Coastal dynamic and shoreline mapping: multi-sources spatial data analysis in Semarang Indonesia

Semarang coastal area has geomorphologically complex processes, such as erosion-sedimentation, land subsidence, and tidal inundation hazard. Multi-years shoreline mapping is considered a valuable task for coastal monitoring and assessment. This paper presents maps illustrating the shoreline dynamic in a coastal area of Semarang-Indonesia using multi-sources spatial data. The segment data has been obtained by visual delineation of the topographic maps Year 1908, 1937, 1992 and Ikonos image Year 2003 as well as digital number (DN) value analysis and masking operation of Landsat MSS Year 1972 and Landsat ETM Year 2001. For the long period of almost 100 year, the shoreline dynamic in Semarang coastal area is dominated by sedimentation process. Shoreline extended to the sea as a result of man-made infrastructure and natural processes. The research's result was satisfactory and the method has proven to be effective considering lack of homogeneous data-series. However, some further improvement regarding geo-processing can be made and the accuracy can be tested in future version.     

Spatiotemporal variation of groundwater quality using integrated multivariate statistical and geostatistical approaches in Amol–Babol Plain,Iran

In recent years, groundwater quality has become a global concern due to its effect on human life and natural ecosystems. To assess the groundwater quality in the Amol–Babol Plain, a total of 308 water samples were collected during wet and dry seasons in 2009. The samples were analysed for their physico-chemical and biological constituents. Multivariate statistical analysis and geostatistical techniques were applied to assess the spatial and temporal variabilities of groundwater quality and to identify the main factors and sources of contamination. Principal component analysis (PCA) revealed that seven factors explained around 75 % of the total variance, which highlighted salinity, hardness and biological pollution as the dominant factors affecting the groundwater quality in the Plain. Two-way analysis of variance (ANOVA) was conducted on the dataset to evaluate the spatio-temporal variation. The results showed that there were no significant temporal variations between the two seasons, which explained the similarity between six component factors in dry and wet seasons based on the PCA results. There are also significant spatial differences (p?>?0.05) of the parameters under study, including salinity, potassium, sulphate and dissolved oxygen in the plain. The least significant difference (LSD) test revealed that groundwater salinity in the eastern region is significantly different to the central and western side of the study area. Finally, multivariate analysis and geostatistical techniques were combined as an effective method for demonstrating the spatial structure of multivariate spatial data. It was concluded that multiple natural processes and anthropogenic activities were the main sources of groundwater salinization, hardness and microbiological contamination of the study area.     

An integrated assessment of seawater intrusion in a small tropical island using geophysical,geochemical, and geostatistical techniques

In this study, geophysics, geochemistry, and geostatistical techniques were integrated to assess seawater intrusion in Kapas Island due to its geological complexity and multiple contamination sources. Five resistivity profiles were measured using an electric resistivity technique. The results reveal very low resistivity <1 Ωm, suggesting either marine clay deposit or seawater intrusion or both along the majority of the resistivity images. As a result, geochemistry was further employed to verify the resistivity evidence. The Chadha and Stiff diagrams classify the island groundwater into Ca-HCO₃, Ca-Na-HCO₃, Na-HCO₃, and Na-Cl water types, with Ca-HCO₃ as the dominant. The Mg²⁺/Mg²⁺+Ca²⁺, HCO₃ ^?/anion, Cl^?/HCO₃ ^?, Na⁺/Cl^?, and SO₄ ^2?/Cl^? ratios show that some sampling sites are affected by seawater intrusion; these sampling sites fall within the same areas that show low-resistivity values. The resulting ratios and resistivity values were then used in the geographical information system (GIS) environment to create the geostatistical map of individual indicators. These maps were then overlaid to create the final map showing seawater-affected areas. The final map successfully delineates the area that is actually undergoing seawater intrusion. The proposed technique is not area specific, and hence, it can work in any place with similar completed characteristics or under the influence of multiple contaminants so as to distinguish the area that is truly affected by any targeted pollutants from the rest. This information would provide managers and policy makers with the knowledge of the current situation and will serve as a guide and standard in water research for sustainable management plan.     

Detoxification effect of chlorination procedure on waste lead glass

This work reports the detoxification effect of chlorinating volatilization procedure on waste lead glass. The effects of various reaction parameters on lead removal efficiencies were examined, and the optimal operation conditions were 1000 °C, 2 h, and 600 ± 50 Pa, respectively. Moreover, it was found that the residues could be safely applied in a wide range, e.g., for wollastonite synthesis by an environmental benign technique. Accordingly, the typical hazardous waste was successfully converted into a safe raw material for further industrial application.     

Understanding of groundwater salinity using statistical modeling in a small tropical island,East Malaysia

This paper presents an understanding of groundwater salinity by identification of effective factors using chemometric methods (cluster analysis and multiple linear regressions) in Manukan Island, Sabah. Local groundwater and environmental properties were used to explore the effective factors of groundwater salinity. Cluster analysis showed salinity and chloride illustrated the highest similarities. Electrical conductivity and total dissolved solids were also grouped in the same cluster. Seawater is the only chloride source in groundwater of Manukan Island demonstrated an indication of seawater mixing in freshwater. It is an effect of upward movement of the seawater by pumping activities. Precipitation and evapotranspiration (environmental condition) with hydraulic heads were clustered together to show that they also influence salinity concentration in groundwater. Multiple linear regressions showed descending order of the factors from chloride (the largest contribution) to evapotranspiration (the smallest contribution) and illustrated the contribution to groundwater salinity in Manukan Island. The integrated results using chemometric methods have provided a way to identify the effective factors on groundwater salinity. This similar approach and resulting equation can be applied in other small tropical islands with alike hydrogeological condition and limited information available for a better understanding of its groundwater salinity.     

Evaluation of the pollution of the surface waters of Greece from the priority compounds of list II, 76/464/EEC directive, and other toxic compounds

The pollution of the surface waters of Greece from the priority compounds of 76/464/EEC Directive was evaluated. The occurrence of 92 toxic compounds, 64 of which belong to priority compounds of List II, candidates for List I, of 76/464/EEC Directive, was studied in surface waters and wastewater through the developed network of 62 sampling stations, which covers the whole Greek territory. The analytical determination was performed by Purge and Trap-Gas chromatography-Mass spectrometry for volatile and semivolatile organic compounds (VOCs), Gas Chromatography-Electron Capture Detection for organochlorine insecticides, Gas Chromatography-Nitrogen Phosphorous Detection for organophosphorous insecticides, High Performance Liquid Chromatography-Photodiode Array Detection for herbicides, and Electrothermal Atomic Absorption Spectrophotometry and Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) for metals and the toluene extractable organotin compounds. The concentrations of VOCs and insecticides detected in the surface waters of Greece were very low, whereas the concentrations of herbicides and metals ranged generally at moderate levels. VOCs were detected almost exclusively in the rivers and very rarely in the lakes, while the frequency of occurrence of insecticides, herbicides and metals was similar for rivers and lakes. Water quality objectives (WQO) and emission limit values (ELV) have been laid down in national legal framework for a number of compounds detected in the samples, in order to safeguard the quality of surface waters from any future deterioration.     

Aerobic biodegradation of organotin compounds in activated sludge batch reactors

The biodegradation behavior of four organotin (OT) compounds, namely tributyltin (TBT), dibutyltin (DBT), monobutyltin (MBT) and triphenyltin (TPhT), was studied in lab-scale activated sludge batch reactors. The activated sludge was spiked with the OT compounds at a level of 100 microg l(-1) as Sn. Determination of the OT compounds by GC-FPD after ethylation in the dissolved and particulate phase revealed that 24 h after the start of the experiments, almost the total of OT compounds has been removed from the dissolved phase and is associated with the suspended solids. Calculation of mass balance in batch reactors showed that OT compounds biodegradation was performed via a sequential dealkylation process. Removals due to biodegradation were differentiated according to the parent compound. In experiments with non-acclimatized biomass, a percentage of 27.1, 8.3, 73.8 and 51.3 was still present as TBT, DBT, MBT and TPhT, respectively, at the end of the experiment (18th day). Half-lives (t1/2) of 10.2 and 5.1 days were calculated for TBT and DBT, respectively, whereas apparent t1/2 values could not be determined for MBT and TPhT (t1/2>18 days). The capacity of activated sludge to biodegrade OT compounds in the absence of supplemental substrate indicated that these compounds can be metabolized as single sources of carbon and energy in activated sludge systems. Excluding TBT, the presence of low concentrations of supplemental substrate did not affect the biodegradation potential of activated sludge. The acclimatization of biomass on OT compounds enhanced significantly biodegradation, resulting in significant decreases of half-lives of OT compounds. As a result in the presence of acclimatized biomass, half-lives of 1.4, 3.6, 9.8 and 5.0 days were calculated for TBT, DBT, MBT and TPhT, respectively.     

Relative Contribution of Various Diesel Vehicle Classes to the Thessaloniki Urban Air Pollution

Within the framework of this paper an attempt is made in order to assess the relative contribution of the main diesel vehicle classes; namely, buses, taxis and heavy goods vehicles (HGVs) to the air pollution of the Thessaloniki (Greece) urban area based on an emission factors approach. Data sets refer to the situation before and after the construction of the city ring road. Findings show the significant contribution of the ring road to the urban air pollution decrease. This reduction could be mainly attributed to the observed significant traffic decrease of HGVs in the city center between 1988 and 1998. Small changes have been observed during the same period for the bus and taxi traffic in the city center. Also, the improvement of the diesel fuel quality and the temporal renewal of the diesel vehicles are considered as important factors for the observed temporal decreasing trend of the air pollutants with diesel oil origin.     

Identification of naphthalene metabolism by white rot fungus Armillaria sp. F022

Armillaria sp. F022, a white rot fungus isolated from tropical rain forest (Samarinda, Indonesia) was used to biodegrade naphthalene in cultured medium. Transformation of naphthalene by Armillaria sp. F022 which is able to use naphthalene, a two ring-polycyclic aromatic hydrocarbon (PAH) as a source of carbon and energy was investigated. The metabolic pathway was elucidated by identifying metabolites, biotransformation studies and monitoring enzyme activities in cell-free extracts. The identification of metabolites suggests that Armillaria sp. F022 initiates its attack on naphthalene by dioxygenation at its C-1 and C-4 positions to give 1,4-naphthoquinone. The intermediate 2-hydroxybenzaldehyde and salicylic acid, and the characteristic of the meta-cleavage of the resulting diol were identified in the long-term incubation. A part from typical metabolites of naphthalene degradation known from mesophiles, benzoic acid was identified as the next intermediate for the naphthalene pathway of this Armillaria sp. F022. Neither phthalic acid, catechol and cis,cis-muconic acid metabolites were detected in culture extracts. Several enzymes (manganese peroxidase, lignin peroxidase, laccase, 1,2-dioxygenase and 2,3-dioxygenase) produced by Armillaria sp. F022 were detected during the incubation.