?±?1.12 and 3.91?±?0.54 %, for HC in PBS and two river samples, respectively), being 3.2–50.4 times more efficient than the others for PBS and 2.7–252 times for river samples. Efficiencies also depended on the initial virus concentration and aqueous matrixes composition. In consequence, the incorporation of an internal standard like PP7 along the process is useful as a control of the water concentration procedure, the nucleic acid extraction, the presence of inhibitors and the variability of the recovery among replicas, and for the calculation of the sample limit of detection. Thus, the use of a process control, as presented here, is crucial for the accurate quantification of viral contamination. 相似文献
754.
José A. Murillo Pulgarín Luisa F. García Bermejo Armando Carrasquero Durán 《Environmental monitoring and assessment》2013,185(1):573-580
A flow injection analysis method based on ion chromatography and luminol chemiluminescence detection was used for the simultaneous determination of copper (II) and cobalt (II) trace levels in soils and sediments following microwave-assisted acid digestion. Detection was based on chemiluminescence (CL) of the luminol–perborate system in an alkaline medium, which is catalyzed by both transition metals. The concentration and pH of the eluent (oxalic acid) was found to affect CL intensities and retention times, both of which were inversely proportional to the oxalic acid concentration. The calibration curves for both metal ions were linear and allowed a limit of detection of 0.003 μg l?1 for cobalt (II) and 0.014 μg l?1 for cooper (II) to be calculated. The proposed method was successfully used to determine both metal ions in certified reference materials of stream and river sediments and soil samples. Based on the results, the determination is free of interferences from the usual concomitant ions. 相似文献
755.
Jesus M. Paniagua Montaña Rufo Antonio Jimenez Alicia Antolin 《Environmental monitoring and assessment》2013,185(1):311-322
Determining the electromagnetic radiation levels in urban areas is a complicated task. Various approaches have been taken, including numerical simulations using different models of propagation, sampling campaigns to measure field values with which to validate theoretical models, and the formalism of spatial statistics. In the work, we present here that this latter technique was used to construct maps of electric field and its associated uncertainty from experimental data. For this purpose, a field meter and a broadband probe sensitive in the 100-kHz–3-GHz frequency range were used to take 1,020 measurements around buildings and along the perimeter of the area. The distance between sampling points was 5 m. The results were stored in a geographic information system to facilitate data handling and analysis, in particular, the application of the formalism of spatial statistical to the analysis of the distribution of the field levels over the study area. The spatial structure was analyzed using the variographic technique, with the field levels at non-sampled points being interpolated by kriging. The results indicated that, in the urban area analyzed in the present work, the linear density of sampling points could be reduced to a distance which coincides with the length of the blocks of buildings without the statistical parameters varying significantly and with the field level maps being reproduced qualitatively and quantitatively. 相似文献
756.
Majid Soleimani Lope G. Tabil Ike Oguocha Jimmy Fung 《Journal of Polymers and the Environment》2018,26(2):532-542
The objective of this work was to improve the impact and thermal properties of polylactic acid (PLA)-based biocomposite by appropriate application of cellulosic fiber and a bioelastomer. Biocomposites formulations with fiber contents of up to 20% in combination with a bioelastomer were extrusion-compounded in a twin-screw extruder followed by molding in an injection molding system. Fibers used in the formulations included three types of cellulosic fiber; namely, raw fiber from oat hull biomass (RF), hydrolysis byproduct (ATF) which was the solid fraction obtained from an acid-catalyzed hydrolysis of RF, and delignified fibers (AD30, AD65, AD100) which were the products of delignification of ATF. Formulated biocomposites were characterized for thermal (glass transition and melting temperatures, and enthalpy of melting) and physico-mechanical (tensile and bending strengths, stiffness, impact energy, and water absorption) properties. Among all types of biofibers, RF resulted in poor properties in the biocomposites due to the high hemicellulose content in the structure. On the other hand, the ratio of lignin to cellulose (in the absence of hemicellulose) in the modified fibers did not significantly affect the physico-mechanical and thermal properties of the biocomposites. The elastomer applied in the formulations improved the impact energy, thermal properties, and elongation at break of the composites. However, it adversely affected the strength and water resistance of biocomposites, especially in the presence of hemicellulose. The results indicated that, depending on the application, a wide range of PLA green composites with different physico-mechanical properties can be achieved. 相似文献
757.
Mostafa Yusefi Mohammad Khalid Faizah Md Yasin Luqman Chuah Abdullah Mohammad Reza Ketabchi Rashmi Walvekar 《Journal of Polymers and the Environment》2018,26(2):474-486
In this work, performance of cow dung (CD) reinforced poly(lactic acid) (PLA) biocomposites was investigated for the potential use in load bearing application. CD of average 4 mm size was blended with PLA at different CD ratios (0–50 wt%) and their effects on the biocomposite properties were studied. The results showed an improvement in the flexural properties, while the tensile and impact strength dropped by 20 and 28% with the addition of 50% CD. The decline in the tensile and impact strength was due to micro-cracking and voids formation at higher CD content. Also, the incorporation of CD slightly decreased the thermal stability of the biocomposite. However, dynamic mechanical properties of the biocomposites generally improved. SEM analysis of tensile and impact fractured surfaces indicated that the CD had a reasonable adhesion with matrix. Moreover, the SEM micrographs of soil burial studies showed an accelerated degradation of higher CD wt% biocomposites. 相似文献
758.
Meriem Fardioui Taoufik Guedira Abou El Kacem Qaiss Rachid Bouhfid 《Journal of Polymers and the Environment》2018,26(2):443-451
The aim of this paper was to study the effects of reinforcing low density polyethylene (LDPE) by using bio-fillers (Doum cellulose or Shrimp chitin) on the mechanical properties. Both, Doum cellulose extracted frsom Doum leaves and Shrimp chitin extracted from shrimp co-products were compounded with LPDE without and with compatibilizer. The biocomposites were prepared by melt blending in a twin-screw extruder. Torsion and flexural tests were performed to investigate the impact of each reinforcement on the biocomposite mechanical properties. The SEM was carried out to study the filler/polymer interface adhesion. The present study has demonstrated that Doum fibers and shrimp chitin succeed in improving the mechanical properties of LPDE bio-composites. The results also showed that the use of maleic anhydride-grafted polyethylene as a compatibilizer improves filler adhesion/matrix and mechanical properties. This study exhibits that polyethylene composites based on Doum fibers or shrimp chitin can be used to replace the polyethylene materials in several fields like packaging and automotive industries. 相似文献
759.
Rui Galhano dos Santos Noemi F. Acero Sandro Matos Ricardo Carvalho Mário Vale Ana C. Marques João C. Bordado Maria M. Mateus 《Journal of Polymers and the Environment》2018,26(1):91-100
The use of petroleum-derived products should be avoided regarding the principles of green and sustainable chemistry. The work reported herein, is aimed at the liquefaction of pine shavings for the production of an environmentally-friendly polyol suitable to be used in the formulations of sprayable polyurethane foams. The biopolyols were obtained in high yield and were used to replace those derived from fossil sources, to produce more “greener” polyurethane foams and therefore, less dependent on petroleum sources, since the polyol component was substituted by products resulting from biomass liquefaction. The partial and fully exchange of the polyols was accomplished, and the results compared with a reference foam. The foams were afterward, chemical, physical, morphological, and mechanically characterized. The complete replacement of polyether polyol and polyol polyester has presented some similar characteristics as that used as a reference, validating that the path chosen for the development of more sustainable materials is on the right track for the contribution to a cleaner world. 相似文献
760.
Yuling Zhang Hanxiao Wei Yijian Jiang Shaoxin Kang Zhiguang Hu Jilong Wang 《Journal of Polymers and the Environment》2018,26(1):116-121
Poly(aspartic acid-itaconic acid) copolymers (PAI) is a new scale inhibitor for water treatment. Thus, it is necessary to investigate its biodegradability. The biodegradability of PAI was investigated through CO2 evolution tests under different conditions based on determination of carbon dioxide production. The investigation results showed that the degradation rate of PAI on day 10 and day 28 were respectively 38.7 and 79.5%, indicating that PAI was one kind of easily biodegradable scale inhibitors. With the increase in the content of itaconic acid in copolymerization process, the biodegradability of PAI was significantly reduced. In addition, the high biodegradability might be attributed to the existence of C–N bone-structure and more –COO–. Finally, Cu2+ could decrease the degradation percentage and the enzyme inhibition effect of Cu2+ was not the linear effect, but the “low-dosage effect”. 相似文献