Global variability of food waste chemical composition and its consequences on the production of biofuels and chemical compounds

Journal of Material Cycles and Waste Management - The use of food waste (FW) for the production of biofuels and value-added compounds is growing worldwide. However, the significant chemical...     

Heterogeneous alternative catalysts: A bibliometric and systematic evaluation of their application in solar photocatalytic processes

The present study sought to objectively demonstrate how a researcher can, in a structured way, select relevant articles about alternative heterogeneous catalysts in photocatalytic processes. Therefore, the ProKnow-C (Knowledge Development Process – Constructivist) method was used to systematize the results found, with the application bibliometric and systematic analysis techniques for the evaluation of the results. The search string adopted as criteria was: solar photocatalysis AND heterogeneous catalysts OR alternative catalysts AND effluents. The databases were Web of Science, Science Direct and Scopus. The final bibliographic portfolio obtained for the research theme was made up of 19 articles. It was possible to verify advances in the number of publications on the theme over the evaluated period, with the Journal of Photochemistry and Photobiology A: Chemistry standing out in the final portfolio. Evaluating each article in the portfolio individually, it was possible to verify that most studies use combinations of catalysts already reported to create an alternative material to those already investigated in the literature. Those that use waste as catalysts chose to source this material from treatment plants and the steel industry. Around 58% of the papers used hydrogen peroxide in their processes, while 42% chose not to use it. Finally, approximately 63% of the papers in the portfolio used synthetic effluent in their processes, while the rest (37% of the research) chose to use real effluent. The results obtained in this research by applying the method can contribute to studies related to heterogeneous photocatalysis by alternative means over the years.     

Biomass from phytopathogens and culture conditions improve Penicillium chrysogenum antimicrobial activity and antifungal compounds production

The present study evaluated the effect of culture conditions and phytopathogenic strain co-culture on the production of antimicrobial metabolites and antifungal activity of Penicillium chrysogenum R1, which PCR identified. Antimicrobial activity was determined using the Hunter-Hunter experimental design with three factors (pH, incubation temperature, and inoculum, at two levels each). The antifungal metabolites, β 1-3 glucanase and chitinase, produced in the presence of live and inactivated Fusarium oxysporum Fsox C11 biomass, were evaluated using HPLC-MS and GC-MS. Results showed that P. chrysogenum inhibited the growth of five phytopathogenic fungal strains, and the most significant inhibition was observed for F. oxysporum Fsox C11. The best conditions to achieve the highest antifungal activity of the cell-free extract were pH 7, 28°C, 1 × 10⁶ spores/mL, and 144 h of fermentation, observing 86% inhibition of F. oxysporum Fsox C11 growth. Production of antifungal metabolites such as 1,4-benzoquinone imine, viridicatic acid, phenol-5-methyl-2-(1-methyl ethyl), and hydrolytic enzymes β 1-3 glucanase and chitinase was detected. The results define the perspective in designing new processes and products for biocontrol phytopathogens.     

Numerical Modeling of the Impact of a Pumped-Storage Hydroelectric Power Plant on the Reservoirs’ Thermal Stratification Structure: a Case Study in NW Spain

Pumped-storage hydroelectric power plants are generally perceived as an environmentally respectful technology. Nevertheless, the pumping of water from a lower reservoir to an upper impoundment, and the return of that water during power generation, can strongly affect the water quality of the reservoirs. In particular, plant operation can alter their thermal structure, deep water mixing, and water circulation characteristics. The objective of this study is to quantify, through the use of 3D hydrodynamic modeling, the potential impacts of a pumped-storage hydroelectric plant on the thermal stability and mixing of two reservoirs in Galicia, northwest of Spain. To this end, three-dimensional hydrodynamic simulations were conducted using the model Delft3D. Two different coupled models, one for each reservoir, were constructed and subsequently tested for several stratification scenarios, according to measured temperature profiles during the spring and summer season. Several reservoir minimum and maximum operation water levels were also considered. Model simulations demonstrated a high level of mixing in the vicinity of the intake-outlet structures, in particular during startup of the power plant, regardless of the water level in the reservoir. Beyond this area, the results showed a limited overall effect on stratification and mixing in the upper reservoir, owing to the relation between the inflow temperatures and the initial temperature profile of this reservoir. A more significant alteration of the thermal structure is expected in the lower reservoir due to its narrow shape and shallow depth at the structure location, as well as the temperature differences between receiving waters and inflow.     

Accumulation of heavy metals in native Andean plants: potential tools for soil phytoremediation in Ancash (Peru)

Metal contamination is a recurring problem in Peru, caused mainly by mine tailings from a past active mining activity. The Ancash region has the largest number of environmental liabilities, which mobilizes high levels of metals and acid drainages into soils and freshwater sources, posing a standing risk on human and environmental health. Native plant species spontaneously growing on naturally acidified soils and acid mine tailings show a unique tolerance to high metal concentrations and are thus potential candidates for soil phytoremediation. However, little is known about their propagation capacity and metal accumulation under controlled conditions. In this study, we aimed at characterizing nine native plant species, previously identified as potential hyperaccumulators, from areas impacted by mine tailings in the Ancash region. Plants were grown on mine soils under greenhouse conditions during 5 months, after which the concentration of Cd, Cu, Ni, Pb, and Zn was analyzed in roots, shoots, and soils. The bioaccumulation (BAF) and translocation factor (TF) were calculated to determine the amount of each metal accumulated in the roots and shoots and to identify which species could be better suited for phytoremediation purposes. Soil samples contained high Cd (6.50–49.80 mg/kg), Cu (159.50–1187.00 mg/kg), Ni (3.50–8.70 mg/kg), Pb (1707.00–4243.00 mg/kg), and Zn (909.00–7100.00 mg/kg) concentrations exceeding national environmental quality standards. After exposure to mine tailings, concentrations of metals in shoots were highest in Werneria nubigena (Cd, 16.68 mg/kg; Cu, 41.36 mg/kg; Ni, 26.85 mg/kg; Zn, 1691.03 mg/kg), Pennisetum clandestinum (Pb, 236.86 mg/kg), and Medicago lupulina (Zn, 1078.10 mg/kg). Metal concentrations in the roots were highest in Juncus bufonius (Cd, 34.34 mg/kg; Cu, 251.07 mg/kg; Ni, 6.60 mg/kg; Pb, 718.44 mg/kg) and M. lupulina (Zn, 2415.73 mg/kg). The greatest BAF was calculated for W. nubigena (Cd, 1.92; Cu, 1.20; Ni, 6.50; Zn, 3.50) and J. bufonius (Ni, 3.02; Zn, 1.30); BCF for Calamagrostis recta (Cd, 1.09; Cu, 1.80; Ni, 1.09), J. bufonius (Cd, 3.91; Cu, 1.79; Ni, 18.36), and Achyrocline alata (Ni, 137; Zn, 1.85); and TF for W. nubigena (Cd, 2.36; Cu, 1.70; Ni, 2.42; Pb, 1.17; Zn, 1.43), A. alata (Cd, 1.14; Pb, 1.94), J. bufonius (Ni, 2.72; Zn, 1.63), and P. clandestinum (Zn, 1.14). Our results suggest that these plant species have a great potential for soil phytoremediation, given their capability to accumulate and transfer metals and their tolerance to highly metal-polluted environments in the Andean region.     

Matrix effect in case of purification of oily waters by membrane separation combined with pre-ozonation

In the present study, oil in water emulsions (c_oil?=?100 ppm; d_{oil droplets}?<?2 μm) was purified with ozonation followed by microfiltration using polyethersulfone (PES) membrane (d_pore?=?0.2 μm). The effects of pre-ozonation on membrane microfiltration were investigated in detail both in case of ultrapure and model groundwater matrices, applying different durations (0, 5, 10, and 20 min) of pre-ozonation. Simultaneously, the effects of added inorganic water components on the combined method were investigated. Size distribution of oil droplets, zeta potentials, fluxes, and purification efficiencies were measured and fouling mechanisms were described in all cases. It was found that the matrix significantly affected the size distribution and adherence ability of oil droplets onto the membrane surface, therefore fouling mechanisms also were strongly dependent on the matrix. In case of low salt concentration, the total resistance was caused mainly by reversible resistance, which could be significantly reduced (eliminated) by pre-ozonation. In case of model groundwater matrix, nearly twice higher total resistance was measured, and irreversible resistance was dominant, because of the higher adhesion ability of the oil droplets onto the membrane surface. In this case, pre-ozonation resulted in much lower irreversible, but higher reversible resistance. Increased duration of pre-ozonation raised the total resistance and reduced the elimination efficiency (due to fragmented oil droplets and water soluble oxidation by-products) in both cases, therefore short pre-ozonation can be recommended both from economic and performance aspects.     

Management of sludge from fish ponds at the edge of the Itaparica Reservoir (Brazil): an alternative to improve agricultural production

Sludge generated in intensively managed tilapia fingerling breeding ponds near the Itaparica Dam in the semi-arid Brazilian northeastern region was tested as a soil conditioner to produce lettuce in an effort to mitigate the present environmental impact of the deposition of this sludge, thereby giving it a productive destiny. A greenhouse experiment was performed by mixing the sludge with a Haplic Planosol topsoil, a characteristic soil of the region, so that the sludge corresponded to 0, 25, 50, 75, and 100% of the mixture (substrate). The experiment was set up as a randomized block design with five blocks, each with three pots (5-kg substrate per pot) of the five sludge proportion treatments. One lettuce plant was transplanted into each pot, maintained under greenhouse conditions, and harvested 35 days after transplanting. Sludge, soil, and the substrates were evaluated for nutrient concentration and physical characteristics. Green and dry weights, stem diameter, and nitrogen, phosphorus, and potassium concentrations in the aboveground parts of the lettuce plants were determined. Sludge incorporation into the substrate improved its chemical and physical characteristics. The lettuce plants grew best in the substrate with 75% sludge, increasing its biomass production by 50% and more than doubling its nitrogen uptake.     

Land cover effects on water balance partitioning in the Colombian Andes: improved water availability in early stages of natural vegetation recovery

Regional Environmental Change - Vegetation actively affects different components of the water budget in multiple spatial and temporal scales. Changes in vegetation cover and structure—such as...     

Leaf morphoanatomy of species tolerant to excess iron and evaluation of their phytoextraction potential

Setaria parviflora (Poir.) Kerguélen and Paspalum urvillei Steudel are grasses that grow naturally in a soil with high iron contents. This study aimed to characterize morphoanatomically and histochemically the iron phytotoxicity on leaves and evaluate the phytoextraction potential of these grasses. Saplings were cultivated in hydroponic solution with and without excess Fe-EDTA. Regarding measurements taken on leaves, reduction was observed among treatments of Fe-EDTA on height values of abaxial epidermis and bundle sheath in both species. As for iron histolocalization, stronger reaction was observed in leaves of S. parviflora, in comparison with P. urvillei. Anatomical damage, such as protoplast retraction, irregular xylem, changes in cell volume, and cell collapse, and visual symptoms, like leaf bronzing, chlorosis, and necrosis, were similar in both species when exposed to excess iron; however, P. urvillei showed more severe damage. This species accumulated more iron in shoots than S. parviflora and therefore is more favorable for use in phytoextraction. The root system of both species accumulated higher iron concentrations in relation to shoots.